US5318722A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Hole-trap-compensated scintillator material
Assignee: General Electric Co
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Filing: 1992-10-13
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Granted: 1994-06-07
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Expires: 2012-10-13
Abstract
Abstract Afterglow in a luminescent material in which a significant factor in afterglow is the release of holes from hole traps in the scintillator material is substantially reduced by adding a hole-trapping species to the scintillator composition which successfully competes with the hole traps in the basic scintillator composition. In gadolinium gallium garnet activated with chromium, the addition of cerium, terbium or praseodymium reduces afterglow in this manner.
Inventors
- 👤 Veneta G. Tsoukala
- 👤 Charles D. Greskovich
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 17:53
CPC Classifications
G; G01; G01T; G01T1/00; G01T1/16; G01T1/20; G01T1/202; G01T1/2023; C; C04; C04B; C04B35/00; C04B35/01; C04B35/622; C04B35/64; C04B35/645; C04B35/6455; C09; C09K; C09K11/00; C09K11/08; C09K11/77; C09K11/7766; C09K11/7776; C04B2235/00; C04B2235/02; C04B2235/30; C04B2235/32; C04B2235/3224; C04B2235/3229; C04B2235/3231; C04B2235/3241; C04B2235/3286; C04B2235/60; C04B2235/604; C04B2235/65; C04B2235/656; C04B2235/6562; C04B2235/658; C04B2235/6583; C04B2235/6585; C04B2235/6587; C04B2235/66; C04B2235/661; C04B2235/662; C04B2235/663; C04B2235/70; C04B2235/74; C04B2235/76; C04B2235/762; C04B2235/764; C04B2235/96; C04B2235/9646; C04B2235/9653
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
135 words
A crystalline scintillator composition consisting of: gadolinium gallium garnet having the formula Gd 3 Ga 5 O 12 : chromium in a concentration in said garnet equivalent to chromium oxide being between 0.05 and 1.0 weight percent of the overall scintillator composition which is effective to render said scintillator composition luminescent in response to high-energy stimulating radiation consisting of X-rays, neutrons or alpha particles; and a hole trapping species, cerium, in a concentration in said garnet of less than 0.2 weight percent of the overall scintillator composition which is effective to reduce the afterglow level relative to the afterglow level of said scintillator composition in the absence of said hole trapping species; said chromium being substituted in said formula for said Ga and said hole trapping species being substituted in said formula for said Gd.
Claim 2
Dependent Claim
135 words
A crystalline scintillator composition consisting of: gadolinium gallium garnet having the formula Gd 3 Ga 5 O 12 : chromium in a concentration in said garnet equivalent to chromium oxide being between 0.05 and 1.0 weight percent of the overall scintillator composition which is effective to render said scintillator composition luminescent in response to high-energy stimulating radiation consisting of X-rays, neutrons or alpha particles; and a hole trapping species, cerium, in a concentration in said garnet of less than 0.2 weight percent of the overall scintillator composition which is effective to reduce the afterglow level relative to the afterglow level of said scintillator composition in the absence of said hole trapping species; said chromium being substituted in said formula for said Ga and said hole trapping species being substituted in said formula for said Gd.
Claim 3
Dependent Claim
22 words
The scintillator composition recited in claim 1 wherein: said weight percentage of chromium equivalent to chromium oxide is between 0.1 and 0.6.
Claim 4
Dependent Claim
18 words
The scintillator compositions recited in claim 1 wherein: said weight percent of cerium is between 0.01 and 0.15.
Claim 5
Dependent Claim
22 words
The scintillator composition recited in claim 1 wherein: said cerium is present in a concentration of between 0.005 and 0.2 weight percent.
Claim 6
Dependent Claim
18 words
The scintillator composition recited in claim 4, wherein: said weight percent of cerium is between 0.01 and 0.1.
Claim 7
Dependent Claim
13 words
The scintillator composition recited in claim 1 wherein: said scintillator composition is polycrystalline.
Claim 8
Dependent Claim
13 words
The scintillator composition recited in claim 6 wherein: said scintillator composition is transparent.
Claim 9
Dependent Claim
125 words
A scintillator composition consisting of: gadolinium gallium garnet having the formula Gd 3 Ga 5 O 12 ; chromium in a concentration equivalent to chromium oxide being between 0.05 and 1.0 weight percent of the overall scintillator composition; and a hole trapping species selected from the group consisting of cerium, terbium, praseodymium and mixtures thereof present in said gadolinium gallium garnet in a concentration between about 0.005 and about 0.15 weight percent of the overall scintillator composition which is effective to reduce the afterglow level relative to the afterglow level of said scintillator composition in the absence of said hole trapping species; said chromium being substituted in said formula for said Ga and said hole trapping species being substituted in said formula for said Gd.
Claim 10
Dependent Claim
125 words
A scintillator composition consisting of: gadolinium gallium garnet having the formula Gd 3 Ga 5 O 12 ; chromium in a concentration equivalent to chromium oxide being between 0.05 and 1.0 weight percent of the overall scintillator composition; and a hole trapping species selected from the group consisting of cerium, terbium, praseodymium and mixtures thereof present in said gadolinium gallium garnet in a concentration between about 0.005 and about 0.15 weight percent of the overall scintillator composition which is effective to reduce the afterglow level relative to the afterglow level of said scintillator composition in the absence of said hole trapping species; said chromium being substituted in said formula for said Ga and said hole trapping species being substituted in said formula for said Gd.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1997-06-06 | 1997-12-06 | 1998-06-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-06-06 | 2001-12-06 | 2002-06-07 | $3760.00 | Window Closed / Lapsed |
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