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US5393593A Expired / Lapsed US ⏱️ 0.0 years remaining

Dark gray, infrared absorbing glass composition and coated glass for privacy glazing

Assignee: Vitro SAB de CV
•
Filing: 1993-10-12
•
Granted: 1995-02-28
•
Expires: 2013-10-12
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Abstract

Abstract A neutral, dark gray, soda-lime-silica glass having luminous transmittance less than 35 percent, infrared transmittance less than 20 percent, and total solar energy transmittance less than 22 percent (all at 3.9 millimeter thickness) is produced with colorants consisting essentially of 1.0 to 2.2 percent by weight total iron, at least 0.20 percent FeO, 0.01 to 0.03 percent CoO, and 0.0005 to 0.005 percent Se. The flat glass product having such a composition is particularly suitable for use as privacy glazing. The use of the glass as a substrate for a reflectively coated product is also disclosed. A low transmittance, reflective coated article is disclosed comprising a soda-lime-silica glass substrate having luminous transmittance less than 35 percent, infrared transmittance less than 20 percent, and total solar energy transmittance less than 22 percent (all at 3.9 millimeter thickness) and a metal oxide coating having a luminous reflectance not more than 25 percent from the coated surface, and not more than 8 percent from the uncoated surface. The low transmittance coated glass product is particularly suitable for use as privacy glazing.

Inventors

  • 👤 Joseph A. Gulotta
  • 👤 John F. Krumwiede
  • 👤 Luke A. Kutilek
  • 👤 Anthony V. Longobardo
  • 👤 Robert B. Heithoff

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 02:51
CPC Classifications
C; C03; C03C; C03C4/00; C03C4/02; C03C1/00; C03C1/10; C03C3/00; C03C3/04; C03C3/076; C03C3/083; C03C3/085; C03C3/087; C03C4/08; C03C4/082; Y; Y10; Y10S; Y10S501/00; Y10S501/90; Y10S501/904; Y10S501/905; Y10T; Y10T428/00; Y10T428/24; Y10T428/24942

