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US5389596A Expired / Lapsed US ⏱️ 0.0 years remaining

Dye mixtures for dye transfer

Assignee: BASF SE
•
Filing: 1993-05-10
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Granted: 1995-02-14
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Expires: 2013-05-10
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Abstract

Abstract Thermal transfer dye mixtures comprise at least one azo dye with a coupling component of the diaminopyridine series and at least one triazolopyridine, pyridone and/or 1-aminopyrid-2,6-dione dye.

Inventors

  • 👤 Karl-Heinz Etzbach
  • 👤 Gunther Lamm
  • 👤 Ruediger Sens

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 14:52
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/382; B41M5/385; B41M5/3858; C; C09; C09B; C09B67/00; C09B67/0033; C09B67/0041; B41M5/3854; B41M5/3856; B41M5/388; B41M5/39; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914; Y10S430/00; Y10S430/165

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 502 words
Dye mixtures comprising at least one azo dye of the formula I ##STR36## where R 1 , R 2 and R 3 are identical or different and each is independently of the others alkyl, alkoxyalkyl, alkanoyloxyalkyl, alkoxycarbonyloxyalkyl or alkoxycarbonylalkyl, each of which may have up to 20 carbon atoms and be phenyl-, C 1 -C 4 -alkylphenyl-, C 1 -C 4 -alkoxyphenyl-, halophenyl-, benzyloxy-, C 1 -C 4 -alkylbenzyloxy-, C 1 -C 4 -alkoxybenzyloxy, halobenzyloxy-, halogen-, hydroxyl- or cyano-substituted, hydrogen, unsubstituted or C 1 -C 4 -alkyl- or C 1 -C 4 -alkoxy-, halogen- or benzyloxy-substituted cyclohexyl or a radical of the formula [--E--O].sub.m --R.sup.5, where E is C 2 -C 6 -alkylene, M is 1, 2, 3, 4, 5 or 6, and R 5 is C 1 -C 4 -alkyl or unsubstituted or C 1 -C 4 -alkyl- or C 1 -C 4 -alkoxy-substituted phenyl, R 4 is C 1 -C 4 -alkyl, R 6 is cyano or carbamoyl, and D is the radical of a diazo component, and at least one dye of the formula II, III and/or IV ##STR37## where L 1 is C 1 -C 20 -alkyl, which may be substituted and may be interrupted by from 1 to 4 oxygen atoms in ether function, substituted or unsubstituted phenyl or hydroxyl, L 2 is a 5- or 6-membered carbocyclic or heterocyclic radical, L 3 is cyano, carbamoyl, carboxyl or C 1 -C 4 -alkoxy-carbonyl, L 4 is oxygen or a radical of the formula ##STR38## where Q 1 is in each case C 1 -C 8 -alkyl, which may be interrupted by 1 or 2 oxygen atoms in ether function, X is CH or nitrogen, L 5 is hydrogen or C 1 -C 4 -alkyl, L 6 and L 7 are identical or different and each is independently of the other hydrogen, substituted or unsubstituted C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl, substituted or unsubstituted phenyl, substituted or unsubstituted pyridyl, substituted or unsubstituted C 1 -C 12 -alkanoyl, C 1 -C 12 -alkoxycarbonyl, substituted or unsubstituted C 1 -C 12 -alkylsulfonyl, C 5 -C 7 -cycloalkylsulfonyl, substituted or unsubstituted phenylsulfonyl, substituted or unsubstituted pyridylsulfonyl, substituted or unsubstituted benzoyl, pyridylcarbonyl or thienylcarbonyl, or together with the nitrogen atom joining them together are unsubstituted or C 1 -C 4 -alkyl-substituted succinimido, unsubstituted or C 1 -C 4 -alkyl -substituted phthalimido or a five- or six-membered saturated heterocyclic radical, which may contain further hetero atoms, Y is cyano or a radical of the formula CO--Q 2 , CO--OQ 2 or CO--NHQ 2 , where Q 2 is hydrogen, C 1 -C 8 -alkyl, which may be substituted and may be interrupted by 1 or 2 oxygen atoms in ether function, C 5 -C 7 -cycloalkyl, phenyl or tolyl, the dye mixture containing from 10 to 90% by weight of the dye mixture of dye of formula I and 90 to 10% by weight of the dye mixture of one or dyes of the formulas II, III and/or IV.
Claim 2
Dependent Claim 502 words
