Multi-layered electrophotographic element having a mixture of perylene pigments

Claim 2

A multi-layered electrophotographic element comprising an electrically conductive substrate, and a photoconductive layer on a surface thereof comprising a mixture of charge generating perylene pigments of the following structures: ##STR12## wherein R=aryl, alkyl, aralkyl, alkaryl, naphtyl, alkoxyaryl or a heterocyclic group and their substituted derivatives, and ##STR13## wherein X=a phenylene, naphtylene, pyridylene or phenanthrene group and the corresponding alkyl, aryl, aralkyl, nitro, chloro, bromo and methoxy substituted derivatives of these groups, wherein said mixture of perylene pigments is selected from the group consisting of a pigment mixture of perylenes of structure 1 with perylenes of structure 2, a pigment mixture of perylenes of structure 1 and a pigment mixture of perylenes of structure 2.

Claim 3

A multi-layered electrophotographic element according to claim 1, wherein said mixture of perylene pigments comprises a mixture of a pigment of structure 1, wherein R is an aralkyl group, and a pigment of structure 2.

Claim 4

A multi-layered electrophotographic element according to claim 2, wherein said mixture of perylene pigments comprises a mixture of a perylene pigment of structure 1, wherein ##STR14## and a perylene pigment of structure 2, wherein X is an o-phenylene group.

Claim 5

A multi-layered electrophotographic element according to claim 1, wherein said mixture of perylene pigments comprises a mixture of a first perylene pigment of structure 1, wherein R is a 2-methylbutyl group, and a second perylene pigment of structure 1, wherein ##STR15##

Claim 6

A multi-layered electrophotographic element according to claim 4, wherein said perylene mixture is comprised of said first and said second perylene pigments in a ratio of from about 60:40 to 10:90 by weight.

Claim 7

A multi-layered electrophotographic element according to claim 1, wherein said mixture of perylene pigments comprises a mixture of a first perylene pigment of structure 1, wherein ##STR16## and a second perylene pigment of structure 1, wherein ##STR17##

Claim 8

A multi-layered electrophotographic element according to claim 6, wherein said perylene mixture is comprised of said first and said second perylene pigments in a ratio of from about 80:20 to 25:75, by weight.

Claim 9

A multi-layered electrophotographic element according to claim 6, wherein said perylene mixture is comprised of said first and said second perylene pigments in a ratio of from about 75:25 to 50:50, by weight.

Claim 10

A multi-layered electrophotographic element comprising an electrically conductive substrate, and a photoconductive layer on a surface thereof comprising a charge generating layer comprising a mixture of charge generating perylene pigments of the following structures: ##STR18## wherein R=aryl, alkyl, aralkyl, alkaryl, naphtyl, alkoxyaryl or a heterocyclic group and their substituted derivatives, and ##STR19## wherein X=a phenylene, naphtylene, pyridylene or phenantrene group and the corresponding alkyl, aryl, aralkyl, nitro, chloro, bromo and methoxy substituted derivatives of these groups, wherein said mixture of perylene pigments is selected from the group consisting of a pigment mixture of perylenes of structure 1 with perylenes of structure 2, a pigment mixture of perylenes of structure 1 and a pigment mixture of perylenes of structure 2, and a charge transport layer containing as a charge transporting agent, homogeneously distributed in an insulating binder, an azine which has the general structural formula ##STR20## wherein R 5 and R 10 each represents a hydrogen atom or an alkyl group having from 1 to 4 carbon atoms and R 5 to R 10 can be the same or different.