Claims Analysis

Total Claims: 51
Claim 1
Independent Claim 98 words
A neutral gray colored glass composition having a base glass portion comprising: ______________________________________ SiO.sub.2 66-75 percent by weight Na.sub.2 O 10-20 CaO 5-15 MgO 0-5 Al.sub.2 O.sub.3 0-5 K.sub.2 O 0-5 ______________________________________ and a colorant portion consisting essentially of: ______________________________________ Fe.sub.2 O.sub.3 (total iron) greater than 1.00 and up to 1.7 percent by weight FeO at least 0.27 Se 0.001 up to but less than 0.005 CoO 0.01-0.02 ______________________________________ the glass having a luminous transmittance of no more than 32 percent, and a total solar infrared transmittance of less than 15 percent at a thickness of 3.9 millimeters.
Claim 2
Dependent Claim 98 words
A neutral gray colored glass composition having a base glass portion comprising: ______________________________________ SiO.sub.2 66-75 percent by weight Na.sub.2 O 10-20 CaO 5-15 MgO 0-5 Al.sub.2 O.sub.3 0-5 K.sub.2 O 0-5 ______________________________________ and a colorant portion consisting essentially of: ______________________________________ Fe.sub.2 O.sub.3 (total iron) greater than 1.00 and up to 1.7 percent by weight FeO at least 0.27 Se 0.001 up to but less than 0.005 CoO 0.01-0.02 ______________________________________ the glass having a luminous transmittance of no more than 32 percent, and a total solar infrared transmittance of less than 15 percent at a thickness of 3.9 millimeters.
Claim 3
Dependent Claim 27 words
The composition of claim 1 wherein the colorant portion includes greater than 1.0 to 1.3 percent by weight total iron expressed as Fe 2 O 3 .
Claim 4
Dependent Claim 15 words
The composition of claim 1 wherein the FeO concentration is at least 0.30 weight percent.
Claim 5
Dependent Claim 15 words
The composition of claim 1 wherein the FeO concentration is at least 0.35 weight percent.
Claim 6
Dependent Claim 27 words
The composition of claim 1 wherein the colorant portion is selected so as to yield total solar infrared transmittance less than 13 percent at 3.9 millimeters thickness.
Claim 7
Dependent Claim 27 words
The composition of claim 1 wherein the colorant portion is selected so as to yield total solar infrared transmittance less than 10 percent at 3.9 millimeters thickness.
Claim 8
Dependent Claim 24 words
The composition of claim 1 wherein the color of the glass is characterized by dominant wavelengths in the range of 485 to 510 nanometers.
Claim 9
Dependent Claim 22 words
The composition of claim 7 wherein the color of the glass is characterized by an excitation purity of no higher than 15%.
Claim 10
Dependent Claim 29 words
The glass composition of claim 1 wherein the colorant portion is selected so as to yield a total solar energy transmittance of less than 25% at 3.9 mm thickness.
Claim 11
Dependent Claim 71 words
The composition as in claim 1 wherein said colorant portion includes 1.15-1.45 wt. % Fe 2 O 3 , 0.25-0.40 wt. % FeO, 0.19-0.23 wt. % CoO, and 0.002-0.0035 wt. % Se, and further wherein said composition has a luminous transmittance of no greater than 25%, a total solar infrared transmittance of no greater than 15% and a total solar energy transmittance of no greater than 25% at 3.9 mm thickness.
Claim 12
Dependent Claim 71 words
The composition as in claim 10 wherein said colorant portion includes 1.18-1.26 wt. % Fe 2 O 3 , 0.28-0.34 wt. % FeO, 0.195-0.215 wt. % CoO, and 0.0022-0.0031 wt. % Se, and further wherein said composition has a luminous transmittance of no greater than 21%, a total solar infrared transmittance of no greater than 12% and a total solar energy transmittance of no greater than 20% at 3.9 mm thickness.
Claim 13
Dependent Claim 97 words
An article of manufacture comprising a glass sheet having a base glass portion comprising: ______________________________________ SiO.sub.2 66-75 percent by weight Na.sub.2 O 10-20 CaO 5-15 MgO 0-5 Al.sub.2 O.sub.3 0-5 K.sub.2 O 0-5 ______________________________________ and a colorant portion consisting essentially of: ______________________________________ Fe.sub.2 O.sub.3 (total iron) greater than 1.00 and up to 1.7 percent by weight FeO at least 0.27 Se 0.001 up to but less than 0.005 CoO 0.01-0.02 ______________________________________ the glass having a luminous transmittance of no more than 32percent, and total solar infrared transmittance less than 15 percent at a thickness of 3.9 millimeters.
Claim 14
Dependent Claim 97 words
