US5346936A
Expired / Lapsed
US
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Starch/polymer mixture, process for the preparation thereof, and products obtainable therefrom
Assignee: Plantic Technologies Ltd
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Filing: 1992-06-15
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Granted: 1994-09-13
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Expires: 2012-06-15
Abstract
Abstract A biodegradable, single-phase starch/polymer mixture comprising (a) 10 to 99 parts of a starch molding composition comprising (i) 95 to 45 parts of at least one chemically modified starch, and (ii) 5 to 55 parts of at least one emulsifier, plasticizer or destructurizing agent, the parts of (i) and (ii) adding up to 100; and (b) 90 to 1 parts of at least one linear polymer, the parts by weight of components (a) and (b) adding up to 100. In addition, 0 to 20 parts of additives which are customary in this area are included. A method of preparation, and the use thereof for thermoplastically molded parts, in particular films, is also disclosed.
Inventors
- 👤 Friedrich S. Buehler
- 👤 Eduard Schmid
- 👤 Hans-Joachim Schultze
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 03:01
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; B32B27/18; B32B27/22; B32B27/32; B32B27/34; B32B27/36; C; C08; C08J; C08J5/00; C08J5/18; C08K; C08K5/00; C08K5/04; C08K5/16; C08K5/21; C08L; C08L3/00; C08L3/04; C08L67/00; C08L67/02; C08L67/04; B32B2307/00; B32B2307/70; B32B2307/716; B32B2307/7163; B32B2307/718; B32B2309/00; B32B2309/08; B32B2309/10; B32B2309/105; C08J2303/00; C08J2303/04; C08L2201/00; C08L2201/06; C08L77/00
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
97 words
A biodegradable, single-phase starch/polymer mixture comprising (a) 10 to 99 parts by weight of a starch molding composition comprising (i) 95 to 45 parts by weight of at least one chemically modified starch, (ii) 0.1 to 5 parts by weight of urea, urea derivatives, or mixtures thereof, (iii) 4.9 to 50 parts of at least one plasticizer, the parts of (i), (ii), and (iii) adding up to 100, and (b) 90 to 1 parts by weight of at least one linear polymer other than ethylene copolymers, the parts of components (a) and (b) adding up to 100.
Claim 2
Dependent Claim
97 words
A biodegradable, single-phase starch/polymer mixture comprising (a) 10 to 99 parts by weight of a starch molding composition comprising (i) 95 to 45 parts by weight of at least one chemically modified starch, (ii) 0.1 to 5 parts by weight of urea, urea derivatives, or mixtures thereof, (iii) 4.9 to 50 parts of at least one plasticizer, the parts of (i), (ii), and (iii) adding up to 100, and (b) 90 to 1 parts by weight of at least one linear polymer other than ethylene copolymers, the parts of components (a) and (b) adding up to 100.
Claim 3
Dependent Claim
18 words
The starch/polymer mixture of claim 1 wherein there are 0 to 20 parts by weight of additives present.
Claim 4
Dependent Claim
29 words
The starch/polymer mixture of claim 2 wherein said additives are selected from the group consisting of optical brighteners, stabilizers, antioxidants, dyes, fillers, flameproofing agents, processing aids, and mixtures thereof.
Claim 5
Dependent Claim
20 words
The starch/polymer mixture of claim 1 wherein (a) comprises 0.1 to 2.0 parts by weight of at least one emulsifier.
Claim 6
Dependent Claim
74 words
The starch/polymer mixture of claim 1 wherein (a) comprises (i) 95 to 53.2 parts by weight of at least one chemically modified starch, (ii) 4.8 to 39.8 parts by weight of at least one plasticizer, (iii) 0.1 to 5 parts by weight of urea, urea derivatives, or mixtures thereof, and (iv) 0.1 to 2 parts by weight of at least one emulsifier, the parts of (i), (ii), (iii), and (iv) adding up to 100.
Claim 7
Dependent Claim
22 words
The starch/polymer mixture of claim 5 wherein (a) contains urea, urea derivatives, and mixtures thereof, in an amount of 0.1% to 2%.
Claim 8
Dependent Claim
20 words
The starch/polymer mixture of claim 1 wherein said chemically modified starch has a natural water content of 5% to 16%.
Claim 9
Dependent Claim
47 words
The starch/polymer mixture of claim 1 wherein said chemically modified starch has been modified by reaction of its OH groups with at least one compound selected from the group consisting of alkylene oxides and other substances which form ethers, esters, urethanes, carbamates or isocyanates and mixtures thereof.
Claim 10
Dependent Claim
14 words
The starch/polymer mixture of claim 8 wherein said amylose content is 20% to 100%.
Claim 11
Dependent Claim
28 words
The starch/polymer mixture of claim 1 wherein said chemically modified starch is a hydroxy-alkyl, acetyl, carbamate starch, or mixtures thereof, said alkyl having 2 to 6 carbon atoms.
Claim 12
Dependent Claim
20 words
The starch/polymer mixture of claim 1 wherein said chemically modified starch has a degree of substitution of 0.01 to 0.2.
Claim 13
Dependent Claim
19 words
The starch/polymer mixture of claim 1 wherein said plasticizer is an organic compound containing at least one hydroxyl group.