Claim 11

A multi-layered electrophotographic element comprising an electrically conductive substrate, and a photoconductive layer on a surface thereof comprising a charge generating layer comprising a mixture of charge generating perylene pigments of the following structures: ##STR18## wherein R=aryl, alkyl, aralkyl, alkaryl, naphtyl, alkoxyaryl or a heterocyclic group and their substituted derivatives, and ##STR19## wherein X=a phenylene, naphtylene, pyridylene or phenantrene group and the corresponding alkyl, aryl, aralkyl, nitro, chloro, bromo and methoxy substituted derivatives of these groups, wherein said mixture of perylene pigments is selected from the group consisting of a pigment mixture of perylenes of structure 1 with perylenes of structure 2, a pigment mixture of perylenes of structure 1 and a pigment mixture of perylenes of structure 2, and a charge transport layer containing as a charge transporting agent, homogeneously distributed in an insulating binder, an azine which has the general structural formula ##STR20## wherein R 5 and R 10 each represents a hydrogen atom or an alkyl group having from 1 to 4 carbon atoms and R 5 to R 10 can be the same or different.

Claim 12

A multi-layered electrophotographic element according to claim 9, wherein said mixture of perylene pigments comprises a mixture of a pigment of structure 1, wherein R is an aralkyl group, and a pigment of structure 2.

Claim 13

A multi-layered electrophotographic element according to claim 10, wherein said mixture of perylene pigments comprises a mixture of a perylene pigment of structure 1, wherein ##STR21## and a perylene pigment of structure 2, wherein X is an o-phenylene group.

Claim 14

A multi-layered electrophotographic element according to claim 9, wherein said mixture of perylene pigments comprises a mixture of a first perylene pigment of structure 1, wherein R is a 2-methylbutyl group, and a second perylene pigment of structure 1, wherein ##STR22##

Claim 15

A multi-layered electrophotographic element according to claim 12, wherein said perylene mixture is comprised of said first and said second perylene pigments in a ratio of from about 60:40 to 10:90, by weight.

Claim 16

A multi-layered electrophotographic element according to claim 9, wherein said mixture of perylene pigments comprises a mixture of a first perylene pigment of structure 1, wherein ##STR23## and a second perylene pigment of structure 1, wherein ##STR24##

Claim 17

A multi-layered electrophotographic element according to claim 14, wherein said perylene mixture is comprised of said first and said second perylene pigments in a ratio of from about 80:20 to 25:75, by weight.

Claim 18

A multi-layered electrophotographic element according to claim 15, wherein said perylene mixture is comprised of said first and said second perylene pigments in a ratio of from about 75:25 to 50:50, by weight.

Claim 19

An electrophotographic imaging method comprising, providing a multi-layered electrophotographic imaging element comprising an electrically conductive substrate, and a photoconductive layer on a surface of said substrate comprising a mixture of charge generating perylene pigments of the following structures ##STR25## wherein said mixture of perylene pigments is selected from the group consisting of a pigment mixture of perylenes of structure 1 with perylenes of structure 2, a pigment mixture of perylenes of structure 1 and a pigment mixture of perylenes of structure 2, applying a uniform electrostatic charge to said photoconductive layer, selectively exposing said uniformly charged photoconductive layer to light so as to form an electrostatic latent image thereon, and developing said electrostatic latent image with electroscopic toner particles to render said latent image visible.

Claim 20

An electrophotographic imaging method comprising, providing a multi-layered electrophotographic imaging element comprising an electrically conductive substrate, and a photoconductive layer on a surface of said substrate comprising a mixture of charge generating perylene pigments of the following structures ##STR25## wherein said mixture of perylene pigments is selected from the group consisting of a pigment mixture of perylenes of structure 1 with perylenes of structure 2, a pigment mixture of perylenes of structure 1 and a pigment mixture of perylenes of structure 2, applying a uniform electrostatic charge to said photoconductive layer, selectively exposing said uniformly charged photoconductive layer to light so as to form an electrostatic latent image thereon, and developing said electrostatic latent image with electroscopic toner particles to render said latent image visible.

Claim 21

An electrophotographic imaging method as in claim 17, wherein said electrophotographic imaging element further includes a charge transport layer containing as a charge transporting agent, homogeneously distributed in an insulating binder, an azine having the general structural formula ##STR26## wherein R 5 and R 10 each represents a hydrogen atom or an alkyl group having from 1 to 4 carbon atoms.