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US5378298A Expired / Lapsed US ⏱️ 0.0 years remaining

Radiation sensitive adhesive composition and method of photoimagingsame

Assignee: Samsung Electronics Co Ltd
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Filing: 1993-06-01
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Granted: 1995-01-03
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Expires: 2013-06-01
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Abstract

Abstract A method of photodelineating an adhesive on a substrate. The first step (10) is to coat the substrate with a layer of photopolymeric adhesive, typically spin coated. The adhesive is then briefly 'soft baked' at a moderate temperature to set it (20). Portions of the adhesive are then selectively exposed to actinic radiation to partially cure them, while other portions are not exposed (30). A photomask is used to selectively expose the photopolymeric adhesive to ultraviolet light at an intensity and for a time sufficient to partially cure the photopolymeric adhesive. The adhesive is developed (40) to selectively remove those portions that were not exposed to radiation, usually in an appropriate solvent, creating a pattern in the adhesive. The developed adhesive pattern is then heated for a time and temperature sufficient to completely cure it (50).

Inventors

  • 👤 Melanie Williams
  • 👤 Thomas J. Swirbel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 16:58
CPC Classifications
H; H05; H05K; H05K3/00; H05K3/30; H05K3/303; H05K3/305; G; G03; G03F; G03F7/00; G03F7/0012; G02; G02F; G02F1/00; G02F1/01; G02F1/13; G02F1/133; G02F1/1333; G02F1/1339; G02F1/13394; H05K2203/00; H05K2203/05; H05K2203/0502; H05K2203/0514; H05K3/32; H05K3/321; Y; Y02; Y02P; Y02P70/00; Y02P70/50

