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US5403775A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making semiconductor devices and techniques for controlled optical confinement

Assignee: University of Illinois System
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Filing: 1994-06-15
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Granted: 1995-04-04
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Expires: 2014-06-15
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Abstract

Abstract The disclosure is directed to improved techniques and devices employing an aluminum-bearing III-V semiconductor material and a native oxide of aluminum that is formed in the semiconductor material. Effective optical confinement, tailored to obtain desired operating conditions, can be achieved with a thick native oxide of aluminum that extends through at least one-third of the thickness of the aluminum-bearing layer in which the native oxide is formed. The resultant lateral index step can be made quite large and employed for devices such as ring lasers.

Inventors

  • 👤 Nick Holonyak, Jr.
  • 👤 Fred A. Kish
  • 👤 Stephen J. Caracci

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:02
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/69; H10P14/692; H10P14/6938; H10P14/6939; H10P14/69391; H01; H01S; H01S5/00; H01S5/10; H01S5/1021; H10P14/63; H10P14/6302; H10P14/6304; H10P14/6306; H10P14/6312; H10P14/6322; H01S5/02; H01S5/026; H01S5/1028; H01S5/1071; H01S5/40; H01S5/4025; H01S5/4031; H01S5/4056; H01S5/4068

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 144 words
A method of making a semiconductor laser having a light path that is at least partially curved, comprising the steps of: forming a layered semiconductor structure comprising an active region between first and second semiconductor confining layers, said first and second semiconductor confining layers being of opposite conductivity types, and said first semiconductor confining layer being an aluminum-bearing III-V semiconductor material; applying a mask pattern over said first semiconductor confining layer, said pattern including a stripe that is at least partially curved; exposing unmasked portions of said first semiconductor confining layer to a water-containing environment and a temperature of at least 375 degrees C. for a time sufficient to form a native oxide of aluminum in said first semiconductor confining layer, said native oxide having a thickness of at least 3000 Å; and coupling respective electrodes with said first and second semiconductor confining layers.
Claim 2
Independent Claim 144 words
A method of making a semiconductor laser having a light path that is at least partially curved, comprising the steps of: forming a layered semiconductor structure comprising an active region between first and second semiconductor confining layers, said first and second semiconductor confining layers being of opposite conductivity types, and said first semiconductor confining layer being an aluminum-bearing III-V semiconductor material; applying a mask pattern over said first semiconductor confining layer, said pattern including a stripe that is at least partially curved; exposing unmasked portions of said first semiconductor confining layer to a water-containing environment and a temperature of at least 375 degrees C. for a time sufficient to form a native oxide of aluminum in said first semiconductor confining layer, said native oxide having a thickness of at least 3000 Å; and coupling respective electrodes with said first and second semiconductor confining layers.
Claim 3
Dependent Claim 39 words
The method as defined by claim 1, wherein said active region includes at least a waveguide layer and a quantum well layer, and wherein said respective electrodes are coupled to said semiconductor confining layers through further respective semiconductor layers.
Claim 4
Dependent Claim 19 words
The method as defined by claim 1, wherein said curved portion is in the shape of an annular arc.
Claim 5
Dependent Claim 15 words
The method as defined by claim 1, wherein said curved portion is an annular ring.
Claim 6
Dependent Claim 30 words
The method as defined by claim 3, wherein said time is sufficient to have said native oxide extend through at least most of the thickness of said first confining layer.
Claim 7
Dependent Claim 30 words
The method as defined by claim 4, wherein said time is sufficient to have said native oxide extend through at least most of the thickness of said first confining layer.
Claim 8
Dependent Claim 21 words
The method as defined by claim 6, wherein said native oxide extends through the entire thickness of said first confining layer.
Claim 9
Dependent Claim 23 words
The method as defined by claim 1, wherein said aluminum-bearing material comprises Al x Ga 1-x As, where x is at least 0.3.
Claim 10
Dependent Claim 28 words
The method as defined by claim 1, wherein said water-containing environment comprises water vapor and an inert gas, and wherein said temperature is at least 450 degrees C.
Claim 11
Independent Claim 133 words
