Sinterable semi-crystalline powder and near-fully dense article formed therewith

Claim 2

A laser-sinterable powder product, adapted to be sintered in a selective laser sintering machine to form a sintered part, said powder consisting essentially of an unblended .polymer which provides signs of crystalline order under X-ray examination, and shows a crystalline melting point Tm as well as a glass transition temperature Tg, said polymer having a two-tier particle size distribution said powder having the following properties: (a) freely-flowable semi-crystalline powder having a crystallinity in the range from 10-90% measured by [DSC] differential scanning calorimetry; (b) a major portion by weight of the powder having a sphericity in the range from greater than 0.5 to 0.9, and a two-tier distribution in which substantially no primary particles has an average diameter greater than 180μm, provided further that the number average ratio of particles smaller than 53μm is greater than 80%, the remaining larger particles being in the size range from 53μm to 180μm; a layer of said powder no more than 250μm deep absorbing essentially all infra-red energy beamed therethrough at a wavelength of 10.6μm, and a layer of said powder no more than 180μm thick absorbing more than 50% of said energy; (c) a number average molecular weight in the range from about 30,000 to 500,000, and a molecular weight distribution M w /M n in the range from 1 to 5; and, (d) a window of sinterability in the temperature range from near said powder's softening temperature T s to said powder's caking temperature T c ; whereby when said powder is sintered layer-wise in said window of sinterability to form a slice, it will not curl.

Claim 3

The laser-sinterable powder product of claim 1, essentially all of which has a sphericity in the range from greater than 0.5 to 0.9, and is freely flowable near said softening temperature T s ±5° C.; said number average ratio of particles smaller than 53μm is greater than 90%, said crystallinity is in the range from 15% to 60%, said molecular weight distribution is in the range from 1.2 to 3, said window of sinterability is in the range from 2°-25° C., and, said powder's storage modulus G' c is in the range from 1×10 6 dynes/cm 2 to 3×10 6 dynes/cm 2 when the temperature of said powder being sintered exceeds T c in less time than is required to melt contiguous large particles >53μm.

Claim 4

The laser-sinterable powder of claim 2 wherein the mean primary particle diameter is in the range from 80μm-100μm.

Claim 5

The laser-sinterable powder of claim 3 wherein said powder is selected from the group consisting of Nylons 6, 11, 12, polybutylene terephthalate, and polyacetal and said window of sinterability is in the range from 5°-20° C.

Claim 6

A bed of a laser-sinterable powder in a selective laser sintering zone, said bed consisting essentially of particles of an unblended synthetic resinous material which provides signs Of crystalline order under X-ray examination, and shows a crystalline melting point Tm as well as a glass transition temperature Tg, said material in particulate form having a two-tier particle size distribution from which powder, a laser-sintered part is formed and removably embedded in said bed, said powder being a freely-flowable semi-crystalline powder having primary particles in the size range smaller than 180μm and a sphericity in the range from greater than 0.5 to 0.9, provided further that the number average ratio of particles smaller than 53μm is greater than 80%, the remaining larger particles being in the size range from 53μm to 180μm; having a crystallinity measured by differential scanning calorimetry in the range from 10% to 90%, and when sufficiently heated, having a softening temperature T s , and a caking temperature T c from about 2°-25° C. above T s , and, when sintered, has a melt viscosity in the range from 100-10 4 poise (10-1000 Pa-sec) when said powder's temperature as it is being sintered, exceeds T c in less time than is required to melt contiguous large particles >53μm; said bed having a porosity in the range from 0.4 to 0.55, and providing, during operation, a temperature profile defined by sequential positive and negative temperature gradients in a vertical plane through upper and lower portions of said bed, respectively, when said bed's uppermost layer, less than 25082 m thick, is in the range from near said T s to said T c ; said bed maintaining said positive temperature gradient from said upper surface to a maximum temperature in a horizontal zone in which said sintered part lies, said upper temperature gradient being in the range 0.2° C./cm (0.5° C./in) to 2° C./cm (5° C./in); and, said bed maintaining a negative temperature gradient from said maximum temperature to the bottom of said bed, said negative lower temperature gradient being in the range from 0.2° C./cm (0.5° C./in) to 2° C./cm (5° C./in).

