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US5436174A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of forming trenches in monocrystalline silicon carbide

Assignee: Intellectual Ventures Holding 81 LLC
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Filing: 1993-01-25
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Granted: 1995-07-25
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Expires: 2013-01-25
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Abstract

Abstract A trench is formed in a monocrystalline silicon carbide substrate by amorphizing a portion of the monocrystalline silicon carbide substrate to define an amorphous silicon carbide region therein. The amorphous silicon carbide region is then removed, to produce a trench in the monocrystalline silicon carbide substrate corresponding to the removed amorphous silicon carbide region. The substrate may be amorphized by implanting ions into a masked substrate so that the implanted ions convert the unmasked portions of the substrate into amorphous silicon carbide. The amorphous silicon carbide may be etched using at least one etchant which etches amorphous silicon carbide relatively quickly and etches monocrystalline silicon carbide relatively slowly, such as hydrofluoric acid and nitric acid. The amorphizing and removing steps may be repeatedly performed to form deep trenches.

Inventors

  • 👤 Bantval J. Baliga
  • 👤 Dev Alok

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 18:16
CPC Classifications
H; H10; H10W; H10W10/00; H10P; H10P50/00; H10W10/01; Y; Y10; Y10S; Y10S148/00; Y10S148/148; Y10S438/00; Y10S438/914; Y10S438/924; Y10S438/931

