Electrically conductive alternating copolymer and method of preparing such a copolymer

Claim 2

A (semi)conductive copolymer of alternating donor and acceptor monomer units, characterized in that the (semi)conductive copolymer is obtained by reacting an acceptor monomer unit A having an unsaturated ring structure which is substituted with at least two double-bonded oxygen atoms and at least one hydroxy group, with a donor monomer unit D formed by a homo or heterocyclic aromatic compound comprising at least two active hydrogen atoms, a polycondensation reaction taking place in the presence of a solvent, thereby forming said alternating (semi)conductive copolymer substantially free of doping, with the proviso that said monomer unit A is selected from the group consisting of croconic acid and 5,6-dihydroxy-5-cyclohexene-1,2,3,4-tetraone when said monomer unit D is p-phenylenediamine.

Claim 3

An alternating copolymer as claimed in claim 1, characterized in that the monomer unit A is selected from the group consisting of squaric acid, croconic acid and 5,6-dihydroxy-5-cyclohexene-1,2,3,4-tetraone.

Claim 4

A method of preparing an alternating copolymer as claimed in claim 2, wherein equimolor quantities of bifunctional acceptor monomer units A and bifunctional donor monomer units D are mixed in a solvent and polymerized by polycondensation, thereby forming the alternating copolymer comprising repeating unit AD.

Claim 5

An alternating copolymer as claimed in claim 1, characterized in that the monomer unit D is selected from the group consisting of ##STR2## where: X 1 =--NR-- and X 2 =O, S, Se, --NR--, --CR═CH--, --CHR--CH 2 -- or --C(alkyl) 2 --, where the alkyl group contains 1-8 C-atoms and X 3 =--CR═ or --N═, where R is and H-atom or a C 1 -C 18 alkyl or alkoxy group; or X 1 =S or O and X 2 = or --CR═CH-- and X 3 =--CR═ or --N═, where R has the above-mentioned meaning.

Claim 6

A method of preparing an alternating copolymer as claimed in claim 4, wherein equimolor quantities of bifunctional acceptor monomer units A and bifunctional donor monomer units D are mixed in a solvent and polymerized by polycondensation, thereby forming the alternating copolymer comprising repeating unit AD.

Claim 7

An alternating copolymer as claimed in claim 4, characterized in that the monomer unit D is selected from the group consisting of ##STR3##

Claim 8

A method of preparing an alternating copolymer as claimed in claim 3, wherein equimolor quantities of bifunctional acceptor monomer units A and bifunctional donor monomer units D are mixed in a solvent and polymerized by polycondensation, thereby forming the alternating copolymer comprising repeating unit AD.

Claim 9

An alternating copolymer as claimed in claim 6, characterized in that the monomer unit A is croconic acid and the monomer unit D corresponds to formula VII, where R 3 represents a methyl group and R 4 represents a dodecyl group.

Claim 10

A method of preparing an alternating copolymer as claimed in claim 8, wherein equimolor quantities of bifunctional acceptor monomer units A and bifunctional donor monomer units D are mixed in a solvent and polymerized by polycondensation, thereby forming the alternating copolymer comprising repeating unit AD.

Claim 11

An alternating copolymer as claimed in claim 1, characterized in that the monomer unit A is selected from the group consisting of croconic acid and 5,6-dihydroxy-5-cyclohexene-1,2,3,4-tetraone and the monomer unit D is an aromatic diamine of the general formula ##STR4## where R 6 and R 7 represent an H-atom or a C 1 -C 18 alkyl group and A is an aromatic core selected from the group consisting of ##STR5## where R 8 and R 9 represent an H-atom or a C 1 -C 18 alkyl group and X 1 =--N═ or --CR═, where R represents an H-atom or a C 1 -C 18 alkyl or alkoxy group, and X 2 =S, O, Se, --NH-- or --N(alkyl)--, where the alkyl group contains 1-18 C-atoms.

