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Olefin polymerization catalyst and olefin polymerization process

Assignee: Tosoh Corp
•
Filing: 1993-08-02
•
Granted: 1995-04-18
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Expires: 2013-08-02
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Abstract

Abstract A catalyst for polymerization of olefin is provided which comprises (A) a metallocene compound, (B) an organoaluminum compound, and (C) a metal borate or a metal aluminate. The metallocene compound (A) is represented by the general formula (1) below: ##STR1## where Cp 1 and Cp 2 are cyclopentadienyl group; R 1 is an alkylene, arylalkylene, dialkylsilylene, dialkylgermanylene, alkylphosphinediyl, or alkylimino group, R 1 crosslinking Cp 1 and Cp 2 together; m is 0 or 1; M is titanium, zirconium, or hafnium; and R 2 and R 3 are independently hydrogen, halogen, or a hydrocarbon group, an alkoxy group, or an aryloxy group having 1 to 12 carbons, the organic aluminum compound (B) is represented by the general formula (2) below: AlR.sup.4.sub.3 (2) where each R 4 is independently hydrogen, alkyl, alkoxy, or an aryl group, at least one R 4 being an alkyl group, and the metal borate or the metal aluminate (C) being represented by the general formula (3): (C(L).sub.n).sub.b (A).sub.d (3) where C is an alkali metal cation or an alkaline earth metal cation; L is a Lewis base; A is an art ion having elemental boron or elemental aluminum; n is an integer of from 0 to 6; b and d are respectively an integer selected to balance the electric charge.

Inventors

  • 👤 Satoru Yamada
  • 👤 Akihiro Yano

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 13:16
CPC Classifications
C; C08; C08F; C08F10/00; C08F4/00; C08F4/42; C08F4/44; C08F4/60; C08F4/62; C08F4/64; C08F4/659; C08F4/65908; C08F4/65912; C08F4/6592; C08F4/65922

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 232 words
A catalyst for polymerization, comprising (A) a metallocene compound, (B) an organoaluminum compound, and (C) a metal borate or a metal aluminate: the metallocene compound (A) being represented by the general formula (1) below: ##STR3## where Cp 1 and Cp 2 are independently a substituted or unsubstituted cyclopentadienyl group; R 1 is an alkylene group, an arylalkylene group, dialkylsilylene group, dialkylgermanylene group, an alkylphosphinediyl group, or an alkylimino group having 1 to 20 carbons, R 1 crosslinking Cp 1 and Cp 2 together; m is 0 or 1; M is titanium, zirconium, or hafnium; and R 2 and R 3 are independently hydrogen, halogen, or a hydrocarbon group, an alkoxy group, or an aryloxy group having 1 to 12 carbons, the organic aluminum compound (B) being represented by the general formula (2) below: AlR.sup.4.sub.3 ( 2) where each R 4 is independently hydrogen, an alkyl group, an alkoxy group, or an aryl group, at least one R 4 being an alkyl group, and the metal borate or the metal aluminate (C) being represented by the general formula (3): (C(L).sub.n).sub.b (A).sub.d ( 3) where C is an alkali metal cation or an alkaline earth metal cation; L is a Lewis base; A is an anion having elemental boron or elemental aluminum; n is an integer of from 1 to 6; b and d are respectively an integer selected to balance the electric charge.
Claim 2
Dependent Claim 232 words
A catalyst for polymerization, comprising (A) a metallocene compound, (B) an organoaluminum compound, and (C) a metal borate or a metal aluminate: the metallocene compound (A) being represented by the general formula (1) below: ##STR3## where Cp 1 and Cp 2 are independently a substituted or unsubstituted cyclopentadienyl group; R 1 is an alkylene group, an arylalkylene group, dialkylsilylene group, dialkylgermanylene group, an alkylphosphinediyl group, or an alkylimino group having 1 to 20 carbons, R 1 crosslinking Cp 1 and Cp 2 together; m is 0 or 1; M is titanium, zirconium, or hafnium; and R 2 and R 3 are independently hydrogen, halogen, or a hydrocarbon group, an alkoxy group, or an aryloxy group having 1 to 12 carbons, the organic aluminum compound (B) being represented by the general formula (2) below: AlR.sup.4.sub.3 ( 2) where each R 4 is independently hydrogen, an alkyl group, an alkoxy group, or an aryl group, at least one R 4 being an alkyl group, and the metal borate or the metal aluminate (C) being represented by the general formula (3): (C(L).sub.n).sub.b (A).sub.d ( 3) where C is an alkali metal cation or an alkaline earth metal cation; L is a Lewis base; A is an anion having elemental boron or elemental aluminum; n is an integer of from 1 to 6; b and d are respectively an integer selected to balance the electric charge.
Claim 3
Dependent Claim 9 words
The catalyst of claim 1, wherein n is 1.
Claim 4
Dependent Claim 13 words
The catalyst of claim 1, wherein said Lewis base is an ether compound.
Claim 5
Dependent Claim 11 words
The catalyst of claim 1, wherein said Lewis base is tetrahydrofuran.
Claim 6
Dependent Claim 12 words
The catalyst of claim 1, wherein said Lewis base is diethyl ether.
Claim 7
Dependent Claim 12 words
The catalyst of claim 2, wherein said Lewis base is diethyl ether.
Claim 8
Dependent Claim 18 words
The catalyst of claim 1, wherein R 1 is an alkylene group having 1 to 20 carbon atoms.
Claim 9
Dependent Claim 9 words
The catalyst of claim 1, wherein M is zirconium.
Claim 10
Dependent Claim 12 words
The catalyst of claim 1, wherein component (C) is a metal borate.
Claim 11
Dependent Claim 12 words
The catalyst of claim 6, wherein component (C) is a metal borate.
Claim 12
Dependent Claim 12 words
The catalyst of claim 1, wherein component (C) is a metal aluminate.
Claim 13
Dependent Claim 12 words
The catalyst of claim 6, wherein component (C) is a metal aluminate.
Claim 14
Dependent Claim 53 words
The catalyst of claim 1, wherein said metallocene compound is selected from the group consisting of ethylenebis(indenyl)-zirconium dichloride and isopropylidene(cyclopentadienyl-1-fluorenyl)zirconium dichloride, said organoaluminum compound is triisobutylaluminum and said component (C) is selected from the group consisting of the diethyl ether complex of lithium tetrakis(pentafluorophenyl)borate and the diethyl ether complex of lithium tetrakis(pentafluorophenyl) aluminate.

References Cited (Backward Citations)

EP0277004A1 Cited
US5241025A Cited
US5278119A Cited
EP0314797A1 Cited
EP0481480A1 Cited
EP0513380A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-04-17 1998-10-17 1999-04-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-04-17 2002-10-17 2003-04-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-04-17 2006-10-17 2007-04-18 $7700.00 Window Closed / Lapsed

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