Electro coat/base coat/clear coat finishes stabilized with S-triazine UV absorbers

Claim 2

A polymer film composition which comprises (a) an electro coat primer in adhesion to a metal substrate; (b) a base or color coat that is in adhesion to the electro coat and which comprises a film-forming binder and an organic pigment or an inorganic pigment or mixture thereof; (c) a clear coat that is in adhesion to the base coat and which comprises a film-forming binder; and (d) an effective stabilizing amount, of at least one tris-aryl-s-triazine UV absorber contained in either the base coat or the clear coat or in both base coat and clear coat.

Claim 3

A composition according to claim 1 wherein the amount of component (d) is between 1 and 20% by weight of the film-forming binder.

Claim 4

A composition according to claim 1 wherein component (d) is a tris-aryl-s-triazine UV absorber of formula A, B or C ##STR6## wherein R 1 , R 2 , and R 3 are the same or different and are hydrogen or straight or branched chain alkyl of 1 to 24 carbon atoms; or said alkyl substituted by one to eight halogen, --R 4 , --OR 5 , --N(R 5 ) 2 , --CON(R 5 ) 2 , --COOR 5 , or --OCOR 5 groups or combinations thereof; or said alkyl interrupted by one to eight --O--, --NR 5 --, --CONR 5 --, --COO--, --OCO--, or --CO-- groups or combinations thereof; or said alkyl both substituted and interrupted by combinations of the groups mentioned above; R 4 is cycloalkyl of 5 to 12 carbon atoms, straight or branched chain alkenyl of 2 to 18 carbon atoms, phenyl, naphthyl, biphenyl, or said phenyl, said naphthyl or said biphenyl substituted by one to three halogen, alkyl of 1 to 8 carbon atoms, alkoxy of 1 to 8 carbon atoms or combinations thereof; or phenylalkyl of 7 to 15 carbon atoms, or said phenylalkyl substituted on the phenyl ring by one to three halogen, alkyl of 1 to 8 carbon atoms, alkoxy of 1 to 8 carbon atoms or combinations thereof; R 5 is defined as is R 4 , or R 5 is also hydrogen or straight or branched chain alkyl of 1 to 24 carbon atoms, Y is hydrogen or straight or branched chain alkyl of 1 to 6 carbon atoms; X is hydrogen, straight or branched chain alkyl of 1 to 4 carbon atoms, phenyl, phenyl substituted by halogen or by alkyl of 1 to 4 carbon atoms; halogen, --SR 6 , --SOR 6 or --SO 2 R 6 , where R 6 is alkyl of 1 to 20 carbon atoms, alkenyl of 3 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 15 carbon atoms, aryl of 6 to 10 carbon atoms or said aryl substituted by one or two alkyl of 1 to 4 carbon atoms; and L is --S--, --SO--, --SO 2 --, --S--S--, --S--E--S--, --SO--E--SO-- or --SO 2 --E--SO 2 --, where E is alkylene of 2 to 12 carbon atoms, cycloalkylene of 5 to 12 carbon atoms or alkylene interrupted by or terminated by cyclohexylene; and with the proviso that when X is halogen, R 1 and R 2 together are not --CH 2 CH(R 7 )OR 8 where R 7 is hydrogen or methyl, and R 8 is hydrogen or --COR 9 where R 9 is alkyl of 1 to 6 carbon atoms.

Claim 5

A composition according to claim 1 wherein component (d) is a tris-aryl-s-triazine of formula I or II ##STR7## where R 1 is straight or branched chain alkyl of 2 to 24 carbon atoms, or said alkyl substituted by one or two --OR 5 , where R 5 is hydrogen, straight or branched chain alkyl of 1 to 24 carbon atoms, phenyl or said phenyl substituted by one to three halogen, alkyl of 1 to 8 carbon atoms or alkoxy of 1 to 8 carbon atoms; X is hydrogen, straight or branched chain alkyl of 1 to 4 carbon atoms, phenyl, phenyl substituted by halogen or by alkyl of 1 to 4 carbon atoms; halogen, --SR 6 , --SOR 6 or --SO 2 R 6 , where R 6 is alkyl of 1 to 20 carbon atoms or aryl of 6 to 10 carbon atoms; and with the proviso that when X is halogen, R 1 is not --CH 2 CH(R 7 )OH where R 7 is hydrogen or methyl.

Claim 6

A composition according to claim 4 where in the compounds of formula I or II, R 1 is straight or branched chain alkyl of 2 to 6 carbon atoms or said alkyl substituted by one or two --OR 5 , where R 5 is hydrogen, straight or branched chain alkyl of 1 to 24 carbon atoms or phenyl; X is hydrogen, straight or branched chain alkyl of 1 to 4 carbon atoms, chloro, --SR 6 , --SOR 6 or --SO 2 R 6 , where R 6 is phenyl; and with the proviso that when X is chloro, R 1 is not --CH 2 CH(R 7 )OH where R 7 is hydrogen or methyl.

Claim 7

A composition according to claim 3 wherein the tris-aryl-s-triazine compound of formula A, B or C is 2,4,6-tris[2-hydroxy 4-(2-hydroxy-3-nonyloxypropoxy)phenyl]-s-triazine; 6-(p-chlorophenyl)-2,4-bis-[2-hydroxy-4-(2-hydroxy-3-nonyloxypropoxy)phenyl]-s-triazine; 2,4-bis-[2-hydroxy-4-(2-hydroxy-3-nonyloxypropoxy)phenyl]-6-phenyl-s-triazine; 2,4-bis-(2,4-dihydroxyphenyl)-6-[4-(phenylthio)phenyl]-s-triazine; 2,4-bis-(4-butoxy-2-hydroxyphenyl)-6-[4-(phenylthio)phenyl]-s-triazine; 2,4-bis-[2-hydroxy-4-(2-hydroxy-3-nonyloxypropoxy)phenyl]-6-[4-(phenylthio)phenyl]-s-triazine; 6-[4-(benzenesulfinyl)phenyl)-2,4-bis-[2-hydroxy-4-(2-hydroxy-3-nonyloxypropoxy)phenyl]-s-triazine; 6-[4-(benzenesulfinyl)phenyl]-2,4-bis-[2-hydroxy-4-(2-hydroxy-3-nonyloxypropoxy)phenyl]-s-triazine; 6-(p-chlorophenyl)-2,4-bis-[2-hydroxy-4-(2-hydroxy-3-phenoxypropoxy)phenyl]-s-triazine; or 2,4,6-tris-(2,4-dihydroxy-5-hexylphenyl)-s-triazine.

Claim 8

A composition according to claim 1 wherein component (d) is incorporated into the base coat.

Claim 9

A composition according to claim 1 wherein the film-forming binder is a high solids thermoset acrylic/melamine resin.