Patent US5328995A successfully refreshed from Google Patents.
US5328995A
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Azo dyes containing triazine middle components and a 1,4-phenylene-2,5-disubstituted coupling component
Assignee: BASF Corp
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Filing: 1993-01-27
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Granted: 1994-07-12
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Expires: 2013-01-27
Abstract
Abstract The compounds of the formula ##STR1## where the substituents are as defined in claim 1, are direct dyes for various substrates, in particular cellulosic fibre materials. They are high temperature resistant and therefore are particularly highly suitable for the one-bath, single-stage dyeing of polyester/cotton blend fabrics with a disperse dye for the polyester fibres under the dyeing conditions for polyester fibres.
Inventors
- 👤 Rudolf Schaulin
- 👤 Urs Lauk
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 00:48
CPC Classifications
C; C09; C09B; C09B43/00; C09B43/11; C09B33/00; C09B33/02; C09B33/06; C09B43/12; C09B43/136; C09B43/16; C09B62/00; C09B62/02; C09B62/04; C09B62/043; C09B62/08; C09B62/09
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
314 words
A compound of the formula ##STR98## where R and R' are each independently of the other hydrogen or C 1 -C 4 alkyl, R 1 is chlorine, hydroxyl-substituted (in the alkyl moiety) N-mono- or N,N-di-C 1 -C 4 alkylamino, or morpholino, X is a bridge member of the formula ##STR99## where R 5 and R' 5 are each independently of the other hydrogen or C 1 -C 4 alkyl and R 6 and R' 6 are each independently of the other hydrogen, sulfo, methyl, methoxy or chlorine, n is 0 or 1, A is a radical of the formula ##STR100## where R 2 and R 3 are each independently of the other C 1 -C 4 alkyl, C 1 -C 4 alkoxy or unsubstituted or hydroxyl-substituted (in the alkyl moiety) C 2 -C 4 alkanoylamino and the phenyl radical (a) contains no further substituents or is further substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, halogen, hydroxyl, carboxyl, unsubstituted or hydroxyl-substituted C 2 -C 4 alkanoylamino or unsubstituted or sulfo-, C 1 -C 4 alkyl-, C 1 -C 4 alkoxy-, halogen- or hydroxyl-substituted 1- or 2-napthylazo or phenylazo, A' has the meaning A or is a radical of the formula ##STR101## where (R' 4 ) 0-2 represents from 0 to 2 identical or different radicals selected from the group consisting of methyl, methoxy, sulfo, chlorine, hydroxyl and carboxyl, (R 7 ) 1-3 represents from 1 to 3 identical or different substituents selected from the group consisting of sulfo, methyl, methoxy, chlorine and o-, m- or p-sulfophenylazo, R 8 is hydrogen, C 1 -C 4 alkyl or C 1 -C 4 alkoxy-C 1 -C 4 alkyl, R 9 is sulfomethyl, cyano or carbamoyl, and (R 10 ) 0-2 represents from 0 to 2 identical or different radicals selected from the group consisting of methyl, methoxy, sulfo, hydroxyl, amino, acetylamino and hydroxyacetylamino.
Claim 2
Dependent Claim
314 words
A compound of the formula ##STR98## where R and R' are each independently of the other hydrogen or C 1 -C 4 alkyl, R 1 is chlorine, hydroxyl-substituted (in the alkyl moiety) N-mono- or N,N-di-C 1 -C 4 alkylamino, or morpholino, X is a bridge member of the formula ##STR99## where R 5 and R' 5 are each independently of the other hydrogen or C 1 -C 4 alkyl and R 6 and R' 6 are each independently of the other hydrogen, sulfo, methyl, methoxy or chlorine, n is 0 or 1, A is a radical of the formula ##STR100## where R 2 and R 3 are each independently of the other C 1 -C 4 alkyl, C 1 -C 4 alkoxy or unsubstituted or hydroxyl-substituted (in the alkyl moiety) C 2 -C 4 alkanoylamino and the phenyl radical (a) contains no further substituents or is further substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, halogen, hydroxyl, carboxyl, unsubstituted or hydroxyl-substituted C 2 -C 4 alkanoylamino or unsubstituted or sulfo-, C 1 -C 4 alkyl-, C 1 -C 4 alkoxy-, halogen- or hydroxyl-substituted 1- or 2-napthylazo or phenylazo, A' has the meaning A or is a radical of the formula ##STR101## where (R' 4 ) 0-2 represents from 0 to 2 identical or different radicals selected from the group consisting of methyl, methoxy, sulfo, chlorine, hydroxyl and carboxyl, (R 7 ) 1-3 represents from 1 to 3 identical or different substituents selected from the group consisting of sulfo, methyl, methoxy, chlorine and o-, m- or p-sulfophenylazo, R 8 is hydrogen, C 1 -C 4 alkyl or C 1 -C 4 alkoxy-C 1 -C 4 alkyl, R 9 is sulfomethyl, cyano or carbamoyl, and (R 10 ) 0-2 represents from 0 to 2 identical or different radicals selected from the group consisting of methyl, methoxy, sulfo, hydroxyl, amino, acetylamino and hydroxyacetylamino.