A method of making a semiconductor laser, comprising the steps of: forming a layered semiconductor structure comprising an active region between first and second semiconductor confining layers, said first and second semiconductor confining layers being of opposite conductivity types, and said first semiconductor confining layer being an aluminum-bearing III-V semiconductor material; applying a mask pattern over said first semiconductor confining layer; exposing unmasked portions of said first semiconductor confining layer to a water-containing environment and a temperature of at least 375 degrees C. for a time sufficient to form a native oxide of aluminum in said first semiconductor confining layer that is at least 3000 Angstroms thick and extends through at least one-third of the thickness of said first confining layer; and coupling respective electrodes with said first and second semiconductor confining layers.
Claim 12
Independent Claim 133 words
A method of making a semiconductor laser, comprising the steps of: forming a layered semiconductor structure comprising an active region between first and second semiconductor confining layers, said first and second semiconductor confining layers being of opposite conductivity types, and said first semiconductor confining layer being an aluminum-bearing III-V semiconductor material; applying a mask pattern over said first semiconductor confining layer; exposing unmasked portions of said first semiconductor confining layer to a water-containing environment and a temperature of at least 375 degrees C. for a time sufficient to form a native oxide of aluminum in said first semiconductor confining layer that is at least 3000 Angstroms thick and extends through at least one-third of the thickness of said first confining layer; and coupling respective electrodes with said first and second semiconductor confining layers.
Claim 13
Dependent Claim 39 words
The method as defined by claim 10, wherein said active region includes at least a waveguide layer and a quantum well layer, and wherein said respective electrodes are coupled to said semiconductor confining layers through further respective semiconductor layers.
Claim 14
Dependent Claim 30 words
The method as defined by claim 10, wherein said time is sufficient to have said native oxide extend through at least most of the thickness of said first confining layer.
Claim 15
Dependent Claim 21 words
The method as defined by claim 10, wherein said native oxide extends through the entire thickness of said first confining layer.
Claim 16
Dependent Claim 23 words
The method as defined by claim 10, wherein said aluminum-bearing material comprises Al x Ga 1-x As, where x is at least 0.3.
Claim 17
Dependent Claim 28 words
The method as defined by claim 10, wherein said water-containing environment comprises water vapor and an inert gas, and wherein said temperature is at least 450 degrees C.
Claim 18
Independent Claim 144 words
A method of producing a lateral index of refraction step of given effective size, comprising the steps of: forming a layered semiconductor structure that includes a second semiconductor layer, a waveguide layer disposed on said second semiconductor layer, and a first semiconductor layer disposed on said waveguide layer, said first semiconductor layer being an aluminum-bearing III-V semiconductor material; applying a masking pattern over at least part of said first semiconductor layer; initiating treatment of the unmasked surface of said first semiconductor layer with a water-containing environment and a temperature of at least 375 degrees C. to initiate formation of a native oxide of aluminum in said first semiconductor layer; and continuing said treatment for a selected period of time that determines the size of the effective lateral index of refraction step in the lateral direction of said waveguide layer and said first semiconductor layer.
Claim 19
Independent Claim 144 words
A method of producing a lateral index of refraction step of given effective size, comprising the steps of: forming a layered semiconductor structure that includes a second semiconductor layer, a waveguide layer disposed on said second semiconductor layer, and a first semiconductor layer disposed on said waveguide layer, said first semiconductor layer being an aluminum-bearing III-V semiconductor material; applying a masking pattern over at least part of said first semiconductor layer; initiating treatment of the unmasked surface of said first semiconductor layer with a water-containing environment and a temperature of at least 375 degrees C. to initiate formation of a native oxide of aluminum in said first semiconductor layer; and continuing said treatment for a selected period of time that determines the size of the effective lateral index of refraction step in the lateral direction of said waveguide layer and said first semiconductor layer.
Claim 20
Dependent Claim 30 words
The method as defined by claim 16, wherein said time is sufficient to have said native oxide extend through at least half of the thickness of said first semiconductor layer.
Claim 21
Dependent Claim 23 words
The method as defined by claim 16, wherein said aluminum-bearing material comprises Al x Ga 1-x As, where x is at least 0.3.
Claim 22
Dependent Claim 28 words
The method as defined by claim 16, wherein said water-containing environment comprises water vapor and an inert gas, and wherein said temperature is at least 450 degrees C.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-04-03 1998-10-03 1999-04-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-04-03 2002-10-03 2003-04-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-04-03 2006-10-03 2007-04-04 $7700.00 Window Closed / Lapsed

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