An article of manufacture comprising a glass sheet having a base glass portion comprising: ______________________________________ SiO.sub.2 66-75 percent by weight Na.sub.2 O 10-20 CaO 5-15 MgO 0-5 Al.sub.2 O.sub.3 0-5 K.sub.2 O 0-5 ______________________________________ and a colorant portion consisting essentially of: ______________________________________ Fe.sub.2 O.sub.3 (total iron) greater than 1.00 and up to 1.7 percent by weight FeO at least 0.27 Se 0.001 up to but less than 0.005 CoO 0.01-0.02 ______________________________________ the glass having a luminous transmittance of no more than 32percent, and total solar infrared transmittance less than 15 percent at a thickness of 3.9 millimeters.
Claim 15
Dependent Claim 16 words
The article of claim 12 wherein the sheet has a thickness of 2 to 10 millimeters.
Claim 16
Dependent Claim 16 words
The article of claim 12 wherein the sheet has a thickness of 3 to 6 millimeters.
Claim 17
Dependent Claim 22 words
The article of claim 12 wherein a surface portion of the sheet includes at least 0.05 percent by weight SnO 2 .
Claim 18
Dependent Claim 20 words
The article of claim 12 wherein the luminous transmittance is less than 30 percent at a thickness of 3.9 millimeters.
Claim 19
Dependent Claim 27 words
The article of claim 12 wherein the colorant portion includes greater than 1.0 to 1.3 percent by weight total iron expressed as Fe 2 O 3 .
Claim 20
Dependent Claim 15 words
The article of claim 12 wherein the FeO concentration is at least 0.30 weight percent.
Claim 21
Dependent Claim 15 words
The article of claim 12 wherein the FeO concentration is at least 0.35 weight percent.
Claim 22
Dependent Claim 27 words
The article of claim 12 wherein the colorant portion is selected so as to yield total solar infrared transmittance less than 13 percent at 3.9 millimeters thickness.
Claim 23
Dependent Claim 27 words
The article of claim 12 wherein the colorant portion is selected so as to yield total solar infrared transmittance less than 10 percent at 3.9 millimeters thickness.
Claim 24
Dependent Claim 24 words
The article of claim 12 wherein the color of the glass is characterized by dominant wavelengths in the range of 485 to 510 nanometers.
Claim 25
Dependent Claim 22 words
The article of claim 22 wherein the color of the glass is characterized by an excitation purity of no higher than 15%.
Claim 26
Dependent Claim 28 words
The article of claim 12 wherein the colorant portion is selected so as to yield a total solar energy transmittance of less than 25% at 3.9 mm thickness.
Claim 27
Dependent Claim 98 words
A neutral gray colored glass composition having a base glass portion comprising: ______________________________________ SiO.sub.2 66-75 percent by weight Na.sub.2 O 10-20 CaO 5-15 MgO 0-5 Al.sub.2 O.sub.3 0-5 K.sub.2 O 0-5 ______________________________________ and a colorant portion consisting essentially of: ______________________________________ Fe.sub.2 O.sub.3 (total iron) greater than 1.00 and up to 2.2 percent by weight FeO at least 0.20 Se 0.0005 up to but less than 0.005 CoO 0.010-0.030 ______________________________________ the glass having a luminous transmittance of no more than 35 percent, and a total solar infrared transmittance of less than 20 percent at a thickness of 3.9 millimeters.
Claim 28
Dependent Claim 98 words
A neutral gray colored glass composition having a base glass portion comprising: ______________________________________ SiO.sub.2 66-75 percent by weight Na.sub.2 O 10-20 CaO 5-15 MgO 0-5 Al.sub.2 O.sub.3 0-5 K.sub.2 O 0-5 ______________________________________ and a colorant portion consisting essentially of: ______________________________________ Fe.sub.2 O.sub.3 (total iron) greater than 1.00 and up to 2.2 percent by weight FeO at least 0.20 Se 0.0005 up to but less than 0.005 CoO 0.010-0.030 ______________________________________ the glass having a luminous transmittance of no more than 35 percent, and a total solar infrared transmittance of less than 20 percent at a thickness of 3.9 millimeters.
Claim 29
Dependent Claim 27 words
The composition of claim 25 wherein the colorant portion includes greater than 1.0 to 1.7 percent by weight total iron expressed as Fe 2 O 3 .
Claim 30
Dependent Claim 15 words
The composition of claim 25 wherein the FeO concentration is at least 0.27 weight percent.
Claim 31
Dependent Claim 16 words
The composition of claim 25 wherein the FeO concentration is between 0.27 to 0.50 weight percent.
Claim 32
Dependent Claim 27 words
The composition of claim 25 wherein the colorant portion is selected so as to yield total solar infrared transmittance less than 13 percent at 3.9 millimeters thickness.
Claim 33
Dependent Claim 24 words
The composition of claim 25 wherein the color of the glass is characterized by dominant wavelengths in the range of 485 to 580 nanometers.
Claim 34
Dependent Claim 22 words
The composition of claim 30 wherein the color of the glass is characterized by an excitation purity of no higher than 15%.
