Patent US1627264A successfully refreshed from Google Patents.
Patent US5326362A successfully refreshed from Google Patents.
US5326362A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of surface hardening orthopedic implant devices
Assignee: Zimmer Technology Inc
•
Filing: 1993-02-02
•
Granted: 1994-07-05
•
Expires: 2013-02-02
Abstract
Abstract A method of surface hardening titanium orthopedic implant devices, and a titanium orthopedic implant device prepared by the disclosed method. An orthopedic implant device made of pure titanium or a titanium alloy, such as Ti-6Al-4V (ELI) is exposed to molecular nitrogen gas at a process temperature and for a process time duration sufficient to enhance surface hardness and wear resistance properties, without the formation of a measurable TiN layer that tends to increase surface roughness and diminish wear resistance properties. The process temperature is in the range of 750° F. to 1300° F., preferably about 1100° F. and the process time duration at the preferred process temperature is approximately 8 hours. The hardened surface of the titanium implant occurs primarily due to solid solution hardening of the titanium with nitrogen by dissolution.
Inventors
- 👤 H. Ravindranath Shetty
- 👤 Walter H. Ottersberg
- 👤 Jack E. Parr
- 👤 Roy D. Crowninshield
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 11:53
CPC Classifications
C; C23; C23C; C23C8/00; C23C8/06; C23C8/08; C23C8/24; A; A61; A61F; A61F2/00; A61F2/02; A61F2/30; A61F2/30767; A61F2/3094; A61F2/32; A61F2/36; A61F2/3609; A61F2/3662; A61F2/367; A61F2/3676; A61F2/30771; A61F2002/3082; A61F2002/30922; A61F2310/00; A61F2310/00005; A61F2310/00011; A61F2310/00023; A61F2310/00389; A61F2310/00592; A61F2310/00598; A61F2310/00616; A61F2310/0073; A61F2310/00748; A61F2310/00856; A61F2310/0088; Y; Y10; Y10S; Y10S623/00; Y10S623/909
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
100 words
A method of manufacturing a titanium orthopedic implant device having enhanced surface hardness and wear resistance properties, comprising the steps of: providing a titanium substrate in the form of an orthopedic implant device; and hardening the surface of said titanium substrate by exposing said titanium substrate to an atmosphere of undiluted molecular nitrogen gas at a process temperature within the range of 750° F. to 1300° F. for a process time duration sufficient to achieve a hardened surface region characterized primarily by solid solution hardening of the surface of the titanium substrate by dissolution of nitrogen in said titanium substrate.
Claim 2
Independent Claim
100 words
A method of manufacturing a titanium orthopedic implant device having enhanced surface hardness and wear resistance properties, comprising the steps of: providing a titanium substrate in the form of an orthopedic implant device; and hardening the surface of said titanium substrate by exposing said titanium substrate to an atmosphere of undiluted molecular nitrogen gas at a process temperature within the range of 750° F. to 1300° F. for a process time duration sufficient to achieve a hardened surface region characterized primarily by solid solution hardening of the surface of the titanium substrate by dissolution of nitrogen in said titanium substrate.
Claim 3
Dependent Claim
15 words
The method of claim 1 in which said titanium substrate comprises commercially pure titanium (CP-Titanium).
Claim 4
Dependent Claim
14 words
The method of claim 1 in which said titanium substrate comprises a titanium alloy.
Claim 5
Dependent Claim
13 words
The method of claim 3 in which said titanium alloy is Ti-6Al-4V (ELI).
Claim 6
Dependent Claim
22 words
The method of claim 1 in which said process temperature is approximately 1100° F. and said process time is approximately eight hours.
Claim 7
Dependent Claim
46 words
The method of claim 1 in which said hardened surface region exhibits a peak nitrogen concentration within the range of 10 atomic percent to 50 atomic percent at a depth between 0.01 and 0.10 μm (100 and 1000 Å) below the surface of said titanium substrate.
Claim 8
Dependent Claim
82 words
The method of claim 1 in which said hardened surface region includes a hardened surface layer limited in thickness to a depth of approximately 0.20 μm (2000 Å) and a hardened diffusion region underneath said hardened surface layer, said surface layer comprising titanium nitride (Ti x N y ), titanium oxide (Ti x O y ), and titanium carbide (Ti x C y ), and said hardened diffusion region comprising a solid solution of nitrogen, oxygen, and carbon in said titanium substrate.
