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US5380584A Expired / Lapsed US ⏱️ 0.0 years remaining

Imaging element for use in electrostatography

Assignee: Eastman Kodak Co
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Filing: 1993-05-21
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Granted: 1995-01-10
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Expires: 2013-05-21
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Abstract

Abstract An electroconductive imaging element, that is especially useful in a high speed laser printing process utilizing electrostatography, is comprised of an insulating support, an electrically-conductive layer overlying the support and a thermoplastic dielectric imaging layer overlying the electrically-conductive layer. The electrically-conductive layer, which is comprised of at least 3 milligrams per square meter of a colloidal gel of vanadium pentoxide dispersed in a polymeric binder combines a high degree of transparency with a high degree of electrical conductivity. The thermoplastic dielectric imaging layer has a thickness of at least 0.2 micrometers and a surface resistivity of at least 10 13 ohms/square and is comprised of a thermoplastic polymer with a glass transition temperature of at least 20° C.

Inventors

  • 👤 Charles C. Anderson
  • 👤 David F. Jennings
  • 👤 Gerald M. Leszyk
  • 👤 David A. Niemeyer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 14:59
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/398; G; G03; G03F; G03F7/00; G03F7/20; G03F7/2002; G03F7/2014; G03F7/2016; G03F7/2018; G03G; G03G5/00; G03G5/10; G03G5/104; Y; Y10; Y10S; Y10S430/00; Y10S430/001; Y10S430/104; Y10T; Y10T428/00; Y10T428/25; Y10T428/31504; Y10T428/31786

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 262 words
An electroconductive imaging element especially adapted for use in a high speed laser printing process which produces an image-bearing element suitable for use as a master in a UV-imaging process, said laser printing process comprising the steps of: (1) toner deposition in which a uniform layer of toner particles is deposited on the surface of said electroconductive imaging element, (2) partial fusion in which said toner particles are adhered to said electroconductive imaging element in an imagewise manner by laser exposure; (3) differential cleaning in which unfused toner particles are removed from the non-imaged areas of said electroconductive imaging element; and (4) final fusion in which toner particles in the image areas are permanently fused to said electroconductive imaging element; said electroconductive imaging element comprising: (a) an insulating support; (b) an electrically-conductive layer overlying said support, which is comprised of a colloidal gel of vanadium pentoxide dispersed in a polymeric binder, said vanadium pentoxide being present in said electrically-conductive layer in an amount of at least 3 milligrams per square meter and said electrically-conductive layer having a surface resistivity of 10 7 ohms/square or less, an internal resistivity of 10 7 ohms/square or less, a UV D min of less than 0.1 and a visible D min of less than 0.05; and (c) a thermoplastic dielectric imaging layer having a thickness of at least 0.2 micrometers overlying said electrically-conductive layer, said thermoplastic dielectric imaging layer having a surface resistivity of at least 10 13 ohms/square and being comprised of a thermoplastic polymer with a glass transition temperature of at least 20° C.
Claim 2
Dependent Claim 262 words
An electroconductive imaging element especially adapted for use in a high speed laser printing process which produces an image-bearing element suitable for use as a master in a UV-imaging process, said laser printing process comprising the steps of: (1) toner deposition in which a uniform layer of toner particles is deposited on the surface of said electroconductive imaging element, (2) partial fusion in which said toner particles are adhered to said electroconductive imaging element in an imagewise manner by laser exposure; (3) differential cleaning in which unfused toner particles are removed from the non-imaged areas of said electroconductive imaging element; and (4) final fusion in which toner particles in the image areas are permanently fused to said electroconductive imaging element; said electroconductive imaging element comprising: (a) an insulating support; (b) an electrically-conductive layer overlying said support, which is comprised of a colloidal gel of vanadium pentoxide dispersed in a polymeric binder, said vanadium pentoxide being present in said electrically-conductive layer in an amount of at least 3 milligrams per square meter and said electrically-conductive layer having a surface resistivity of 10 7 ohms/square or less, an internal resistivity of 10 7 ohms/square or less, a UV D min of less than 0.1 and a visible D min of less than 0.05; and (c) a thermoplastic dielectric imaging layer having a thickness of at least 0.2 micrometers overlying said electrically-conductive layer, said thermoplastic dielectric imaging layer having a surface resistivity of at least 10 13 ohms/square and being comprised of a thermoplastic polymer with a glass transition temperature of at least 20° C.
Claim 3
Dependent Claim 31 words
An electroconductive imaging element as claimed in claim 1, wherein said vanadium pentoxide is present in said electrically-conductive layer in an amount of from 4 to 20 milligrams per square meter.
Claim 4
Dependent Claim 31 words
An electroconductive imaging element as claimed in claim 1, wherein said vanadium pentoxide is present in said electrically-conductive layer in an amount of from 4 to 12 milligrams per square meter.
Claim 5
Dependent Claim 23 words
An electroconductive imaging element as claimed in claim 1, wherein said thermoplastic dielectric imaging layer has a thickness of at least one micrometer.
Claim 6
Dependent Claim 23 words
An electroconductive imaging element as claimed in claim 1, wherein said thermoplastic polymer has a glass transition temperature of at least 30° C.
Claim 7
Dependent Claim 33 words
An electroconductive imaging element as claimed in claim 1, wherein said electrically-conductive layer has a surface resistivity of 5×10 6 ohms/square or less and an internal resistivity of 5×10 6 ohms/square or less.
Claim 8
Dependent Claim 17 words
An electroconductive imaging element as claimed in claim 1, wherein said insulting support is a polyester film.
Claim 9
Dependent Claim 23 words
An electroconductive imaging element as claimed in claim 1, wherein said insulting support is a film composed of poly(ethylene terephthalate) or poly(ethylene naphthalate).
Claim 10
Dependent Claim 17 words
An electroconductive imaging element as claimed in claim 1, wherein said vanadium pentoxide is doped with silver.
Claim 11
Dependent Claim 31 words
An electroconductive imaging element as claimed in claim 1, wherein the weight ratio of polymer to vanadium pentoxide in said electrically-conductive layer is in the range of from 1:1 to 10:1.
Claim 12
Dependent Claim 23 words
An electroconductive imaging element as claimed in claim 1, wherein said polymer in said electrically-conductive layer is a vinylidene chloride/methyl acrylate/itaconic acid terpolymer.
Claim 13
Dependent Claim 22 words
An electroconductive imaging element as claimed in claim 1, wherein said polymer in said electrically-conductive layer is a vinylidene chloride/acrylonitrile/methacrylic acid terpolymer.
Claim 14
Dependent Claim 22 words
An electroconductive imaging element as claimed in claim 1, wherein said polymer in said electrically-conductive layer is an aqueous dispersible polyester ionomer.
Claim 15
Dependent Claim 25 words
An electroconductive imaging element as claimed in claim 1, wherein said polymer in said thermoplastic dielectric imaging layer is a methyl acrylate/vinylidene chloride/itaconic acid terpolymer.
Claim 16
Dependent Claim 21 words
An electroconductive imaging element as claimed in claim 1, wherein said polymer in said thermoplastic dielectric imaging layer is a polyurethane.
Claim 17
Dependent Claim 24 words
An electroconductive imaging element as claimed in claim 1, wherein said polymer in said thermoplastic dielectric imaging layer is an aqueous dispersible polyester ionomer.

References Cited (Backward Citations)

US4919757A Cited
US5194356A Cited
US5296898A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-01-09 1998-07-11 1999-01-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-01-09 2002-07-11 2003-01-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-01-09 2006-07-11 2007-01-10 $7700.00 Window Closed / Lapsed

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