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Resin composition containing fluorine-containing elastomer

Assignee: Idemitsu Kosan Co Ltd
•
Filing: 1993-04-09
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Granted: 1995-02-14
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Expires: 2013-04-09
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Abstract

Abstract PCT No. PCT/JP93/00456 Sec. 371 Date Nov. 8, 1993 Sec. 102(e) Date Nov. 8, 1993 PCT Filed Apr. 9, 1993 PCT Pub. No. WO93/21272 PCT Pub. Date Oct. 28, 1993.The thermoplastic resin composition containing a fluorine-containing elastomer, which is produced by incorporating a base-treated fluorine-containing elastomer into a thermoplastic resin and has a base-treated fluorine-containing elastomer content of 0.1 to 50% by weight, the composition being excellent in impact resistance and heat resistance and useful for producing various products in the fields of aviation, machinery, office machines, electricity and electronics.

Inventors

  • 👤 Toru Bando

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 15:07
CPC Classifications
C; C08; C08L; C08L69/00; C08L27/00; C08L27/02; C08L27/12; C08L67/00; C08L67/02; C08L67/03; C08L71/00; C08L79/00; C08L79/04; C08L79/08; C08L81/00; C08L81/06

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 56 words
A thermoplastic resin composition which comprises (a) a base-treated fluorine-containing elastomer obtained by contacting a fluorine-containing elastomer with a basic compound in an inert atmosphere to form a carbon-carbon unsaturated bond in the fluorine-containing elastomer and (b) a thermoplastic resin, the content of the base-treated fluorine-containing elastomer in the composition being 0.1 to 50% by weight.
Claim 2
Dependent Claim 56 words
A thermoplastic resin composition which comprises (a) a base-treated fluorine-containing elastomer obtained by contacting a fluorine-containing elastomer with a basic compound in an inert atmosphere to form a carbon-carbon unsaturated bond in the fluorine-containing elastomer and (b) a thermoplastic resin, the content of the base-treated fluorine-containing elastomer in the composition being 0.1 to 50% by weight.
Claim 3
Dependent Claim 28 words
A composition according to claim 1, wherein the carbon-carbon unsaturated bond is contained in an amount of 1 to 5 per 100 recurring units constituting the fluorine-containing elastomer.
Claim 4
Dependent Claim 21 words
A composition according to claim 1, wherein the base-treated fluorine-containing elastomer has an average particle diameter of 0.05 to 0.25 μm.
Claim 5
Dependent Claim 21 words
A composition according to claim 1, wherein the fluorine-containing elastomer is a copolymer formed from monomers containing at least vinylidene fluoride.
Claim 6
Dependent Claim 39 words
A composition according to claim 4, wherein the copolymer is formed from vinylidene fluoride and another fluorine containing olefin selected from the group consisting of hexafluoropropylene, pentafluororopylene, trifluoroethylene, trifluorochloroethylene, tetrafluoroethylene, vinyl fluoride, perfluoromethyl vinyl ether and perfluoropropyl vinyl ether.
Claim 7
Dependent Claim 91 words
A composition according to claim 4, wherein the copolymer is selected from the group consisting of (a) a copolymer formed from vinylidene fluoride and another fluorine-containing olefin, and (b) a block copolymer containing said copolymer (a) as a soft segment and any of the following (i), (ii) and (iii) as a hard segment: (i) a homopolymer of tetrafluoroethylene, or a copolymer formed from tetrafluoroethylene and another fluorine-containing monomer, (ii) a homopolymer of tetrafluoroethylene, or (iii) a homopolymer of vinylidene fluoride, or a copolymer formed from vinylidene fluoride and another fluorine-containing monomer.
Claim 8
Dependent Claim 73 words
A composition according to claim 4, wherein the copolymer is a block copolymer containing (a) a copolymer formed from vinylidene fluoride and another fluorine containing olefin selected from the group consisting of hexafluoropropylene, pentafluoropropylene, trifluoroethylene, trifluorochloroethylene, tetrafluoroethylene, vinyl fluoride, perfluoromethyl vinyl ether and perfluoropropyl vinyl ether and (b) a homopolymer selected from the group consisting of (i) a homopolymer of tetrafluoroethylene, (ii) a homopolymer of trifluorochloroethylene and (iii) a homopolymer of vinylidene fluoride.
Claim 9
Dependent Claim 30 words
A composition according to claim 1, wherein the basic compound is selected from the group consisting of amines, amides, nitrogen-containing cyclic compounds, alkali metal hydroxides and alkaline earth metal hydroxides.
Claim 10
Dependent Claim 36 words
A composition according to claim 1, wherein the thermoplastic resin is at least one thermoplastic resin selected from the group consisting of polycarbonate, polyarylate, polyether sulfone, polysulfone, polyetherimide, polyether ether ketone, polyphenylene sulfide and polycyanoaryl ether.
Claim 11
Dependent Claim 22 words
A composition according to claim 1, wherein the composition is a melt-mixed product of the base-treated fluorine-containing elastomer and the thermoplastic resin.
Claim 12
Dependent Claim 37 words
A composition according to claim 1, wherein the composition is a product obtained by dissolving the base-treated fluorine-containing elastomer and the thermoplastic resin in a solvent to form a solution and removing the solvent from the solution.
Claim 13
Dependent Claim 53 words
A composition according to claim 1, wherein the composition is a product obtained by adding a fluorine-containing elastomer to a hot thermoplastic resin solution which is obtained during or after the thermoplastic resin is produced by solution polymerization in the presence of a basic compound and an inert atmosphere and carrying out mixing.
Claim 14
Dependent Claim 13 words
A composition according to claim 1, wherein the composition further contains a filler.
Claim 15
Dependent Claim 15 words
A composition according to claim 13, wherein the filler is an inorganic or organic filler.
Claim 16
Dependent Claim 49 words
A composition according to claim 1 wherein the basic compound is selected from the group consisting of n-propylamine, isopropylamine, n-butylamine, isobutylamine, dipropylamine, dibutylamine, triethylamine, tributylamine, N-methyl-2-pyrrolidone, dimethylacetamide, dimethylformamide, 1,3-dimethyl-2-imidazolidinone, N-methylcaprolactam; 1,8-diazabicyclo(4.3.0)-7-undecene, pyridine, piperidine, quinoline, indole, imidazole, potassium hydroxide, lithium hydroxide, sodium hydroxide, cesium hydroxide, magnesium hydroxide and calcium hydroxide.
Claim 17
Dependent Claim 22 words
A composition according to claim 15, wherein the base-treated fluorine containing elastomer has an average particle diameter of 0.07 to 0.20 μm.
Claim 18
Dependent Claim 36 words
A composition according to claim 16, wherein the thermoplastic resin is at least one thermoplastic resin selected from the group consisting of polycarbonate, polyarylate, polyether sulfone, polysulfone, polyetherimide, polyether ether ketone, polyphenylene sulfide and polycyanoaryl ether.
Claim 19
Dependent Claim 22 words
A composition according to claim 17, wherein the base-treated fluorine containing elastomer is in an amount of 0.5 to 30% by weight.
Claim 20
Dependent Claim 22 words
A composition according to claim 17, wherein the base-treated fluorine containing elastomer is in an amount of 1 to 20% by weight.

References Cited (Backward Citations)

US3400065A Cited
US3507844A Cited
US3821326A Cited
US4742126A Cited
US5039722A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-02-13 1998-08-15 1999-02-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-02-13 2002-08-15 2003-02-14 $3760.00 Window Closed / Lapsed
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