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Syndiotactic hot melt adhesive

Assignee: ExxonMobil Chemical Patents Inc
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Filing: 1992-08-25
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Granted: 1994-05-31
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Expires: 2012-08-25
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Abstract

Abstract A hot melt adhesive including syndiotactic polypropylene having a polymer chain of at least 80% racemic dyads and having a melting point of about 100° C. to 180° C.

Inventors

  • 👤 Patrick Brant
  • 👤 Kenneth O. McElrath, Jr.
  • 👤 Martha H. Robertson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 23:32
CPC Classifications
C; C09; C09J; C09J123/00; C09J123/02; C09J123/10; C08; C08L; C08L2666/00; C08L2666/02

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 44 words
A hot melt adhesive comprising tackifier and syndiotactic propylene homopolymer or copolymer, said homopolymer or the propylene segment of the copolymer comprising at least about 80% racemic dyads and said homopolymer or copolymer having a melting point of from 100° C. to 180° C.
Claim 2
Dependent Claim 44 words
A hot melt adhesive comprising tackifier and syndiotactic propylene homopolymer or copolymer, said homopolymer or the propylene segment of the copolymer comprising at least about 80% racemic dyads and said homopolymer or copolymer having a melting point of from 100° C. to 180° C.
Claim 3
Dependent Claim 22 words
The hot melt adhesive of claim 1, wherein said homopolymer or propylene segment of the copolymer comprises at least 85% racemic dyads.
Claim 4
Dependent Claim 13 words
The hot melt adhesive of claim 1, wherein said copolymer comprises ethylene comonomer.
Claim 5
Dependent Claim 21 words
The hot melt adhesive of claim 1, wherein the comonomer of the copolymer is a C 4 to C 12 alpha-olefin.
Claim 6
Dependent Claim 23 words
The hot melt adhesive of claim 1, wherein the copolymer comonomer is selected from the group consisting of 1-pentene, 1-hexene, 1-heptene and 1-octene.
Claim 7
Dependent Claim 12 words
The hot melt adhesive of claim 1, wherein said copolymer comprises 1-hexene.
Claim 8
Dependent Claim 18 words
The hot melt adhesive of claim 4, wherein said copolymer comprises 1 to 50 weight % of comonomer.
Claim 9
Dependent Claim 18 words
The hot melt adhesive of claim 4, wherein said copolymer comprises 3 to 20 weight % of comonomer.
Claim 10
Dependent Claim 21 words
The hot melt adhesive of claim 4, wherein the comonomer is hexene-1 and is present at 3 to 20 weight %.
Claim 11
Dependent Claim 17 words
The hot melt adhesive of claim 1, wherein the copolymer comprises 5 to 18 weight % hexene-1.
Claim 12
Dependent Claim 18 words
The hot melt adhesive of claim 1, wherein the tackifier is present at 1 to 70 weight %.
Claim 13
Dependent Claim 16 words
The adhesive of claim 1, wherein the tackifier is present at 40 to 60 weight %.
Claim 14
Dependent Claim 12 words
The adhesive of claim 1, wherein the tackifier is a hydrogenated resin.
Claim 15
Dependent Claim 13 words
The adhesive of claim 1, wherein the tackifier is a hydrogenated cyclic resin.
Claim 16
Dependent Claim 23 words
The adhesive of claim 1, wherein the tackifier is an aliphatic resin with a softening point of about 12° to about 100° C.
Claim 17
Dependent Claim 14 words
The adhesive of claim 1, where the syndiotactic propylene homopolymer or copolymer is deashed.
Claim 18
Dependent Claim 15 words
The holt melt adhesive of claim 1, wherein the propylene polymer is said propylene homopolymer.
Claim 19
Dependent Claim 65 words
A hot melt adhesive produced by a process comprising combining tackifier with syndiotactic propylene homopolymer or copolymer, said homopolymer or the propylene segment of the copolymer comprising at least about 80% racemix dyads and said homopolymer or copolymer further having a melting point of from 100° to 180° C. wherein the hot melt adhesive is characterized by an open time of 5 minutes or more.
Claim 20
Dependent Claim 65 words
A hot melt adhesive produced by a process comprising combining tackifier with syndiotactic propylene homopolymer or copolymer, said homopolymer or the propylene segment of the copolymer comprising at least about 80% racemix dyads and said homopolymer or copolymer further having a melting point of from 100° to 180° C. wherein the hot melt adhesive is characterized by an open time of 5 minutes or more.
Claim 21
Dependent Claim 28 words
The product of claim 18, wherein the hot melt adhesive is characterized by a peel strength after 24 hours at or above the peel strength at 10 minutes.
Claim 22
Dependent Claim 30 words
The product of claim 18, wherein the hot melt adhesive is characterized by a peel strength after 24 hours about the same or above the peel strength at 10 minutes.
Claim 23
Dependent Claim 22 words
The product of claim 18, wherein the hot melt adhesive is characterized by an open time of about ten minutes or more.

References Cited (Backward Citations)

US3258455A Cited
US3305538A Cited
US3700758A Cited
US4937138A Cited
US4892851A Cited
EP0351392A2 Cited
EP0387691A1 Cited
EP0387690A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-05-30 1997-11-29 1998-05-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-05-30 2001-11-29 2002-05-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-05-30 2005-11-29 2006-05-31 $7700.00 Window Closed / Lapsed

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