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 162 words
A method of forming a trench in a monocrystalline silicon carbide substrate, comprising the steps of: directing first electrically inactive ions selected from the group consisting of silicon, hydrogen, neon, helium, carbon and argon to a face of a monocrystalline silicon carbide substrate, so that the first electrically inactive ions implant into a first portion of the monocrystalline silicon carbide substrate and create a first amorphous silicon carbide region therein, said first electrically inactive ions directing step also being performed so that the first electrically inactive ions are implanted at a first oblique angle relative to an axis extending orthogonal to the face; and removing the first amorphous silicon carbide region from the monocrystalline silicon carbide substrate to thereby form a trench in the monocrystalline silicon carbide substrate, said trench having a first sidewall and a bottom which intersects the first sidewall at a second oblique angle which is different from 90 degrees by an amount equal to the first oblique angle.
Claim 2
Independent Claim 162 words
A method of forming a trench in a monocrystalline silicon carbide substrate, comprising the steps of: directing first electrically inactive ions selected from the group consisting of silicon, hydrogen, neon, helium, carbon and argon to a face of a monocrystalline silicon carbide substrate, so that the first electrically inactive ions implant into a first portion of the monocrystalline silicon carbide substrate and create a first amorphous silicon carbide region therein, said first electrically inactive ions directing step also being performed so that the first electrically inactive ions are implanted at a first oblique angle relative to an axis extending orthogonal to the face; and removing the first amorphous silicon carbide region from the monocrystalline silicon carbide substrate to thereby form a trench in the monocrystalline silicon carbide substrate, said trench having a first sidewall and a bottom which intersects the first sidewall at a second oblique angle which is different from 90 degrees by an amount equal to the first oblique angle.
Claim 3
Dependent Claim 37 words
The method of claim 1, wherein said removing step comprises the step of etching the silicon carbide substrate with at least one etchant which selectively etches amorphous silicon carbide at a higher rate than monocrystalline silicon carbide.
Claim 4
Dependent Claim 60 words
The method of claim 1, wherein said first electrically inactive ions directing step and said removing step are performed in sequence to form a trench having a first depth and then said first electrically inactive ions directing step and said removing step are again performed in sequence so that the trench has a second depth, greater than the first depth.
Claim 5
Dependent Claim 22 words
The method of claim 1, wherein said first electrically inactive ions directing step is repeatedly performed before said removing step is performed.
Claim 6
Dependent Claim 48 words
The method of claim 1, wherein said first electrically inactive ions directing step comprises the step of directing first electrically inactive ions from the group to the face and then directing second electrically inactive ions from the group, different from the first electrically inactive ions, to the face.
Claim 7
Dependent Claim 25 words
The method of claim 2, wherein the at least one etchant is selected from the group consisting of HF, buffered HF and HF+HNO 3 .
Claim 8
Dependent Claim 98 words
The method of claim 1, wherein said removing step is preceded by the step of directing electrically inactive ions selected from the group consisting of silicon, hydrogen, neon, helium, carbon and argon to the face of the monocrystalline silicon carbide substrate, so that the electrically inactive ions implant into a second portion of the monocrystalline silicon carbide substrate and create a second amorphous silicon carbide region therein, said electrically inactive ions directing step also being performed so that the electrically inactive ions are implanted at a third oblique angle relative to an axis extending orthogonal to the face.
Claim 9
Independent Claim 281 words
A method of forming a trench in a monocrystalline silicon carbide substrate, comprising the steps of: directing first electrically inactive ions selected from the group consisting of silicon, hydrogen, neon, helium, carbon and argon to a face of a monocrystalline silicon carbide substrate, so that the first electrically inactive ions implant into a first portion of the monocrystalline silicon carbide substrate and create a first amorphous silicon carbide region therein, said first electrically inactive ions directing step also being performed so that the first electrically inactive ions are implanted at a first oblique angle relative to an axis extending orthogonal to the face; and directing second electrically inactive ions selected from the group consisting of silicon, hydrogen, neon, helium, carbon and argon to the face of the monocrystalline silicon carbide substrate, so that the second electrically inactive ions implant into a second portion of the monocrystalline silicon carbide substrate and create a second amorphous silicon carbide region therein, said directing second electrically inactive ions step also being performed so that the second electrically inactive ions are implanted at a third oblique angle relative to an axis extending orthogonal to the face; and removing the first and second amorphous silicon carbide regions from the monocrystalline silicon carbide substrate to thereby form a trench in the monocrystalline silicon carbide substrate, said trench having a first sidewall and a bottom which intersects the first sidewall at a second oblique angle which is different from 90° by an amount equal to the first oblique angle, said trench also having a second sidewall which intersects the bottom at a fourth oblique angle which is different from 90° by an amount equal to the third oblique angle.
Claim 10
Independent Claim 281 words
A method of forming a trench in a monocrystalline silicon carbide substrate, comprising the steps of: directing first electrically inactive ions selected from the group consisting of silicon, hydrogen, neon, helium, carbon and argon to a face of a monocrystalline silicon carbide substrate, so that the first electrically inactive ions implant into a first portion of the monocrystalline silicon carbide substrate and create a first amorphous silicon carbide region therein, said first electrically inactive ions directing step also being performed so that the first electrically inactive ions are implanted at a first oblique angle relative to an axis extending orthogonal to the face; and directing second electrically inactive ions selected from the group consisting of silicon, hydrogen, neon, helium, carbon and argon to the face of the monocrystalline silicon carbide substrate, so that the second electrically inactive ions implant into a second portion of the monocrystalline silicon carbide substrate and create a second amorphous silicon carbide region therein, said directing second electrically inactive ions step also being performed so that the second electrically inactive ions are implanted at a third oblique angle relative to an axis extending orthogonal to the face; and removing the first and second amorphous silicon carbide regions from the monocrystalline silicon carbide substrate to thereby form a trench in the monocrystalline silicon carbide substrate, said trench having a first sidewall and a bottom which intersects the first sidewall at a second oblique angle which is different from 90° by an amount equal to the first oblique angle, said trench also having a second sidewall which intersects the bottom at a fourth oblique angle which is different from 90° by an amount equal to the third oblique angle.
Claim 11
Dependent Claim 15 words
The method of claim 8, wherein the second oblique angle equals the fourth oblique angle.

References Cited (Backward Citations)

US4108715A Cited
JPS56112723A Cited
JPS59112618A Cited
US4735920A Cited
US5087576A Cited
US4981551A Cited
US4925805A Cited
JPH0298129A Cited
JPH03228315A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-07-24 1999-01-23 1999-07-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-07-24 2003-01-23 2003-07-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-07-24 2007-01-23 2007-07-25 $7700.00 Window Closed / Lapsed

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