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US5328995A Expired / Lapsed US ⏱️ 0.0 years remaining

Azo dyes containing triazine middle components and a 1,4-phenylene-2,5-disubstituted coupling component

Assignee: BASF Corp
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Filing: 1993-01-27
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Granted: 1994-07-12
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Expires: 2013-01-27
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Abstract

Abstract The compounds of the formula ##STR1## where the substituents are as defined in claim 1, are direct dyes for various substrates, in particular cellulosic fibre materials. They are high temperature resistant and therefore are particularly highly suitable for the one-bath, single-stage dyeing of polyester/cotton blend fabrics with a disperse dye for the polyester fibres under the dyeing conditions for polyester fibres.

Inventors

  • 👤 Rudolf Schaulin
  • 👤 Urs Lauk

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 23:58
CPC Classifications
C; C09; C09B; C09B43/00; C09B43/11; C09B33/00; C09B33/02; C09B33/06; C09B43/12; C09B43/136; C09B43/16; C09B62/00; C09B62/02; C09B62/04; C09B62/043; C09B62/08; C09B62/09

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 314 words
A compound of the formula ##STR98## where R and R' are each independently of the other hydrogen or C 1 -C 4 alkyl, R 1 is chlorine, hydroxyl-substituted (in the alkyl moiety) N-mono- or N,N-di-C 1 -C 4 alkylamino, or morpholino, X is a bridge member of the formula ##STR99## where R 5 and R' 5 are each independently of the other hydrogen or C 1 -C 4 alkyl and R 6 and R' 6 are each independently of the other hydrogen, sulfo, methyl, methoxy or chlorine, n is 0 or 1, A is a radical of the formula ##STR100## where R 2 and R 3 are each independently of the other C 1 -C 4 alkyl, C 1 -C 4 alkoxy or unsubstituted or hydroxyl-substituted (in the alkyl moiety) C 2 -C 4 alkanoylamino and the phenyl radical (a) contains no further substituents or is further substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, halogen, hydroxyl, carboxyl, unsubstituted or hydroxyl-substituted C 2 -C 4 alkanoylamino or unsubstituted or sulfo-, C 1 -C 4 alkyl-, C 1 -C 4 alkoxy-, halogen- or hydroxyl-substituted 1- or 2-napthylazo or phenylazo, A' has the meaning A or is a radical of the formula ##STR101## where (R' 4 ) 0-2 represents from 0 to 2 identical or different radicals selected from the group consisting of methyl, methoxy, sulfo, chlorine, hydroxyl and carboxyl, (R 7 ) 1-3 represents from 1 to 3 identical or different substituents selected from the group consisting of sulfo, methyl, methoxy, chlorine and o-, m- or p-sulfophenylazo, R 8 is hydrogen, C 1 -C 4 alkyl or C 1 -C 4 alkoxy-C 1 -C 4 alkyl, R 9 is sulfomethyl, cyano or carbamoyl, and (R 10 ) 0-2 represents from 0 to 2 identical or different radicals selected from the group consisting of methyl, methoxy, sulfo, hydroxyl, amino, acetylamino and hydroxyacetylamino.
Claim 2
Dependent Claim 314 words
A compound of the formula ##STR98## where R and R' are each independently of the other hydrogen or C 1 -C 4 alkyl, R 1 is chlorine, hydroxyl-substituted (in the alkyl moiety) N-mono- or N,N-di-C 1 -C 4 alkylamino, or morpholino, X is a bridge member of the formula ##STR99## where R 5 and R' 5 are each independently of the other hydrogen or C 1 -C 4 alkyl and R 6 and R' 6 are each independently of the other hydrogen, sulfo, methyl, methoxy or chlorine, n is 0 or 1, A is a radical of the formula ##STR100## where R 2 and R 3 are each independently of the other C 1 -C 4 alkyl, C 1 -C 4 alkoxy or unsubstituted or hydroxyl-substituted (in the alkyl moiety) C 2 -C 4 alkanoylamino and the phenyl radical (a) contains no further substituents or is further substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, halogen, hydroxyl, carboxyl, unsubstituted or hydroxyl-substituted C 2 -C 4 alkanoylamino or unsubstituted or sulfo-, C 1 -C 4 alkyl-, C 1 -C 4 alkoxy-, halogen- or hydroxyl-substituted 1- or 2-napthylazo or phenylazo, A' has the