Claim 7

A bed of a laser-sinterable powder in a selective laser sintering zone, said bed consisting essentially of particles of an unblended synthetic resinous material which provides signs Of crystalline order under X-ray examination, and shows a crystalline melting point Tm as well as a glass transition temperature Tg, said material in particulate form having a two-tier particle size distribution from which powder, a laser-sintered part is formed and removably embedded in said bed, said powder being a freely-flowable semi-crystalline powder having primary particles in the size range smaller than 180μm and a sphericity in the range from greater than 0.5 to 0.9, provided further that the number average ratio of particles smaller than 53μm is greater than 80%, the remaining larger particles being in the size range from 53μm to 180μm; having a crystallinity measured by differential scanning calorimetry in the range from 10% to 90%, and when sufficiently heated, having a softening temperature T s , and a caking temperature T c from about 2°-25° C. above T s , and, when sintered, has a melt viscosity in the range from 100-10 4 poise (10-1000 Pa-sec) when said powder's temperature as it is being sintered, exceeds T c in less time than is required to melt contiguous large particles >53μm; said bed having a porosity in the range from 0.4 to 0.55, and providing, during operation, a temperature profile defined by sequential positive and negative temperature gradients in a vertical plane through upper and lower portions of said bed, respectively, when said bed's uppermost layer, less than 25082 m thick, is in the range from near said T s to said T c ; said bed maintaining said positive temperature gradient from said upper surface to a maximum temperature in a horizontal zone in which said sintered part lies, said upper temperature gradient being in the range 0.2° C./cm (0.5° C./in) to 2° C./cm (5° C./in); and, said bed maintaining a negative temperature gradient from said maximum temperature to the bottom of said bed, said negative lower temperature gradient being in the range from 0.2° C./cm (0.5° C./in) to 2° C./cm (5° C./in).

Claim 8

A bed of a laser-sinterable powder in a selective laser sintering zone, said bed consisting essentially of finely divided particles of an unblended synthetic resinous material which provides signs of crystalline order under X-ray examination, and Shows a crystalline melting point Tm as well as a glass transition temperature Tg, said material in finely divided particulate form having a two-tier particle size distribution from which particles a laser-sintered part is formed, said powder being a freely-flowable semi-crystalline powder having a crystallinity measured by differential scanning calorimetry in the range from 10% to 90%, said powder having primary particles in the size range smaller than 180μm, having a sphericity in the range from greater than 0.5 to 0.9, provided further that the number average ratio of particles smaller than 53μm is greater than 80%, the remaining larger particles being in the size range from 53μm to 180μm; said bed having a porosity in the range from 0.4 to 0.55 allowing a pressure drop of less than 6.89 kPa when cooling gas is flowed in a direction from top to bottom through said bed at a rate of 5 L/min and said bed is 30 cm deep.

Claim 9

A bed of a laser-sinterable powder in a selective laser sintering zone, said bed consisting essentially of finely divided particles of an unblended synthetic resinous material which provides signs of crystalline order under X-ray examination, and Shows a crystalline melting point Tm as well as a glass transition temperature Tg, said material in finely divided particulate form having a two-tier particle size distribution from which particles a laser-sintered part is formed, said powder being a freely-flowable semi-crystalline powder having a crystallinity measured by differential scanning calorimetry in the range from 10% to 90%, said powder having primary particles in the size range smaller than 180μm, having a sphericity in the range from greater than 0.5 to 0.9, provided further that the number average ratio of particles smaller than 53μm is greater than 80%, the remaining larger particles being in the size range from 53μm to 180μm; said bed having a porosity in the range from 0.4 to 0.55 allowing a pressure drop of less than 6.89 kPa when cooling gas is flowed in a direction from top to bottom through said bed at a rate of 5 L/min and said bed is 30 cm deep.

Claim 10

The bed of powder of claim 6 wherein said powder is selected from the group consisting of Nylons 6, 11, 12, polybutylene terephthalate, and polyacetal and said window of sinterability is in the range from 7°-17° C.

Claim 11

The bed of powder of claim 7 wherein said powder is Nylon 11 having a number average molecular weight in the range from 75,000 to 80,000 and a molecular weight distribution in the range from 1.2-1.7.

