Patent US5368922A successfully refreshed from Google Patents.
US5368922A
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Prepreg of thermoplastic polymer particles in liquid thermosettable resin
Assignee: 3M Co
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Filing: 1993-11-04
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Granted: 1994-11-29
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Expires: 2013-11-04
Abstract
Abstract A thermosettable resin composition having a viscosity that decreases during processing temperatures and increases as the temperature is raised to curing temperatures is provided. The composition comprises thermosettable resins and thermoplastic particles that are insoluble in the thermosettable resins at processing temperatures but soluble in the thermosettable resins at curing temperatures. Prepregs prepared from the thermosettable resin composition are also provided.
Inventors
- 👤 Gene B. Portelli
- 👤 William J. Schultz
- 👤 John T. Boden
- 👤 Daniel M. Kaufer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 01:31
CPC Classifications
C; C08; C08L; C08L63/00; C08J; C08J5/00; C08J5/24; C08J5/241; C08J5/243; C08J5/249; C08K; C08K5/00; C08K5/0008; C08K5/0016; C08K5/0025; C08L101/00; C08L2312/00; H; H05; H05K; H05K1/00; H05K1/02; H05K1/03; H05K1/0313; H05K1/0353; H05K1/0373; H05K3/00; H05K3/22; H05K3/28; H05K3/285; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507; Y10T428/31511; Y10T428/31525; Y10T428/31529; Y10T428/31551; Y10T428/31565; Y10T428/31573; Y10T428/31598; Y10T428/31605; Y10T428/31678; Y10T428/31681; Y10T428/31721; Y10T428/31725; Y10T428/31736; Y10T428/31739; Y10T428/31743; Y10T428/31786; Y10T428/31797; Y10T428/31855; Y10T442/00; Y10T442/20; Y10T442/2631; Y10T442/2656; Y10T442/2738; Y10T442/2861; Y10T442/2893; Y10T442/2926; Y10T442/2951; Y10T442/2975; Y10T442/2984; Y10T442/2992; Y10T442/60; Y10T442/699
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
195 words
A prepreg comprising reinforcing filaments and a hot melt coatable thermosettable resin composition comprising: a) a thermosettable mixture that is liquid at a temperature in the range of 20° to 100° C. comprising one or more thermosettable resins and one or more curatives for the thermosettable resins and b) resin particles of one or more amorphous thermoplastic polymers, said particles being dispersed in the thermosettable mixture at a temperature below the dissolution temperature of the particles, the particles having an average diameter in the range of 0.5 to 50 micrometers, a surface area of at least 1.0 m 2 /g, and a dissolution temperature of 50° C. or higher and being essentially insoluble in the thermosettable resin at temperatures up to 15° C. below the dissolution temperature; said resin composition being free of solvent for the thermoplastic particles and having a viscosity that decreases with increasing temperature up to a dissolution temperature and that increases with increasing temperatures at temperatures above the dissolution temperature, said amorphous particles being completely dissolved in the thermosettable resin at a temperature at least 20° C. below the cure temperature of the resin, and providing a homogeneous cured resin composition.
Claim 2
Dependent Claim
195 words
A prepreg comprising reinforcing filaments and a hot melt coatable thermosettable resin composition comprising: a) a thermosettable mixture that is liquid at a temperature in the range of 20° to 100° C. comprising one or more thermosettable resins and one or more curatives for the thermosettable resins and b) resin particles of one or more amorphous thermoplastic polymers, said particles being dispersed in the thermosettable mixture at a temperature below the dissolution temperature of the particles, the particles having an average diameter in the range of 0.5 to 50 micrometers, a surface area of at least 1.0 m 2 /g, and a dissolution temperature of 50° C. or higher and being essentially insoluble in the thermosettable resin at temperatures up to 15° C. below the dissolution temperature; said resin composition being free of solvent for the thermoplastic particles and having a viscosity that decreases with increasing temperature up to a dissolution temperature and that increases with increasing temperatures at temperatures above the dissolution temperature, said amorphous particles being completely dissolved in the thermosettable resin at a temperature at least 20° C. below the cure temperature of the resin, and providing a homogeneous cured resin composition.
Claim 3
Dependent Claim
13 words
The prepreg according to claim 1 wherein said resin particles are a polyetherimide.
Claim 4
Dependent Claim
31 words
The prepreg according to claim 1 wherein said thermosettable resin is at least one member selected from the group consisting of aromatic epoxy, cycloaliphatic epoxy, N,N'-bismaleimide, and polycyanate monomer and prepolymer.
Claim 5
Dependent Claim
53 words
The prepreg according to claim 1 wherein said resin particles are at least one member selected from the group consisting of polyesters, polyethers, polycarbonates, polyamides, polyimides, polyetherimides other than said polyimides, and polyamideimides other than said polyamides and polyimides, polyarylates other than said polyester, polysulfones, and polyarylsulfones and polyethersulfones other than said polysulfones.
Claim 6
Dependent Claim
12 words
The prepreg according to claim 1 wherein said filaments are a roving.
Claim 7
Dependent Claim
20 words
The prepreg according to claim 1 wherein said filaments are selected from the group consisting of organic and inorganic fibers.
Claim 8
Dependent Claim
43 words
The prepreg according to claim 6 wherein said inorganic fibers are selected from the group consisting of glass, carbon, ceramic, boron, silicon carbide, and mixtures thereof; and said organic fibers are selected from the group consisting of polyimide, polyester, polyolefin, and mixtures thereof.
Claim 9
Dependent Claim
24 words
The prepreg according to claim 1 which has been cured to provide a composite structure comprising reinforcing filaments and the cured thermoset resin composition.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-11-28 | 1998-05-30 | 1998-11-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-11-28 | 2002-05-30 | 2002-11-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-11-28 | 2006-05-30 | 2006-11-29 | $7700.00 | Window Closed / Lapsed |