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US5352640A Expired / Lapsed US ⏱️ 0.0 years remaining

Colored glass compositions and glazings produced therewith

Assignee: Saint Gobain Glass France SAS
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Filing: 1993-04-07
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Granted: 1994-10-04
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Expires: 2013-04-07
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Abstract

Abstract The invention relates to a colored glass composition for producing glazings for use, e.g., as automobile sunroofs. The colored glass according to the invention is a soda-lime-silica glass comprising, as coloring agents, 1.4 to 4% iron oxide expressed as Fe 2 O 3 and 0 to 0.05% cobalt oxide, with the cobalt oxide exceeding about 0.02% when the Fe 2 O 3 is below about 2% and, optionally, selenium and chromium oxide, whereby the sum of the CoO+Se+Cr 2 O 3 is preferably less than about 0.24% by weight. The glass of the invention has a total light transmission factor under illuminant A equal to or below approximately 20% and a total energy transmission factor equal to or below approximately 12% for a thickness of 3.85 mm.

Inventors

  • 👤 Pierre Combes
  • 👤 Jean-Jacques Massol
  • 👤 Pedro C. Alvarez

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 02:36
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/04; C03C3/076; C03C3/083; C03C3/085; C03C3/087; C03C17/00; C03C17/22; C03C17/23; C03C3/078; C03C4/00; C03C4/02; C03C2217/00; C03C2217/20; C03C2217/21; C03C2217/211; Y; Y10; Y10S; Y10S501/00; Y10S501/90; Y10S501/904; Y10S501/905

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 209 words
A glass composition for forming colored glazings consisting essentially of, in percent by weight, 64 to 75% SiO 2 , 5 to 15% CaO, 10 to 18% Na 2 O, at least one of Al 2 O 3 , B 2 O 3 , MgO or K 2 O, each in an amount of up to 5% by weight and CoO as a coloring agent in an amount of up to 0.05% by weight, wherein the amount of CoO is greater than about 0.02% by weight when Fe 2 O 3 is present in said composition in an amount less than 2% by weight, and selenium in an amount up to about 0.005%, and as a coloring agent, 1.4 to 4% Fe 2 O 3 , wherein the amount of alkaline earth oxides is between about 6-16% by weight and the amount of alkali metal oxides is between about 10-20% by weight and wherein glazings formed of said composition when illuminated under Illuminant C, has a dominant percentage light transmission between about 485-570 nm, and which have a total light transmission factor under illuminant A of less than 20% and a total energy transmission factor of less than 12% when said glazings have a thickness of about 3.85 mm.
Claim 2
Dependent Claim 209 words
A glass composition for forming colored glazings consisting essentially of, in percent by weight, 64 to 75% SiO 2 , 5 to 15% CaO, 10 to 18% Na 2 O, at least one of Al 2 O 3 , B 2 O 3 , MgO or K 2 O, each in an amount of up to 5% by weight and CoO as a coloring agent in an amount of up to 0.05% by weight, wherein the amount of CoO is greater than about 0.02% by weight when Fe 2 O 3 is present in said composition in an amount less than 2% by weight, and selenium in an amount up to about 0.005%, and as a coloring agent, 1.4 to 4% Fe 2 O 3 , wherein the amount of alkaline earth oxides is between about 6-16% by weight and the amount of alkali metal oxides is between about 10-20% by weight and wherein glazings formed of said composition when illuminated under Illuminant C, has a dominant percentage light transmission between about 485-570 nm, and which have a total light transmission factor under illuminant A of less than 20% and a total energy transmission factor of less than 12% when said glazings have a thickness of about 3.85 mm.
Claim 3
Dependent Claim 42 words
The composition of claim 1 which further comprises a color effective amount of chromium oxide as an additional coloring agent, wherein the total amount of CoO, selenium and Cr 2 O 3 is less than about 0.24% by weight of said composition.
Claim 4
Dependent Claim 33 words
The composition of claim 2 which consists essentially of 2 to 3% by weight Fe 2 O 3 , 0.014 to 0.04 percent by weight CoO and up to 0.005% by weight selenium.
Claim 5
Dependent Claim 32 words
The composition of claim 2 which consists essentially of 1.4 to 2.5% by weight Fe 2 O 3 , 0.015 to 0.003% by weight CoO and 0.0010 to 0.0035% by weight selenium.
Claim 6
Dependent Claim 35 words
The composition of claim 2 which consists essentially of 1.5 to 2.5% by weight Fe 2 O 3 , 0.015 to 0.030% by weight CoO and 0.07 to 0.2% by weight Cr 2 O 3
Claim 7
Dependent Claim 21 words
The composition of claim 1 wherein said Fe 2 O 3 comprises between about 16 to 40% by weight of FeO.
Claim 8
Dependent Claim 24 words
The composition of claim 6 wherein said Fe 2 O 3 is present in said composition in an amount between about 3-4% by weight.
Claim 9
Dependent Claim 15 words
A glazing comprising at least one colored glass sheet having the composition of claim 3.
Claim 10
Dependent Claim 15 words
A glazing comprising at least one colored glass sheet having the composition of claim 4.
Claim 11
Dependent Claim 15 words
A glazing comprising at least one colored glass sheet having the composition of claim 5.
Claim 12
Dependent Claim 15 words
A glazing comprising at least one colored glass sheet having the composition of claim 8.
Claim 13
Dependent Claim 22 words
The glazing of claim 8, 9, 10 or 11 wherein the thickness of said glazing is between about 2 and 10 millimeters.
Claim 14
Dependent Claim 18 words
The glazing of claim 12 wherein the thickness of said glazing is between about 3 and 6 millimeters.
Claim 15
Dependent Claim 23 words
The glazing of claim 13 which further comprises at least one metal oxide layer coated upon at least a portion of said glazing.

References Cited (Backward Citations)

US2524719A Cited
GB803927A Cited
US4104076A Cited
GB1512704A Cited
US4525462A Cited
US4500567A Cited
US4873206A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-10-03 1998-04-04 1998-10-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-10-03 2002-04-04 2002-10-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-10-03 2006-04-04 2006-10-04 $7700.00 Window Closed / Lapsed

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