Claim 12

A laser-sintered article or `part` of arbitrary shape sintered in a selective laser sintering machine containing a laser-sinterable powder of a semi-crystalline synthetic resin, said part consisting essentially of a sintered mass of said powder, said part having a density in the range from 80% to 90% of the density of an isotropically molded part of said powder and fracture surfaces, when broken by bending, which are visually identical to fracture surfaces of said molded part but including a profusion of cavities having an average diameter in the range from 1μm-30μm randomly scattered throughout said part which has substantially the same flexural modulus and maximum stress at yield (psi) when fractured in bending, but substantially less ultimate elongation (%), and notched Izod impact (ftlb/in), than a compression molded article molded from a portion of said powder.

Claim 13

A laser-sintered article or `part` of arbitrary shape sintered in a selective laser sintering machine containing a laser-sinterable powder of a semi-crystalline synthetic resin, said part consisting essentially of a sintered mass of said powder, said part having a density in the range from 80% to 90% of the density of an isotropically molded part of said powder and fracture surfaces, when broken by bending, which are visually identical to fracture surfaces of said molded part but including a profusion of cavities having an average diameter in the range from 1μm-30μm randomly scattered throughout said part which has substantially the same flexural modulus and maximum stress at yield (psi) when fractured in bending, but substantially less ultimate elongation (%), and notched Izod impact (ftlb/in), than a compression molded article molded from a portion of said powder.

Claim 14

The laser-sintered article of claim 9 wherein said article is free from growth on its surfaces which are smooth to the touch.

Claim 15

The laser-sintered article of claim 10 wherein said powder consists essentially of an unblended polymer having a two-tier particle size distribution said powder having the following properties: (a) freely-flowable semi-crystalline powder having a crystallinity in the range from 10-90% measured by differential scanning calorimetry; (b) a major portion by weight of the powder having a sphericity in the range from greater than 0.5 to 0.9, and a two-tier distribution in which substantially no primary particles having an average diameter greater than 180μm, provided further that the number average ratio of particles smaller than 53μm is greater than 80%, the remaining larger particles being in the size range from 53μm to 180μm; a layer of said powder no more than 250μm deep absorbing essentially all infra-red energy beamed therethrough at a wavelength of 10.6μm, and a layer of said powder no more than 180μm thick absorbing more than 50% of said energy; and, (b) a number average molecular weight in the range from about 30,000 to 500,000, and a molecular weight distribution M w /M n in the range from 1 to 5; (c) a window of sinterability in the temperature range from near said powder's softening temperature T s to said powder's caking temperature T c .

Claim 16

The laser-sintered article of claim 11 wherein said powder consists essentially of an unblended polymer having a two-tier particle size distribution said powder having the following properties: (a) freely-flowable semi-crystalline powder having a crystallinity in the range from 10-90% measured by differential scanning calorimetry; (b) a major portion by weight of the powder having a sphericity in the range from greater than 0.5 to 0.9, and a two-tier distribution in which substantially no primary particles having an average diameter greater than 180μm, provided further that the number average ratio of particles smaller than 53μm is greater than 80%, the remaining larger particles being in the size range from 53μm to 180μm; a layer of said powder no more than 250μm deep absorbing essentially all infra-red energy beamed therethrough at a wavelength of 10.6μm, and a layer of said powder no more than 180μm thick absorbing more than 50% of said energy; (b) a number average molecular weight in the range from about 30,00 to 500,000, and a molecular weight distribution M w /M n in the range from 1 to 5; and, (c) a melt viscosity in the range from 100-10 4 poise (10-1000 Pa-sec) when the powder being sintered exceeds T c in less time than is required to melt contiguous large particles >53μm.

Claim 17

The laser-sintered article of claim 12 wherein said article is essentially distortion-free having no linear dimension of a part and no dimension of a surface out of plane by more than ±250μm (20 mils).

Claim 18

The laser-sinterable powder product of claim 13 wherein said crystallinity is in the range from 15-60%.

Claim 19

The laser-sinterable powder product of claim 2 wherein said crystallinity is in the range from 15-60%.

Claim 20

The bed of powder of claim 7 wherein said crystallinity is in the range from 15-60%.