meaning A or is a radical of the formula ##STR101## where (R' 4 ) 0-2 represents from 0 to 2 identical or different radicals selected from the group consisting of methyl, methoxy, sulfo, chlorine, hydroxyl and carboxyl, (R 7 ) 1-3 represents from 1 to 3 identical or different substituents selected from the group consisting of sulfo, methyl, methoxy, chlorine and o-, m- or p-sulfophenylazo, R 8 is hydrogen, C 1 -C 4 alkyl or C 1 -C 4 alkoxy-C 1 -C 4 alkyl, R 9 is sulfomethyl, cyano or carbamoyl, and (R 10 ) 0-2 represents from 0 to 2 identical or different radicals selected from the group consisting of methyl, methoxy, sulfo, hydroxyl, amino, acetylamino and hydroxyacetylamino.
Claim 3
Dependent Claim 13 words
A compound according to claim 1, wherein R and R' are each hydrogen.
Claim 4
Dependent Claim 14 words
A compound according to claim 1, wherein R 1 is N-β-hydroxyethylamino, N,N-di-β-hydroxyethylamino or morpholino.
Claim 5
Dependent Claim 10 words
A compound according to claim 1, wherein n is 1.
Claim 6
Dependent Claim 10 words
A compound according to claim 1, wherein n is 0.
Claim 7
Dependent Claim 26 words
A compound according to claim 1, wherein R 2 and R 3 are each independently of the other methyl, ethyl, methoxy, ethoxy, acetylamino, propionylamino or hydroxyacetylamino.
Claim 8
Dependent Claim 22 words
A compound according to claim 1, wherein R 2 and R 3 are each independently of the other methyl, methoxy, or acetylamino.
Claim 9
Dependent Claim 16 words
A compound according to claim 1, wherein R 2 is methoxy and R 3 is methyl.
Claim 10
Dependent Claim 44 words
A compound according to claim 1, wherein the phenyl radical (a) is unsubstituted or further substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, chlorine, hydroxyl, carboxyl, C 2 -C 3 alkanoylamino and/or unsubstituted or sulfo-, methyl-, methoxy- and/or chlorine-substituted phenylazo.
Claim 11
Dependent Claim 22 words
A compound according to claim 1, wherein the phenyl radical (a) is unsubstituted or further substituted by methyl, methoxy, acetylamino or chlorine.
Claim 12
Dependent Claim 17 words
A compound according to claim 1, wherein A and A' and R and R' are each identical.
Claim 13
Dependent Claim 118 words
A compound according to claim 1 of the formula ##STR102## where R" is hydrogen, methyl or ethyl, R' 1 is hydroxyl-substituted (in the alkyl moiety) N-mono- or N,N-di-C 1 -C 4 alkylamino or morpholino, A 1 is a radical of the formula ##STR103## where R' 2 and R' 3 are each independently of the other methyl, ethyl, methoxy, ethoxy, acetylamino, propionylamino or hydroxyacetylamino, and the phenyl radical (a) is as defined in claim 1, and A' 1 has the meaning A 1 or is a radical of the formula ##STR104## where (R' 4 ) 0-2 , (R 7 ) 1-3 , R 8 , R 9 and (R 10 ) 0-2 are each as defined in claim 1.
Claim 14
Dependent Claim 14 words
A compound according to claim 12, wherein A 1 and A' 1 are identical.
Claim 15
Dependent Claim 91 words
A compound according to claim 1 of the formula ##STR105## where R" 1 is hydroxyl-substituted (in the alkyl moiety) N-mono- or N,N-di-C 1 -C 2 alkylamino or morpholino, and A" 1 is a radical of the formula ##STR106## where R" 2 and R" 3 are each independently of the other methyl, methoxy or acetylamino, and the phenyl radical (a) is unsubstituted or further substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, chlorine, hydroxyl, carboxyl, C 2 -C 3 alkanoylamino or unsubstituted or sulfo-, methyl-, methoxy-or chlorine-substituted phenylazo.
Claim 16
Dependent Claim 33 words
A compound according to claim 1 of the formula ##STR107## where R" 1 is N-β-hydroxyethylamino, N,N-di-β-hydroxyethylamino or morpholino, and the phenyl radical is unsubstituted or further substituted by methyl, methoxy, acetylamino or chlorine.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-07-11 1998-01-10 1998-07-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-07-11 2002-01-10 2002-07-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-07-11 2006-01-10 2006-07-12 $7700.00 Window Closed / Lapsed

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