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US5336079A Expired / Lapsed US ⏱️ 0.0 years remaining

Biaxially oriented laminated film comprising particles in a specific ratio of particle density

Assignee: Toray Industries Inc
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Filing: 1992-03-04
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Granted: 1994-08-09
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Expires: 2012-03-04
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Abstract

Abstract Disclosed is a biaxially oriented laminated film having at least three layers which has excellent abrasion resistance and electromagnetic conversion property when the film is used as the base film of a magnetic recording media. The biaxially oriented laminated film comprises at least one outermost layer containing particles A, the particle density ratio at surface layer of the particles A is not less than 0.01, and the mean primary particle size D of the particles A and the thickness T of the outermost layer containing the particles A satisfies the equation; D≦T≦200D.

Inventors

  • 👤 Iwao Okazaki
  • 👤 Koichi Abe
  • 👤 Hidehito Minamizawa
  • 👤 Takeo Fukuyama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 08:51
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/36; B32B27/18; G; G11; G11B; G11B5/00; G11B5/62; G11B5/73; G11B5/739; G11B5/73923; G11B5/73927; G11B5/73931; B32B2307/00; B32B2307/50; B32B2307/514; B32B2307/518; B32B2307/554; B32B2367/00; B32B2429/00; B32B2429/02; Y; Y10; Y10S; Y10S428/00; Y10S428/91; Y10T; Y10T428/00; Y10T428/25; Y10T428/254; Y10T428/256; Y10T428/257; Y10T428/259; Y10T428/31

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 116 words
A biaxially oriented laminated film having at least three layers, wherein an outermost layer contains particles A, said particles A comprising primary particles and secondary particles the ratio of (a) the particle density of said particles A in said outermost layer at a depth of 3 nm to (b) the particle density of said particles A in said outermost layer at a depth of 30 nm being not less than 0.01, the ratio E/D of the mean secondary particle size E to the mean primary particle size D of the particles A being in the range of 2-60, and said mean primary particle size D and thickness T of the outermost layer satisfying the equation D<=T<=200D.
Claim 2
Dependent Claim 116 words
A biaxially oriented laminated film having at least three layers, wherein an outermost layer contains particles A, said particles A comprising primary particles and secondary particles the ratio of (a) the particle density of said particles A in said outermost layer at a depth of 3 nm to (b) the particle density of said particles A in said outermost layer at a depth of 30 nm being not less than 0.01, the ratio E/D of the mean secondary particle size E to the mean primary particle size D of the particles A being in the range of 2-60, and said mean primary particle size D and thickness T of the outermost layer satisfying the equation D<=T<=200D.
Claim 3
Dependent Claim 20 words
The biaxially oriented laminated film according to claim 1, wherein said layer containing the particles A is composed of polyester.
Claim 4
Dependent Claim 34 words
The biaxially oriented laminated film according to claim 1, wherein particles B having a mean particle size greater than that of the particles A are also contained in said layer containing the particles A.
Claim 5
Dependent Claim 36 words
The biaxially oriented laminated film according to claim 3, wherein the mean particle size D1 of the particles B and the thickness T of the layer containing the particles A and B satisfies the equation; 0.5D1≦T≦5D1.
Claim 6
Dependent Claim 28 words
The biaxially oriented laminated film according to claim 3, wherein the mean particle size D1 of the particles B is in the range of 0.1 to 2 μm.
Claim 7
Dependent Claim 35 words
The biaxially oriented laminated film according to claim 3, wherein the content of the particles A and B in said layer containing the particles B is in the range of 0.005 to 5% by weight.
Claim 8
Dependent Claim 30 words
The biaxially oriented laminated film according to claim 3, wherein the relative standard deviation of the distribution of the particle size of the particles B is not greater than 0.6.
Claim 9
Dependent Claim 30 words
The biaxially oriented laminated film according to claim 3, wherein said particles B are selected from the group consisting of calcium carbonate particles, crosslinked polymer particles and colloidal silica particles.
Claim 10
Dependent Claim 19 words
The biaxially oriented laminated film according to claim 8, wherein said calcium carbonate particles are of the vaterite structure.
Claim 11
Dependent Claim 46 words
The biaxially oriented laminated film according to claim 3, wherein particles C having a mean particle size greater than that of the particles A and smaller than that of the particles B are also contained in said layer containing the particles A and the particles B.
Claim 12
Dependent Claim 29 words
The biaxially oriented laminated film according to claim 1, wherein the mean primary particle size D of the particles A is in the range of 1 to 300 nm.
Claim 13
Dependent Claim 33 words
The biaxially oriented laminated film according to claim 1, wherein the content of the particles A in said layer containing the particles A is in the range of 0.01 to 2% by weight.
Claim 14
Dependent Claim 26 words
The biaxially oriented laminated film according to claim 1, wherein said particles A are selected from the group consisting of zirconia, chain-shaped silica and alumina particles.
Claim 15
Dependent Claim 24 words
The biaxially oriented laminated film according to claim 1, wherein said particles A form non-incorporated particles internally of which seeds are the particles A.
Claim 16
Dependent Claim 52 words
The biaxially oriented laminated film according to claim 1, wherein said biaxially oriented laminated film is a laminated film having at least four layers comprising an intermediate layer, cover layers laminated on both surfaces of the intermediate layer and said outermost layer being laminated on at least one of the cover layers.
Claim 17
Dependent Claim 22 words
The biaxially oriented laminated film according to claim 15, wherein the thickness of said intermediate layer is not less than 0.1 μm.
Claim 18
Dependent Claim 24 words
The biaxially oriented laminated film according to claim 15, wherein the thickness of each of said cover layers is not less than 0.2 μm.
Claim 19
Dependent Claim 37 words
The biaxially oriented laminated film according to claim 15, wherein each of said cover layers contains particles, and the content of said particles contained in each of said cover layers is not greater than 2% by weight.
Claim 20
Dependent Claim 32 words
The biaxially oriented laminated film according to claim 1, wherein the surface resistivity of at least one outermost layer of said biaxially oriented laminated film is not greater than 1×10 14 Ω/□.
Claim 21
Dependent Claim 43 words
The biaxially oriented laminated film according to claim 19, wherein a sulfate group compound is added to said at least one outermost layer with a surface resistivity of not greater than 1×10 14 Ω/□ at a content of 0.2 to 5% by weight.

References Cited (Backward Citations)

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US4693932A Cited
US4990400A Cited
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US5069962A Cited
US5084335A Cited
JPH031941A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-08-08 1998-02-07 1998-08-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-08-08 2002-02-07 2002-08-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-08-08 2006-02-07 2006-08-09 $7700.00 Window Closed / Lapsed

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