Claim 35
Dependent Claim 29 words
The glass composition of claim 25 wherein the colorant portion is selected so as to yield a total solar energy transmittance of less than 25% at 3.9 mm thickness.
Claim 36
Dependent Claim 71 words
The article as in claim 12 wherein said colorant portion includes 1.15-1.45 wt. % Fe 2 O 3 , 0.25-0.40 wt. % FeO, 0.19-0.23 wt. % CoO, and 0.002-0.0035 wt. % Se, and further wherein said glass has a luminous transmittance of no greater than 25%, a total solar infrared transmittance of no greater than 15% and a total solar energy transmittance of no greater than 25% at 3.9 mm thickness.
Claim 37
Dependent Claim 71 words
The article as in claim 33 wherein said colorant portion includes 1.18-1.26 wt. % Fe 2 O 3 , 0.28-0.34 wt. % FeO, 0.195-0.215 wt. % CoO, and 0.0022-0.0031 wt. % Se, and further wherein said glass has a luminous transmittance of no greater than 21%, a total solar infrared transmittance of no greater than 12% and a total solar energy transmittance of no greater than 20% at 3.9 mm thickness.
Claim 38
Dependent Claim 98 words
An article of manufacture comprising a glass sheet having a base glass portion comprising: ______________________________________ SiO.sub.2 66-75 percent by weight Na.sub.2 O 10-20 CaO 5-15 MgO 0-5 Al.sub.2 O.sub.3 0-5 K.sub.2 O 0-5 ______________________________________ and a colorant portion consisting essentially of: ______________________________________ Fe.sub.2 O.sub.3 (total iron) greater than 1.00 and up to 2.2 percent by weight FeO at least 0.20 Se 0.0005 up to but less than 0.005 CoO 0.010-0.030 ______________________________________ the glass having a luminous transmittance of no more than 35 percent, and total solar infrared transmittance less than 20 percent at a thickness of 3.9 millimeters.
Claim 39
Dependent Claim 98 words
An article of manufacture comprising a glass sheet having a base glass portion comprising: ______________________________________ SiO.sub.2 66-75 percent by weight Na.sub.2 O 10-20 CaO 5-15 MgO 0-5 Al.sub.2 O.sub.3 0-5 K.sub.2 O 0-5 ______________________________________ and a colorant portion consisting essentially of: ______________________________________ Fe.sub.2 O.sub.3 (total iron) greater than 1.00 and up to 2.2 percent by weight FeO at least 0.20 Se 0.0005 up to but less than 0.005 CoO 0.010-0.030 ______________________________________ the glass having a luminous transmittance of no more than 35 percent, and total solar infrared transmittance less than 20 percent at a thickness of 3.9 millimeters.
Claim 40
Dependent Claim 16 words
The article of claim 35 wherein the sheet has a thickness of 2 to 10 millimeters.
Claim 41
Dependent Claim 22 words
The article of claim 35 wherein a surface portion of the sheet includes at least 0.05 percent by weight SnO 2 .
Claim 42
Dependent Claim 20 words
The article of claim 35 wherein the luminous transmittance is less than 30 percent at a thickness of 3.9 millimeters.
Claim 43
Dependent Claim 27 words
The article of claim 35 wherein the colorant portion includes greater than 1.0 to 1.7 percent by weight total iron expressed as Fe 2 O 3 .
Claim 44
Dependent Claim 15 words
The article of claim 35 wherein the FeO concentration is at least 0.27 weight percent.
Claim 45
Dependent Claim 16 words
The article of claim 35 wherein the FeO concentration is between 0.28 to 0.50 weight percent.
Claim 46
Dependent Claim 21 words
The article of claim 41 wherein the Fe 2 O 3 concentration is from greater than 1.0 to 1.2 weight percent.
Claim 47
Dependent Claim 19 words
The article of claim 41 wherein the Fe 2 O 3 concentration is from 1.3 to 1.7 weight percent.
Claim 48
Dependent Claim 27 words
The article of claim 35 wherein the colorant portion is selected so as to yield total solar infrared transmittance less than 13 percent at 3.9 millimeters thickness.
Claim 49
Dependent Claim 24 words
The article of claim 35 wherein the color of the glass is characterized by dominant wavelengths in the range of 485 to 580 nanometers.
Claim 50
Dependent Claim 22 words
The article of claim 45 wherein the color of the glass is characterized by an excitation purity of no higher than 15%.
Claim 51
Dependent Claim 28 words
The article of claim 35 wherein the colorant portion is selected so as to yield a total solar energy transmittance of less than 25% at 3.9 mm thickness.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-02-27 1998-08-29 1999-02-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-02-27 2002-08-29 2003-02-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-02-27 2006-08-29 2007-02-28 $7700.00 Window Closed / Lapsed

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