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US5325704A Expired / Lapsed US ⏱️ 0.0 years remaining

Surface acoustic wave (SAW) chemical multi-sensor array

Assignee: United States Department of the Army
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Filing: 1993-11-22
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Granted: 1994-07-05
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Expires: 2013-11-22
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Abstract

Abstract A sensor for chemical vapor detection using a surface acoustic wave (SAW) ray that provides a means for simultaneously detecting several chemical agents. The sensor has a piezoelectric substrate and a bidirectional surface acoustic wave transducer on the substrate. Also on the substrate are several pairs of identical acoustic sensing and reference channels each on opposite sides of the transducer in a mirror image fashion. Each channel pair has a thin film capable of absorbing a chemical vapor to be monitored and a metallic surface acoustic wave grating reflector capable of receiving and reflecting surface acoustic waves through the thin film and back to the transducer. An acoustic absorber separates each channel. The reference channels are protected from ambient conditions while the sensing channels are exposed to such conditions. An RF signal is applied to the transducer causing the propagation of an acoustic signal into each of the sensing channels and reference channels. Output signals from the transducer are then detected. The array is preferably in a miniature configuration which is suitable for wearing on a person's wrist or arm.

Inventors

  • 👤 Elio A. Mariani
  • 👤 William J. Skudera, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 10:47
CPC Classifications
G; G01; G01N; G01N29/00; G01N29/02; G01N29/022; G01N2291/00; G01N2291/02; G01N2291/021; G01N2291/0215; G01N2291/025; G01N2291/0256; G01N2291/028; G01N2291/02836; G01N2291/04; G01N2291/042; G01N2291/0422; G01N2291/0423; G01N2291/10; G01N2291/106; G01N30/00