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 67 words
A method of photodelineating an adhesive, comprising the steps of: coating a substrate with a layer of photopolymeric adhesive; soft baking the photopolymeric adhesive; selectively exposing only portions of the adhesive to actinic radiation to partially cure said portions; developing the adhesive to selectively remove those portions that were not exposed, thereby creating a pattern in the adhesive; and heating the developed adhesive to completely cure it.
Claim 2
Independent Claim 67 words
A method of photodelineating an adhesive, comprising the steps of: coating a substrate with a layer of photopolymeric adhesive; soft baking the photopolymeric adhesive; selectively exposing only portions of the adhesive to actinic radiation to partially cure said portions; developing the adhesive to selectively remove those portions that were not exposed, thereby creating a pattern in the adhesive; and heating the developed adhesive to completely cure it.
Claim 3
Dependent Claim 37 words
The method as described in claim 1, wherein the step of soft baking comprises heating the photopolymeric adhesive at a temperature between about 40° C. and about 85° C. for between about 1 and about 15 minutes.
Claim 4
Independent Claim 89 words
A method of photodelineating an adhesive, comprising the steps off: coating a substrate with a layer of photopolymeric adhesive; treating the layer of photopolymeric adhesive so as to partially cure the layer; selectively exposing only portions of the partially cured layer of photopolymeric adhesive to actinic radiation to further cure said portions; developing the layer of photopolymeric adhesive to remove those portions that were not selectively exposed to actinic radiation, thereby creating a pattern in the layer of photopolymeric adhesive; and fully curing the developed layer of photopolymeric adhesive.
Claim 5
Independent Claim 89 words
A method of photodelineating an adhesive, comprising the steps off: coating a substrate with a layer of photopolymeric adhesive; treating the layer of photopolymeric adhesive so as to partially cure the layer; selectively exposing only portions of the partially cured layer of photopolymeric adhesive to actinic radiation to further cure said portions; developing the layer of photopolymeric adhesive to remove those portions that were not selectively exposed to actinic radiation, thereby creating a pattern in the layer of photopolymeric adhesive; and fully curing the developed layer of photopolymeric adhesive.
Claim 6
Dependent Claim 15 words
The method as described in claim 1, wherein the photopolymeric adhesive is not a photoresist.
Claim 7
Independent Claim 108 words
A method of depositing an adhesive in a selected pattern, comprising the steps of: spin coating a layer of a photopolymeric adhesive on a substrate; soft baking the photopolymeric adhesive; temporarily applying a photomask over the photopolymeric adhesive; selectively exposing the photopolymeric adhesive to ultraviolet light through the photomask, in a manner and for a time sufficient to partially cure the photopolymeric adhesive; developing the selectively exposed adhesive in a suitable solvent to remove the adhesive that was not selectively exposed, thereby creating a pattern in the adhesive; and further curing the adhesive pattern by heating it for a time and temperature sufficient to fully cure the adhesive.
Claim 8
Independent Claim 108 words
A method of depositing an adhesive in a selected pattern, comprising the steps of: spin coating a layer of a photopolymeric adhesive on a substrate; soft baking the photopolymeric adhesive; temporarily applying a photomask over the photopolymeric adhesive; selectively exposing the photopolymeric adhesive to ultraviolet light through the photomask, in a manner and for a time sufficient to partially cure the photopolymeric adhesive; developing the selectively exposed adhesive in a suitable solvent to remove the adhesive that was not selectively exposed, thereby creating a pattern in the adhesive; and further curing the adhesive pattern by heating it for a time and temperature sufficient to fully cure the adhesive.
Claim 9
Independent Claim 145 words
A method of depositing an adhesive in a selected pattern, comprising the steps of: spin coating a layer of a photopolymeric adhesive on a first substrate; soft baking the layer of photopolymeric adhesive; temporarily applying a photomask over the layer of photopolymeric adhesive; exposing portions of the layer of photopolymeric adhesive to ultraviolet light through the photomask, in a manner and for a time sufficient to partially cure the exposed portions of photopolymeric adhesive; developing the layer of photopolymeric adhesive in a suitable solvent to remove the photopolymeric adhesive that was not exposed to ultraviolet light, thereby creating a pattern in the adhesive; adding a second substrate on the developed layer of photopolymeric adhesive; further curing the developed layer of photopolymeric adhesive by heating it for a time and temperature sufficient to fully cure it and adhesively bond the second substrate to the first substrate.
Claim 10
Independent Claim 145 words
A method of depositing an adhesive in a selected pattern, comprising the steps of: spin coating a layer of a photopolymeric adhesive on a first substrate; soft baking the layer of photopolymeric adhesive; temporarily applying a photomask over the layer of photopolymeric adhesive; exposing portions of the layer of photopolymeric adhesive to ultraviolet light through the photomask, in a manner and for a time sufficient to partially cure the exposed portions of photopolymeric adhesive; developing the layer of photopolymeric adhesive in a suitable solvent to remove the photopolymeric adhesive that was not exposed to ultraviolet light, thereby creating a pattern in the adhesive; adding a second substrate on the developed layer of photopolymeric adhesive; further curing the developed layer of photopolymeric adhesive by heating it for a time and temperature sufficient to fully cure it and adhesively bond the second substrate to the first substrate.
Claim 11
Independent Claim 189 words
A method of depositing an adhesive in a selected pattern, comprising the following steps in the order named: A) spin coating a layer of a UV curable adhesive on a substrate; B) heating the UV curable adhesive at a temperature between about 40° C. and about 85° C. for between about 1 and about 15 minutes; C) temporarily masking portions of the UV curable adhesive with an opaque material, while leaving other portions exposed; D) selectively exposing the UV curable adhesive to ultraviolet light through the mask, in a manner and for a time sufficient to partially cure the exposed portions of the UV curable adhesive, thereby reacting the adhesive to a B-Stage; E) developing the UV curable adhesive in a suitable solvent to remove the portions that were not selectively exposed, thereby creating a pattern in the UV curable adhesive; F) adding another substrate on the developed UV curable adhesive; and G) further curing the B-Stage adhesive pattern by heating it for a time and temperature sufficient to full cure the adhesive, converting it from B-Stage to C-Stage, and adhesively bonding the second substrate to the first substrate.
Claim 12
Independent Claim 189 words
A method of depositing an adhesive in a selected pattern, comprising the following steps in the order named: A) spin coating a layer of a UV curable adhesive on a substrate; B) heating the UV curable adhesive at a temperature between about 40° C. and about 85° C. for between about 1 and about 15 minutes; C) temporarily masking portions of the UV curable adhesive with an opaque material, while leaving other portions exposed; D) selectively exposing the UV curable adhesive to ultraviolet light through the mask, in a manner and for a time sufficient to partially cure the exposed portions of the UV curable adhesive, thereby reacting the adhesive to a B-Stage; E) developing the UV curable adhesive in a suitable solvent to remove the portions that were not selectively exposed, thereby creating a pattern in the UV curable adhesive; F) adding another substrate on the developed UV curable adhesive; and G) further curing the B-Stage adhesive pattern by heating it for a time and temperature sufficient to full cure the adhesive, converting it from B-Stage to C-Stage, and adhesively bonding the second substrate to the first substrate.
Claim 13
Dependent Claim 16 words
The method as described in claim 7, wherein the UV curable adhesive is an acrylic adhesive.
Claim 14
Dependent Claim 15 words
The method as described in claim 7, wherein step (B) comprises heating at 55° C.
Claim 15
Dependent Claim 25 words
The method as described in claim 7, wherein step (D) comprises exposing the adhesive to between about 500 and about 2000 millijoules of ultraviolet light.
Claim 16
Dependent Claim 17 words
The method as described in claim 7, wherein the suitable solvent in step (E) comprises n-butyl acetate.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-01-02 1998-07-04 1999-01-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-01-02 2002-07-04 2003-01-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-01-02 2006-07-04 2007-01-03 $7700.00 Window Closed / Lapsed

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