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Fishing lines and related products

Assignee: EIDP Inc
•
Filing: 1992-11-16
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Granted: 1994-10-11
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Expires: 2012-11-16
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Abstract

Abstract Novel fishing lines, and related products, especially monofilamentary products, of polyesters that are biodegradable and disintegrate, when immersed over a period of weeks or months in water, to avoid residues thereof obstructing the aqueous environment, but are storage-stable, i.e.. do not disintegrate while being stored in air, before such lengthy immersion.

Inventors

  • 👤 Robert B. Fish, Jr.
  • 👤 Francis G. Gallagher
  • 👤 James M. McKenna
  • 👤 Raymond F. Tietz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 13:50
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/18; A; A61; A61F; A61F13/00; A61F13/15; A61F13/15203; A61F13/15252; A61L; A61L15/00; A61L15/16; A61L15/22; A61L15/26; C08G; C08G63/00; C08G63/02; C08G63/60; C08G63/68; C08G63/688; C08G63/6884; C08G63/6886; D; D01; D01F; D01F6/00; D01F6/78; D01F6/84; D01F6/86; A61F13/51; A61F2013/51002; A61F2013/51023; A61F2013/51035; A61F13/514; A61F13/51401; A61F2013/51409; A61F2013/51433; C08J2367/00; C08J2367/02; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2929; Y10T428/2933; Y10T428/2964; Y10T428/2967; Y10T428/2969

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 244 words
A degradable fishing line that consists essentially of a monofilament having a tensile strength of at least 50,000 psi, said monofilament consisting essentially of a linear polyester consisting essentially of recurring structural units of the formula: --C(O)--R--C(O)--OGO-- wherein R consists essentially of divalent hydrocarbylene radicals and at least 75 mole % of R is p-phenylene, wherein G consists essentially of the following radicals: a radical of a polyalkylene ether glycol of molecular weight at least 250, in amount at least 5 % by weight of the polyester, a polyethylene ether radical selected from the group consisting of --(CH 2 ) 2 --O--(CH 2 ) 2 --and --(CH 2 ) 2 --O--(CH 2 ) 2 --O--(CH 2 ) 2 --, in amount up to about mole % of G, and the remainder of G is a hydrocarbylene radical selected from the group consisting of --(CH.sub.2).sub.2 --,--(CH.sub.2).sub.3 --, and --(CH.sub.2).sub.4 --radicals, and wherein up to 3 mole % of the polyester may contain alkali metal or alkaline earth metal sulfo groups; and wherein the polyester is stabilized by a stabilizer, in amount up to 5 percent by weight said stabilizer and said amount being, selected such that the tensile strength of the fishing line is not reduced more than 5 % over a 2 month storage period in ambient air, when protected from light, but is reduced by at least 15 % over a 2 month period of exposure to aerated water at 30 degrees C.
Claim 2
Dependent Claim 244 words
A degradable fishing line that consists essentially of a monofilament having a tensile strength of at least 50,000 psi, said monofilament consisting essentially of a linear polyester consisting essentially of recurring structural units of the formula: --C(O)--R--C(O)--OGO-- wherein R consists essentially of divalent hydrocarbylene radicals and at least 75 mole % of R is p-phenylene, wherein G consists essentially of the following radicals: a radical of a polyalkylene ether glycol of molecular weight at least 250, in amount at least 5 % by weight of the polyester, a polyethylene ether radical selected from the group consisting of --(CH 2 ) 2 --O--(CH 2 ) 2 --and --(CH 2 ) 2 --O--(CH 2 ) 2 --O--(CH 2 ) 2 --, in amount up to about mole % of G, and the remainder of G is a hydrocarbylene radical selected from the group consisting of --(CH.sub.2).sub.2 --,--(CH.sub.2).sub.3 --, and --(CH.sub.2).sub.4 --radicals, and wherein up to 3 mole % of the polyester may contain alkali metal or alkaline earth metal sulfo groups; and wherein the polyester is stabilized by a stabilizer, in amount up to 5 percent by weight said stabilizer and said amount being, selected such that the tensile strength of the fishing line is not reduced more than 5 % over a 2 month storage period in ambient air, when protected from light, but is reduced by at least 15 % over a 2 month period of exposure to aerated water at 30 degrees C.
Claim 3
Dependent Claim 201 words
A degradable fishing line that consists essentially of a monofilament having a tensile strength of at least 50,000 psi, said monofilament consisting essentially of a linear polyester consisting essentially of recurring structural units of the formula: --C(O)--R--C(O)--OGO-- wherein R consists essentially of divalent hydrocarbylene radicals and at least 75 mole % of R is p-phenylene, wherein G consists essentially of the following radicals: a radical of a polyalkylene ether glycol of molecular weight at least 250, in amount at least 5 % by weight of the polyester, and the remainder of G is a hydrocarbylene radical selected from the group consisting of --(CH.sub.2).sub.2 --,--(CH.sub.2).sub.3 --, and --(CH.sub.2).sub.4 - radicals, and wherein up to 3 mole % of the polyester may contain alkali metal or alkaline earth metal sulfo groups; and wherein the polyester is stabilized by a stabilizer, in amount up to 5 percent by weight said stabilizer said amount being, selected such that the tensile strength of the fishing line is not reduced more than 5% over a 2 month storage period in ambient air, when protected from light, but is reduced by at least 15% over a 2 month period of exposure to aerated water at 30 degrees C.
Claim 4
Dependent Claim 201 words
A degradable fishing line that consists essentially of a monofilament having a tensile strength of at least 50,000 psi, said monofilament consisting essentially of a linear polyester consisting essentially of recurring structural units of the formula: --C(O)--R--C(O)--OGO-- wherein R consists essentially of divalent hydrocarbylene radicals and at least 75 mole % of R is p-phenylene, wherein G consists essentially of the following radicals: a radical of a polyalkylene ether glycol of molecular weight at least 250, in amount at least 5 % by weight of the polyester, and the remainder of G is a hydrocarbylene radical selected from the group consisting of --(CH.sub.2).sub.2 --,--(CH.sub.2).sub.3 --, and --(CH.sub.2).sub.4 - radicals, and wherein up to 3 mole % of the polyester may contain alkali metal or alkaline earth metal sulfo groups; and wherein the polyester is stabilized by a stabilizer, in amount up to 5 percent by weight said stabilizer said amount being, selected such that the tensile strength of the fishing line is not reduced more than 5% over a 2 month storage period in ambient air, when protected from light, but is reduced by at least 15% over a 2 month period of exposure to aerated water at 30 degrees C.
Claim 5
Dependent Claim 21 words
A fishing line according to claim 1, wherein the polyester contains up to 0.3 mole % of a trifunctional branching agent.
Claim 6
Dependent Claim 21 words
A fishing line according to claim 2, wherein the polyester contains up to 0.3 mole % of a trifunctional branching agent.
Claim 7
Dependent Claim 48 words
A fishing line according to any one of claims 1 to 4, wherein the monofilament is composed of a core and a sheath of one or more concentric layers, said core having a significantly higher wet initial tensile modulus than said sheath that consists essentially of said polyester.

References Cited (Backward Citations)

US3651014A Cited
US3763109A Cited
US4297413A Cited
US4459337A Cited
US4584240A Cited
EP0427496A2 Cited
JPH04108331A Cited
US5097004A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-10-10 1998-04-11 1998-10-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-10-10 2002-04-11 2002-10-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-10-10 2006-04-11 2006-10-11 $7700.00 Window Closed / Lapsed

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