Claim 14
Dependent Claim
30 words
The starch/polymer mixture of claim 12 wherein said organic compound is selected from the group consisting of sorbitol, mannitol, D-glucose, glycerol, ethylene glycol, polyethylene glycol, propylene glycol, and mixtures thereof.
Claim 15
Dependent Claim
17 words
The starch/polymer mixture of claim 1 wherein said emulsifier has an HLB value of 0 to 20.
Claim 16
Dependent Claim
37 words
The starch/polymer mixture of claim 14 wherein said emulsifier is selected from the group consisting of metal stearates, glycerol monostearates, polyoxyethylene (20) sorbitan monolaurate, polyoxyethylene (20) sorbitan monopalmitate, polyoxyethylene (40) stearate, polyoxyethylene (100) stearate, and mixtures thereof.
Claim 17
Dependent Claim
19 words
The starch/polymer mixture of claim 1 wherein (b) has a melting or softening point of 50° to 160° C.
Claim 18
Dependent Claim
61 words
The mixture of claim 16 wherein said linear polymer is selected from the group consisting of homopolyamides, copolymides, and mixtures thereof, said homopolyamides being made from a compound selected from the group consisting of ω-aminocarboxylic acid and lactams having 6 to 12 carbon atoms; said copolyamides being made from ωaminocarboxylic acids, lactams having 6 to 12 carbon atoms, and mixtures thereof.
Claim 19
Dependent Claim
99 words
The mixture of claim 16 wherein said linear polymer is selected from the group consisting of homopolyamides, copolyamides, and mixtures thereof, said homopolyamides being made from aliphatic diamines having 2 to 6 carbon atoms or polyetherdiamines reacted with linear dicarboxylic acids having 2 to 12 carbon atoms or dimerized fatty acids; said copolyamides being reaction products of compounds selected from the group consisting of aliphatic diamines having 2 to 6 carbon atoms, polyetherdiamines, and mixtures thereof with compounds selected from the group consisting of linear dicarboxylic acids having 2 to 12 carbon atoms, dimerized fatty acids, and mixtures thereof.
Claim 20
Dependent Claim
82 words
The mixture of claim 16 wherein said linear polymer is selected from the group consisting of homopolyesters, copolyesters, and mixtures thereof, said homopolyesters being made from a compound selected from the group consisting of ω-hydroxycarboxylic acids having 2 to 12 carbon atoms and lactones having 6 to 12 carbon atoms; said copolyester being a reaction product of compounds selected from the group consisting of ω-hydroxycarboxylic acids having 2 to 12 carbon atoms, lactones having 6 to 12 carbon atoms, and mixtures thereof.
Claim 21
Dependent Claim
141 words
The mixture of claim 15 wherein said linear polymer is selected from the group consisting of homopolyesters, copolyesters, and mixtures thereof, said homopolyesters being made from a first alcohol and a first acid, said first alcohol being selected from the group consisting of aliphatic diols having 2 to 6 carbon atoms, said first acid being selected from the group consisting of linear dicarboxylic acids having 2 to 12 carbon atoms, terephthalic acid, and isophthalic acid; said copolyesters being made from second alcohols and second acids, said second alcohols being selected from the group consisting of aliphatic diols having 2 to 6 diols, an aliphatic diol mixture having 2 to 18 carbon atoms, and mixtures thereof, said second acid being selected from the group consisting of linear dicarboxylic acids having 2 to 12 carbon atoms, terephthalic acid, isophthalic acid, and mixtures thereof.
Claim 22
Dependent Claim
73 words
A process for the preparation of the starch/polymer mixture of claim 1 wherein (a) and (b) are premixed in a ratio of from 10:90 to 99:1, (a) and (b) being homogeneously mixed in a melt at temperatures of at least 10° C. below the decomposition point of said starch and a maximum of 30° C. above the melting or softening point of the said linear polymer, and said mixture is extruded or coextruded.
Claim 23
Dependent Claim
22 words
Thermoplastically molded parts produced from the starch/polymer mixture of claim 1 by injection molding, extrusion, coextrusion, blow molding, thermoforming, or injection stamping.
Claim 24
Dependent Claim
23 words
The molded parts of claim 22 which are films comprising 50 to 95 parts of (a) and 50 to 5 parts of (b).
Claim 25
Dependent Claim
27 words
The molded parts of claim 22 which are coextruded films comprising at least one further polymer having a melting or softening point of 50° to 180° C.
Claim 26
Dependent Claim
23 words
The molded parts of claim 24 wherein said further polymer is selected from the group consisting of copolyamides, copolyesters, polyolefins, and mixtures thereof.
Claim 27
Dependent Claim
23 words
The molded parts of claim 25 wherein said polyolefin are selected from the group consisting of polyethylene/polypropylene, polybutylene, and derivatives and mixtures thereof.
Claim 28
Dependent Claim
30 words
The molded parts of claim 24 wherein said coextruded films comprise a middle layer of said starch/polymer mixture, and an upper layer and a lower layer of said further polymer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-09-12 | 1998-03-14 | 1998-09-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-09-12 | 2002-03-14 | 2002-09-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-09-12 | 2006-03-14 | 2006-09-13 | $7700.00 | Window Closed / Lapsed |