Dye mixtures comprising at least one azo dye of the formula I ##STR36## where R 1 , R 2 and R 3 are identical or different and each is independently of the others alkyl, alkoxyalkyl, alkanoyloxyalkyl, alkoxycarbonyloxyalkyl or alkoxycarbonylalkyl, each of which may have up to 20 carbon atoms and be phenyl-, C 1 -C 4 -alkylphenyl-, C 1 -C 4 -alkoxyphenyl-, halophenyl-, benzyloxy-, C 1 -C 4 -alkylbenzyloxy-, C 1 -C 4 -alkoxybenzyloxy, halobenzyloxy-, halogen-, hydroxyl- or cyano-substituted, hydrogen, unsubstituted or C 1 -C 4 -alkyl- or C 1 -C 4 -alkoxy-, halogen- or benzyloxy-substituted cyclohexyl or a radical of the formula [--E--O].sub.m --R.sup.5, where E is C 2 -C 6 -alkylene, M is 1, 2, 3, 4, 5 or 6, and R 5 is C 1 -C 4 -alkyl or unsubstituted or C 1 -C 4 -alkyl- or C 1 -C 4 -alkoxy-substituted phenyl, R 4 is C 1 -C 4 -alkyl, R 6 is cyano or carbamoyl, and D is the radical of a diazo component, and at least one dye of the formula II, III and/or IV ##STR37## where L 1 is C 1 -C 20 -alkyl, which may be substituted and may be interrupted by from 1 to 4 oxygen atoms in ether function, substituted or unsubstituted phenyl or hydroxyl, L 2 is a 5- or 6-membered carbocyclic or heterocyclic radical, L 3 is cyano, carbamoyl, carboxyl or C 1 -C 4 -alkoxy-carbonyl, L 4 is oxygen or a radical of the formula ##STR38## where Q 1 is in each case C 1 -C 8 -alkyl, which may be interrupted by 1 or 2 oxygen atoms in ether function, X is CH or nitrogen, L 5 is hydrogen or C 1 -C 4 -alkyl, L 6 and L 7 are identical or different and each is independently of the other hydrogen, substituted or unsubstituted C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl, substituted or unsubstituted phenyl, substituted or unsubstituted pyridyl, substituted or unsubstituted C 1 -C 12 -alkanoyl, C 1 -C 12 -alkoxycarbonyl, substituted or unsubstituted C 1 -C 12 -alkylsulfonyl, C 5 -C 7 -cycloalkylsulfonyl, substituted or unsubstituted phenylsulfonyl, substituted or unsubstituted pyridylsulfonyl, substituted or unsubstituted benzoyl, pyridylcarbonyl or thienylcarbonyl, or together with the nitrogen atom joining them together are unsubstituted or C 1 -C 4 -alkyl-substituted succinimido, unsubstituted or C 1 -C 4 -alkyl -substituted phthalimido or a five- or six-membered saturated heterocyclic radical, which may contain further hetero atoms, Y is cyano or a radical of the formula CO--Q 2 , CO--OQ 2 or CO--NHQ 2 , where Q 2 is hydrogen, C 1 -C 8 -alkyl, which may be substituted and may be interrupted by 1 or 2 oxygen atoms in ether function, C 5 -C 7 -cycloalkyl, phenyl or tolyl, the dye mixture containing from 10 to 90% by weight of the dye mixture of dye of formula I and 90 to 10% by weight of the dye mixture of one or dyes of the formulas II, III and/or IV.
Claim 3
Dependent Claim 22 words
Dye mixtures as claimed in claim 1 comprising an azo dye of the formula I and a dye of the formula II.
Claim 4
Dependent Claim 22 words
Dye mixtures as claimed in claim 1 comprising an azo dye of the formula I and a dye of the formula III.
Claim 5
Dependent Claim 22 words
Dye mixtures as claimed in claim 1 comprising an azo dye of the formula I and a dye of the formula IV.
Claim 6
Dependent Claim 60 words
Dye mixtures as claimed in claim 1 comprising from 10 to 90% by weight, based on the weight of the dye mixture, of one or more azo dyes of the formula I and also from 10 to 90% by weight, based on the weight of the dye mixture, of one or more dyes of the formula II, III and/or IV.
Claim 7
Dependent Claim 39 words
A process for transferring dyes from a transfer to plastic-coated paper by diffusion or sublimation by means of an energy source, which comprises applying an energy source to the transfer containing a dye mixture as claimed in claim 1.

References Cited (Backward Citations)

US4939118A Cited
EP0399473B1 Cited
US5079365A Cited
EP0441282A1 Cited
WO1992000505A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-02-13 1998-08-15 1999-02-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-02-13 2002-08-15 2003-02-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-02-13 2006-08-15 2007-02-14 $7700.00 Window Closed / Lapsed

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