Claim 12

A method of preparing an alternating copolymer as claimed in claim 10, wherein equimolor quantities of bifunctional acceptor monomer units A and bifunctional donor monomer units D are mixed in a solvent and polymerized by polycondensation, thereby forming the alternating copolymer comprising repeating unit AD.

Claim 13

An alternating copolymer as claimed in claim 10, characterized in that the monomer unit D is selected from the group consisting of p-phenylenediamine, thionine and 3,6-diamino acridine.

Claim 14

A method of preparing an alternating copolymer as claimed in claim 12, wherein equimolor quantities of bifunctional acceptor monomer units A and bifunctional donor monomer units D are mixed in a solvent and polymerized by polycondensation, thereby forming the alternating copolymer comprising repeating unit AD.

Claim 15

An electronic circuit which comprises an alternating copolymer as claimed in claim 1.

Claim 16

An electronic circuit as claimed in claim 14 in which said copolymer is present as a semiconductor element.

Claim 17

An antistatic layer which comprises an alternating copolymer as claimed in claim 1.

Claim 18

An electromagnetic protective layer which comprises an alternating copolymer as claimed in claim 1.

Claim 19

An alternating copolymer as claimed in claim 1, wherein the monomer unit A is squaric acid and the monomer unit D is an aromatic diamine of the general formula ##STR6## where R 6 and R 7 represent a C 1 -C 18 alkyl group and Ar is an aromatic core selected from the group consisting of ##STR7## where R 8 and R 9 represent an H-atom or a C 1 -C 18 alkyl group and X 1 =--N═ or --CR═, where R represents an H-atom or a C 1 -C 18 alkyl or alkoxy group, and X 2 =S, O, Se, --NH-- or --N (alkyl)--, where the alkyl group contains 1-18 C-atoms.

Claim 20

A method of preparing an alternating copolymer as claimed in claim 18 wherein equimolor quantities of bifunctional acceptor monomer units A and bifunctional donor monomer units D are mixed in a solvent and polymerized by polycondensation, thereby forming the alternating copolymer comprising repeating unit AD.

Claim 21

An alternating copolymer as claimed in claim 18, characterized in that the monomer unit D is selected from the group consisting of thionine and 3,6-diamino acridine.

Claim 22

A method of preparing an alternating copolymer as claimed in claim 20 wherein equimolor quantities of bifunctional acceptor monomer units A and bifunctional donor monomer units D are mixed in a solvent and polymerized by polycondensation, thereby forming the alternating copolymer comprising repeating unit AD.

Claim 23

A method of preparing an alternating copolymer as claimed in claim 1, in which equimolar quantities of bifunctional acceptor monomer units A and bifunctional donor monomer units D are mixed in a solvent and polymerized by polycondensation, thereby forming the alternating copolymer comprising repeating unit AD.

Claim 24

A (semi)conductive copolymer of alternating donor and acceptor monomer units, characterized in that the (semi)conductive copolymer is obtained by reacting an acceptor monomer unit A selected from the group consisting of squaric acid, croconic acid and 5,6-dihydroxy-5-cyclohexene-1,2,3,4-tetraone with a donor monomer unit D selected from the group consisting of ##STR8## where: X 1 =--NR-- and X 2 =O, S, Se, --NR--, --CR═CH--, --CHR--CH 2 -- or --C(alkyl) 2 --, where the alkyl group contains 1-18 C-atoms and X 3 =--CR═ or --N═, where R is an H-atom or a C 1 -C 18 alkyl or alkoxy group; or X 1 =S or O and X 2 = or --CR═CH-- and X 3 =--CR═ or --N═, where R has the above-mentioned meaning, a polycondensation reaction taking place in the presence of a solvent, thereby forming said alternating (semi)conductive copolymer substantially free of doping.