Claim 9
Independent Claim
103 words
A method of manufacturing a titanium orthopedic implant device having enhanced surface hardness and wear resistance properties, comprising the steps of: providing a titanium substrate in the form of an orthopedic implant device; and exposing said titanium substrate to an atmosphere of undiluted molecular nitrogen gas at a process temperature and for a process time duration sufficient to cause nitrogen dissolution in said titanium substrate without measurable formation of titanium nitride (TiN) on the surface of said titanium substrate, thereby enhancing the surface harness and wear resistance properties of said titanium substrate without increasing surface roughness that would diminish the wear resistance properties.
Claim 10
Independent Claim
103 words
A method of manufacturing a titanium orthopedic implant device having enhanced surface hardness and wear resistance properties, comprising the steps of: providing a titanium substrate in the form of an orthopedic implant device; and exposing said titanium substrate to an atmosphere of undiluted molecular nitrogen gas at a process temperature and for a process time duration sufficient to cause nitrogen dissolution in said titanium substrate without measurable formation of titanium nitride (TiN) on the surface of said titanium substrate, thereby enhancing the surface harness and wear resistance properties of said titanium substrate without increasing surface roughness that would diminish the wear resistance properties.
Claim 11
Dependent Claim
15 words
The method of claim 8 in which said titanium substrate comprises commercially pure titanium (CP-Titanium).
Claim 12
Dependent Claim
14 words
The method of claim 8 in which said titanium substrate comprises a titanium alloy.
Claim 13
Dependent Claim
13 words
The method of claim 10 in which said titanium alloy is Ti-5Al-4V (ELI).
Claim 14
Dependent Claim
20 words
The method of claim 8 in which said process temperature is in the range of 750° F. to 1300° F.
Claim 15
Dependent Claim
14 words
The method of claim 12 in which said process temperature is approximately 1100° F.
Claim 16
Dependent Claim
14 words
The method of claim 8 in which said process time is approximately eight hours.
Claim 17
Dependent Claim
22 words
The method of claim 8 in which said process temperature is approximately 1100° F. and said process time is approximately eight hours.
Claim 18
Dependent Claim
28 words
The method of claim 8 in which said atmosphere of molecular nitrogen gas is provided at a process pressure within the range of 1 psig to 2 psig.
Claim 19
Independent Claim
104 words
A method of increasing the surface hardness and wear resistance properties of an orthopedic implant device that is fabricated from a titanium material, comprising the steps of: providing a substrate of titanium material in the form of an orthopedic implant device; and exposing said substrate to an atmosphere of undiluted molecular nitrogen gas at a process temperature and for a process time duration sufficient to enhance both surface hardness and wear resistance properties of said substrate by nitrogen dissolution in said substrate without increasing surface roughness and thereby diminishing wear resistance properties by the measurable formation of TiN on the surface of said substrate.
Claim 20
Independent Claim
104 words
A method of increasing the surface hardness and wear resistance properties of an orthopedic implant device that is fabricated from a titanium material, comprising the steps of: providing a substrate of titanium material in the form of an orthopedic implant device; and exposing said substrate to an atmosphere of undiluted molecular nitrogen gas at a process temperature and for a process time duration sufficient to enhance both surface hardness and wear resistance properties of said substrate by nitrogen dissolution in said substrate without increasing surface roughness and thereby diminishing wear resistance properties by the measurable formation of TiN on the surface of said substrate.
Claim 21
Dependent Claim
20 words
The method of claim 17 in which said process temperature is in the range of 750° F. to 1300° F.
References Cited (Backward Citations)
US3643658A
Cited
US4040129A
Cited
FR2123207A1
Cited
CH585278A5
Cited
US4687487A
Cited
GB2154450A
Cited
US4768757A
Cited
US4790851A
Cited
US4693760A
Cited
US4855101A
Cited
JPS63241157A
Cited
EP0449793A1
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-07-04 | 1998-01-03 | 1998-07-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-07-04 | 2002-01-03 | 2002-07-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-07-04 | 2006-01-03 | 2006-07-05 | $7700.00 | Window Closed / Lapsed |