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 249 words
A surface acoustic wave, multi-channel sensor which comprises a piezoelectric substrate; a bidirectional surface acoustic wave transducer disposed on the substrate; a plurality of pairs of acoustic sensing and reference channels, each pair member being substantially identical to its corresponding other pair member, the sensing channels being sequentially disposed on the substrate in juxtaposition with one side of the transducer and the reference channels being sequentially disposed on the substrate in juxtaposition with the other side of the transducer; each respective sensing channel and reference channel pair sequentially comprising a thin film whose composition is capable of absorbing a chemical vapor to be monitored, and a metallic surface acoustic wave grating reflector capable of receiving incident surface acoustic waves transmitted by the transducer through the thin film and reflecting them back again into the thin film to the transducer; for each channel pair, the reflector grating and thin film is spaced equidistantly from the center line of the bidirectional transducer such that each respective sensing channel and reference channel pair is a mirror image of the other; an acoustic absorber disposed on the substrate between each sensing channel and each reference channel; means for protecting each of the reference channels from ambient conditions and simultaneously exposing each of the sensing channels to ambient conditions; means for applying an RF signal to the transducer which causes the propagation of an acoustic signal into each of the sensing channels and reference channels; and means for detecting output signals from the transducer.
Claim 2
Dependent Claim 249 words
A surface acoustic wave, multi-channel sensor which comprises a piezoelectric substrate; a bidirectional surface acoustic wave transducer disposed on the substrate; a plurality of pairs of acoustic sensing and reference channels, each pair member being substantially identical to its corresponding other pair member, the sensing channels being sequentially disposed on the substrate in juxtaposition with one side of the transducer and the reference channels being sequentially disposed on the substrate in juxtaposition with the other side of the transducer; each respective sensing channel and reference channel pair sequentially comprising a thin film whose composition is capable of absorbing a chemical vapor to be monitored, and a metallic surface acoustic wave grating reflector capable of receiving incident surface acoustic waves transmitted by the transducer through the thin film and reflecting them back again into the thin film to the transducer; for each channel pair, the reflector grating and thin film is spaced equidistantly from the center line of the bidirectional transducer such that each respective sensing channel and reference channel pair is a mirror image of the other; an acoustic absorber disposed on the substrate between each sensing channel and each reference channel; means for protecting each of the reference channels from ambient conditions and simultaneously exposing each of the sensing channels to ambient conditions; means for applying an RF signal to the transducer which causes the propagation of an acoustic signal into each of the sensing channels and reference channels; and means for detecting output signals from the transducer.
Claim 3
Dependent Claim 25 words
The sensor of claim i wherein the piezoelectric substrate comprises a material selected from the group consisting of polished quartz, lithium niobate, and lithium tantalate.
Claim 4
Dependent Claim 24 words
The sensor of claim 1 wherein the acoustically absorbing material is selected from the group consisting of rubber, silicone, and room temperature vulcanizable material.
Claim 5
Dependent Claim 22 words
The sensor of claim 1 wherein the thin film comprises a material selected from the group consisting of poly(epichlorohydrin), polyisobutylene and fluoropolyols.
Claim 6
Dependent Claim 21 words
The sensor of claim 1 wherein the thin film material has a thickness of from about 2,000 to about 6,000 angstroms.
Claim 7
Dependent Claim 23 words
The sensor of claim 1 wherein the thin film material has a length and width ranging from about 0.01 to about 1.0 inch.
Claim 8
Dependent Claim 28 words
The sensor of claim 1 wherein the surface acoustic wave transducer comprises a layer of a metal having a thickness of from about 500 to about 2,000 angstroms.
Claim 9
Dependent Claim 19 words
The sensor of claim 1 wherein the surface acoustic wave transducer comprises aluminum, gold or aluminum alloyed with copper.
Claim 10
Dependent Claim 33 words
The sensor of claim 1 wherein the piezoelectric substrate has a length and width ranging from about 0.25 to about 2.0 inches and a thickness of from about 0.01 to about 0.03 inch.
Claim 11
Independent Claim 309 words
A method for detecting chemical contamination comprising the steps of: A.) providing a surface acoustic wave, multi-channel sensor which comprises a.) a piezoelectric substrate; b.) a bidirectional surface acoustic wave transducer disposed on the substrate; c.) a plurality of pairs of acoustic sensing and reference channels, each pair member being substantially identical to its corresponding other pair member, the sensing channels being sequentially disposed on the substrate in juxtaposition with one side of the transducer and the reference channels being sequentially disposed on the substrate in juxtaposition with the other side of the transducer; each respective sensing channel and reference channel pair sequentially comprising a thin film whose composition is capable of absorbing a chemical vapor to be monitored, and a metallic surface acoustic wave grating reflector capable of receiving incident surface acoustic waves transmitted by the transducer through the thin film and reflecting them back again into the thin film to the transducer; for each channel pair, the reflector grating and thin film is spaced equidistantly from the center line of the bidirectional transducer such that each respective sensing channel and reference channel pair is a mirror image of the other; d.) an acoustic absorber disposed on the substrate between each sensing channel and each reference channel; e.) means for protecting each of the reference channels from ambient conditions and simultaneously exposing each of the sensing channels to ambient conditions; f.) means for applying an RF signal to the transducer which causes the propagation of an acoustic signal into each of the sensing channels and reference channels; g.) means for detecting output signals from the transducer; and B.) applying an RF signal to the transducer and causing the propagation of an acoustic signal into each of the sensing channels and reference channels; and C.) detecting output signals from the sensing channels and the reference channels via the transducer.
Claim 12
Independent Claim 309 words
A method for detecting chemical contamination comprising the steps of: A.) providing a surface acoustic wave, multi-channel sensor which comprises a.) a piezoelectric substrate; b.) a bidirectional surface acoustic wave transducer disposed on the substrate; c.) a plurality of pairs of acoustic sensing and reference channels, each pair member being substantially identical to its corresponding other pair member, the sensing channels being sequentially disposed on the substrate in juxtaposition with one side of the transducer and the reference channels being sequentially disposed on the substrate in juxtaposition with the other side of the transducer; each respective sensing channel and reference channel pair sequentially comprising a thin film whose composition is capable of absorbing a chemical vapor to be monitored, and a metallic surface acoustic wave grating reflector capable of receiving incident surface acoustic waves transmitted by the transducer through the thin film and reflecting them back again into the thin film to the transducer; for each channel pair, the reflector grating and thin film is spaced equidistantly from the center line of the bidirectional transducer such that each respective sensing channel and reference channel pair is a mirror image of the other; d.) an acoustic absorber disposed on the substrate between each sensing channel and each reference channel; e.) means for protecting each of the reference channels from ambient conditions and simultaneously exposing each of the sensing channels to ambient conditions; f.) means for applying an RF signal to the transducer which causes the propagation of an acoustic signal into each of the sensing channels and reference channels; g.) means for detecting output signals from the transducer; and B.) applying an RF signal to the transducer and causing the propagation of an acoustic signal into each of the sensing channels and reference channels; and C.) detecting output signals from the sensing channels and the reference channels via the transducer.
Claim 13
Dependent Claim 20 words
The method of claim 10 wherein the RF signal has a frequency ranging from about 100 to about 1,000 megahertz.
Claim 14
Dependent Claim 19 words
The method of claim 10 wherein the output signals from the sensing channels and the reference channels are coherent.
Claim 15
Dependent Claim 21 words
The method of claim 10 wherein the output signals from the sensing channels and the reference channels are out of phase.
Claim 16
Dependent Claim 22 words
The method of claim 10 wherein the output signals from the sensing channels and the reference channels are 180° out of phase.
Claim 17
Dependent Claim 25 words
The method of claim 10 wherein the piezoelectric substrate comprises a material selected from the group consisting of polished quartz, lithium niobate, and lithium tantalate.
Claim 18
Dependent Claim 24 words
The method of claim 10 wherein the acoustically absorbing material is selected from the group consisting of rubber, silicone, and room temperature vulcanizable material.
Claim 19
Dependent Claim 22 words
The method of claim 10 wherein the thin film comprises a material selected from the group consisting of poly(epichlorohydrin), polyisobutylene and fluoropolyols.
Claim 20
Dependent Claim 34 words
The method of claim 10 wherein the thin film material has a thickness of from about 2,000 to about 6,000 angstroms and a length and width ranging from about 0.01 to about 1.0 inch.
Claim 21
Dependent Claim 28 words
The method of claim 10 wherein the surface acoustic wave transducer comprises a layer of a metal having a thickness of from about 500 to about 2,000 angstroms.
Claim 22
Dependent Claim 19 words
The method of claim 10 wherein the surface acoustic wave transducer comprises aluminum, gold or aluminum alloyed with copper.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-07-04 1998-01-03 1998-07-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-07-04 2002-01-03 2002-07-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-07-04 2006-01-03 2006-07-05 $7700.00 Window Closed / Lapsed

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