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Reusable, positive-charging organic photoconductor containing phthalocyanine pigment, hydroxy binder and silicon stabilizer

Assignee: Hewlett Packard Development Co LP
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Filing: 1993-01-28
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Granted: 1994-06-14
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Expires: 2013-01-28
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Abstract

Abstract An organic, positive-charging photoconductor for laser printers is disclosed. The photoconductor has a conductive substrate, a hydroxy-containing binder which forms a layer greater than or equal to about 1 micron thick on the substrate, a phthalocyanine pigment uniformly distributed throughout said binder, and a reactive stabilizer containing silicon, also uniformly distributed throughout said binder. The silicon-containing stabilizer reacts with the hydroxy group in the binder, the effect of which is to improve the electrical stability of the photoconductor in the severe laser printing electrophotographic environment, and to improve surface release characteristics of the photoconductor for more efficient toner image transfer.

Inventors

  • 👤 Khe C. Nguyen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 15:15
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/05; G03G5/0528; G03G5/0592; G03G5/0503; G03G5/051; G03G5/0514; G03G5/0517; G03G5/0557; G03G5/0578; G03G5/06; G03G5/0664; G03G5/0696

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 151 words
An organic photoconductor for positive charging, said photoconductor having improved surface release characteristics, and comprising: a conductive substrate component; a water insoluble hydroxy-containing binder component forming a layer greater than or equal to about 1 micron thick on said substrate; a phthalocyanine pigment component having the general structure: M--PcX.sub.n (A) where M=hydrogen (metal free), Cu, Mg, Zn, TiO, VO, InY (Y=halogen, Cl, Br, l, F) X=halogen (Cl, Br, l, F), nitro --NO 2 , cyano--CN, sulfonyl --SO 2 alkyl, alkoxy, and N=0-4, said phthalocyanine pigment being uniformly distributed throughout said binder component; a reactive stabilizer component selected from the group of polysiloxanes, organo-silane compounds and porous fillers containing silicon atoms, said reactive stabilizer component also being uniformly distributed throughout said binder component; and, said photoconductor being prepared by a curing process which includes thermal curing, moisture or hydrolysis curing, and radiation curing, the latter including UV, X-ray and electron beam curing.
Claim 2
Dependent Claim 151 words
An organic photoconductor for positive charging, said photoconductor having improved surface release characteristics, and comprising: a conductive substrate component; a water insoluble hydroxy-containing binder component forming a layer greater than or equal to about 1 micron thick on said substrate; a phthalocyanine pigment component having the general structure: M--PcX.sub.n (A) where M=hydrogen (metal free), Cu, Mg, Zn, TiO, VO, InY (Y=halogen, Cl, Br, l, F) X=halogen (Cl, Br, l, F), nitro --NO 2 , cyano--CN, sulfonyl --SO 2 alkyl, alkoxy, and N=0-4, said phthalocyanine pigment being uniformly distributed throughout said binder component; a reactive stabilizer component selected from the group of polysiloxanes, organo-silane compounds and porous fillers containing silicon atoms, said reactive stabilizer component also being uniformly distributed throughout said binder component; and, said photoconductor being prepared by a curing process which includes thermal curing, moisture or hydrolysis curing, and radiation curing, the latter including UV, X-ray and electron beam curing.
Claim 3
Dependent Claim 39 words
The photoconductor of claim 1 wherein the hydroxy-containing binder is selected from the group of polyvinyl acetals, phenolic resins, phenoxy resins, cellulose and its derivatives, copolymers of vinyl alcohol, hydroxylated polymers, and copolymers of hydroxy monomers and silicon resins.
Claim 4
Dependent Claim 28 words
The photoconductor of claim 1 wherein the phthalocyanine pigment has a particle size of less than one micron with absorption maxima in the infrared or near infrared range.
Claim 5
Dependent Claim 21 words
The photoconductor of claim 1 wherein the phthalocyanine pigment component is a combination of two or more types of phthalocyanine pigments.
Claim 6
Dependent Claim 52 words
The photoconductor of claim 1 wherein the reactive stabilizer component is a polysiloxane selected from the group having the general formula: ##STR14## Where R 1 , R 2 =hydrogen, hydroxy --OH, amino --NH 2 , alkyl, amino-alkyl, carboxylic, carbinol, aryl, arylamino; R 3 , R 4 =hydrogen, alkyl, fluoroalkyl, aryl, and n>50.
Claim 7
Dependent Claim 18 words
The photoconductor of claim 5 wherein the polysiloxane is a combination of two or more types of polysiloxanes.
Claim 8
Dependent Claim 53 words
The photoconductor of claim 1 wherein the reactive stabilizer component is an organo-silane compound selected from the group having the general formula: ##STR15## Where R 1 , R 2 , R 3 , R 4 =hydrogen, alky, alkoxy, aryl, alkene, amino, halogen, hydroxy, carboxilic, acetate, alkene, oxide, mercapto, ether, fluoroalkyl, cyano and cyanoalkyl.
Claim 9
Dependent Claim 20 words
The photoconductor of claim 7 wherein the organo-silane compound is a combination of two or more types of organo-silane compounds.
Claim 10
Dependent Claim 29 words
The photoconductor of claim 1 wherein the porous fillers containing silicon atoms are selected from the group of hydrophillic colloidal silica, hydrophobic colloidal silica, SiC powder and SiN powder.
Claim 11
Dependent Claim 20 words
The photoconductor of claim 9 wherein the porous filler is a combination of two or more types of porous fillers.
Claim 12
Dependent Claim 22 words
The photoconductor of claim 1 wherein the solution for coating has been kept calm for at least 3 days prior to coating.
Claim 13
Dependent Claim 31 words
The photoconductor of claim 1 wherein the phthalocyanine pigment component is present in the range of about 8 wt. % to about 50 wt. % relative to the hydroxy-containing binder component.
Claim 14
Dependent Claim 31 words
The photoconductor of claim 1 wherein the reactive stabilizer component is present in the range of about 0.0015 wt. % to about 95 wt. %, relative to the hydroxy-containing binder component.
Claim 15
Dependent Claim 22 words
The photoconductor of claim 1 wherein the hydroxy-containing binder layer is formed on the substrate from a solution containing an alcohol component.
Claim 16
Dependent Claim 19 words
The photoconductor of claim 1 wherein the phthalocyanine pigment component is formed from a premixed suspension with a solvent.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-06-13 1997-12-13 1998-06-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-06-13 2001-12-13 2002-06-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-06-13 2005-12-13 2006-06-14 $7700.00 Window Closed / Lapsed

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