Claim 3
Dependent Claim
13 words
A compound according to claim 1, wherein R and R' are each hydrogen.
Claim 4
Dependent Claim
14 words
A compound according to claim 1, wherein R 1 is N-β-hydroxyethylamino, N,N-di-β-hydroxyethylamino or morpholino.
Claim 5
Dependent Claim
10 words
A compound according to claim 1, wherein n is 1.
Claim 6
Dependent Claim
10 words
A compound according to claim 1, wherein n is 0.
Claim 7
Dependent Claim
26 words
A compound according to claim 1, wherein R 2 and R 3 are each independently of the other methyl, ethyl, methoxy, ethoxy, acetylamino, propionylamino or hydroxyacetylamino.
Claim 8
Dependent Claim
22 words
A compound according to claim 1, wherein R 2 and R 3 are each independently of the other methyl, methoxy, or acetylamino.
Claim 9
Dependent Claim
16 words
A compound according to claim 1, wherein R 2 is methoxy and R 3 is methyl.
Claim 10
Dependent Claim
44 words
A compound according to claim 1, wherein the phenyl radical (a) is unsubstituted or further substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, chlorine, hydroxyl, carboxyl, C 2 -C 3 alkanoylamino and/or unsubstituted or sulfo-, methyl-, methoxy- and/or chlorine-substituted phenylazo.
Claim 11
Dependent Claim
22 words
A compound according to claim 1, wherein the phenyl radical (a) is unsubstituted or further substituted by methyl, methoxy, acetylamino or chlorine.
Claim 12
Dependent Claim
17 words
A compound according to claim 1, wherein A and A' and R and R' are each identical.
Claim 13
Dependent Claim
118 words
A compound according to claim 1 of the formula ##STR102## where R" is hydrogen, methyl or ethyl, R' 1 is hydroxyl-substituted (in the alkyl moiety) N-mono- or N,N-di-C 1 -C 4 alkylamino or morpholino, A 1 is a radical of the formula ##STR103## where R' 2 and R' 3 are each independently of the other methyl, ethyl, methoxy, ethoxy, acetylamino, propionylamino or hydroxyacetylamino, and the phenyl radical (a) is as defined in claim 1, and A' 1 has the meaning A 1 or is a radical of the formula ##STR104## where (R' 4 ) 0-2 , (R 7 ) 1-3 , R 8 , R 9 and (R 10 ) 0-2 are each as defined in claim 1.
Claim 14
Dependent Claim
14 words
A compound according to claim 12, wherein A 1 and A' 1 are identical.
Claim 15
Dependent Claim
91 words
A compound according to claim 1 of the formula ##STR105## where R" 1 is hydroxyl-substituted (in the alkyl moiety) N-mono- or N,N-di-C 1 -C 2 alkylamino or morpholino, and A" 1 is a radical of the formula ##STR106## where R" 2 and R" 3 are each independently of the other methyl, methoxy or acetylamino, and the phenyl radical (a) is unsubstituted or further substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, chlorine, hydroxyl, carboxyl, C 2 -C 3 alkanoylamino or unsubstituted or sulfo-, methyl-, methoxy-or chlorine-substituted phenylazo.
Claim 16
Dependent Claim
33 words
A compound according to claim 1 of the formula ##STR107## where R" 1 is N-β-hydroxyethylamino, N,N-di-β-hydroxyethylamino or morpholino, and the phenyl radical is unsubstituted or further substituted by methyl, methoxy, acetylamino or chlorine.
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