Claim 25

A (semi)conductive copolymer of alternating donor and acceptor monomer units, characterized in that the (semi)conductive copolymer is obtained by reacting an acceptor monomer unit A selected from the group consisting of squaric acid, croconic acid and 5,6-dihydroxy-5-cyclohexene-1,2,3,4-tetraone with a donor monomer unit D selected from the group consisting of ##STR8## where: X 1 =--NR-- and X 2 =O, S, Se, --NR--, --CR═CH--, --CHR--CH 2 -- or --C(alkyl) 2 --, where the alkyl group contains 1-18 C-atoms and X 3 =--CR═ or --N═, where R is an H-atom or a C 1 -C 18 alkyl or alkoxy group; or X 1 =S or O and X 2 = or --CR═CH-- and X 3 =--CR═ or --N═, where R has the above-mentioned meaning, a polycondensation reaction taking place in the presence of a solvent, thereby forming said alternating (semi)conductive copolymer substantially free of doping.

Claim 26

A method of preparing an alternating copolymer as claimed in claim 23 wherein equimolor quantities of bifunctional acceptor monomer units A and bifunctional donor monomer units D are mixed in a solvent and polymerized by polycondensation, thereby forming the alternating copolymer comprising repeating unit AD.

Claim 27

A (semi)conductive copolymer of alternating donor and acceptor monomer units, characterized in that the (semi)conductive copolymer is obtained by reacting an acceptor monomer unit A selected from the group of squaric acid, croconic acid and 5,6-dihydroxy-5-cyclohexene-1,2,3,4-tetraone with a donor monomer unit D selected from an aromatic diamine of the general formula ##STR9## where R 6 and R 7 represent an H-atom or a C 1 -C 18 alkyl group and Ar is an aromatic core selected from the group consisting of ##STR10## where R 8 and R 9 represent an H-atom or a C 1 -C 18 alkyl group and X 1 =--N═ or --CR═, where R represents an H-atom or a C 1 -C 18 alkyl or alkoxy group, and X 2 =S, O, Se, --NH-- or --N (alkyl)--, where the alkyl group contains 1-18 C-atoms, with the proviso that said monomer unit A is selected from the group consisting of croconic acid and 5,6-dihydroxy-5-cyclohexene-1,2,3,4-tetratone when said monomer unit D is p-phenylenediamine, a polycondensation reaction taking place in the presence of a solvent, thereby forming said alternating (semi)conductive copolymer substantially free of doping.

Claim 28

A (semi)conductive copolymer of alternating donor and acceptor monomer units, characterized in that the (semi)conductive copolymer is obtained by reacting an acceptor monomer unit A selected from the group of squaric acid, croconic acid and 5,6-dihydroxy-5-cyclohexene-1,2,3,4-tetraone with a donor monomer unit D selected from an aromatic diamine of the general formula ##STR9## where R 6 and R 7 represent an H-atom or a C 1 -C 18 alkyl group and Ar is an aromatic core selected from the group consisting of ##STR10## where R 8 and R 9 represent an H-atom or a C 1 -C 18 alkyl group and X 1 =--N═ or --CR═, where R represents an H-atom or a C 1 -C 18 alkyl or alkoxy group, and X 2 =S, O, Se, --NH-- or --N (alkyl)--, where the alkyl group contains 1-18 C-atoms, with the proviso that said monomer unit A is selected from the group consisting of croconic acid and 5,6-dihydroxy-5-cyclohexene-1,2,3,4-tetratone when said monomer unit D is p-phenylenediamine, a polycondensation reaction taking place in the presence of a solvent, thereby forming said alternating (semi)conductive copolymer substantially free of doping.

Claim 29

A method of preparing an alternating copolymer as claimed in claim 25 wherein equimolor quantities of bifunctional acceptor monomer units A and bifunctional donor monomer units D are mixed in a solvent and polymerized by polycondensation, thereby forming the alternating copolymer comprising repeating unit AD.

Claim 30

An alternating copolymer as claimed in claim 25 wherein the monomer unit D is selected from the group consisting of p-phenylenediamine, thionine and 3,6-diamino acridine.

Claim 31

A method of preparing an alternating copolymer as claimed in claim 27 wherein equimolor quantities of bifunctional acceptor monomer units A and bifunctional donor monomer units D are mixed in a solvent and polymerized by polycondensation, thereby forming the alternating copolymer comprising repeating unit AD.