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US5314953A Expired / Lapsed US ⏱️ 0.0 years remaining

Clear coating composition for clear coat/color coat finish

Assignee: EIDP Inc
•
Filing: 1993-09-08
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Granted: 1994-05-24
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Expires: 2013-09-08
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Abstract

Abstract A improved process for applying a clear coat/color coat composition to a substrate in which a color coat is applied to a substrate and then a clear coat is applied over the color coat; the improvement used therewith is a clear coating composition having a film forming binder solids content of about 30-70% by weight and an organic liquid carrier, wherein the binder contains about (A) 50-80% by weight, based on the weight of the binder, of an acrylic polymer of polymerized monomers of styrene, a methacrylate monomer from the group of methyl methacrylate, isobornyl methacrylate, cyclohexyl methacrylate or any mixtures thereof, a second methacrylate monomer from the group of n-butyl methacrylate, isobutyl methacrylate or ethyl hexyl methacrylate or any mixtures thereof and a hydroxy alkyl methacrylate or acrylate each having 1-4 carbon atoms in the alkyl group, where the polymer has a number average molecular weight of about 5,000-20,000 determined by gel permeation chromatography and a calculated Tg of at least 40° C. and correspondingly, (B) 20-50% by weight, based on the weight of the binder, of an organic polyisocyanate; wherein the clear coating composition on curing is in a tack free state within 3 hours after application and has a Persoz hardness of at least 30 counts.

Inventors

  • 👤 Patrick H. Corcoran
  • 👤 Gary W. Nickel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 15:25
CPC Classifications
B; B05; B05D; B05D7/00; B05D7/50; B05D7/52; B05D7/53; B05D7/532; C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/62; C08G18/6216; C08G18/622; C08G18/6225; C08G18/6229; C09; C09D; C09D175/00; C09D175/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31605

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 178 words
A clear coating composition having a film forming binder solids content of about 30-70% by weight and an organic liquid carrier, wherein the binder consists essentially of about (A) 50-80% by weight, based on the weight of the binder, of an acrylic polymer consisting essentially of polymerized monomers of styrene, a methacrylate monomer selected from the group consisting of methyl methacrylate, isobornyl methacrylate, cyclohexyl methacrylate or any mixtures thereof, a second methacrylate monomer selected from the group consisting of n-butyl methacrylate, isobutyl methacrylate or ethyl hexyl methacrylate or any mixtures thereof and a hydroxy alkyl methacrylate or hydroxy alkyl acrylate each having 1-4 carbon atoms in the alkyl group; wherein the acrylic polymer has a number average molecular weight of about 5,000-20,000 determined by gel permeation chromatography and a calculated Tg of at least 40° C. and correspondingly, (B) 20-50% by weight, based on the weight of the binder, of an organic polyisocyanate; wherein the coating composition cures to a tack free state within 3 hours of application and to a Persoz hardness of at least 30 counts.
Claim 2
Dependent Claim 178 words
A clear coating composition having a film forming binder solids content of about 30-70% by weight and an organic liquid carrier, wherein the binder consists essentially of about (A) 50-80% by weight, based on the weight of the binder, of an acrylic polymer consisting essentially of polymerized monomers of styrene, a methacrylate monomer selected from the group consisting of methyl methacrylate, isobornyl methacrylate, cyclohexyl methacrylate or any mixtures thereof, a second methacrylate monomer selected from the group consisting of n-butyl methacrylate, isobutyl methacrylate or ethyl hexyl methacrylate or any mixtures thereof and a hydroxy alkyl methacrylate or hydroxy alkyl acrylate each having 1-4 carbon atoms in the alkyl group; wherein the acrylic polymer has a number average molecular weight of about 5,000-20,000 determined by gel permeation chromatography and a calculated Tg of at least 40° C. and correspondingly, (B) 20-50% by weight, based on the weight of the binder, of an organic polyisocyanate; wherein the coating composition cures to a tack free state within 3 hours of application and to a Persoz hardness of at least 30 counts.
Claim 3
Dependent Claim 25 words
The composition of claim 1 in which the acrylic polymer consists essentially of polymerized monomers of styrene, methyl methacrylate, isobutyl methacrylate and hydroxy ethyl methacrylate.
Claim 4
Dependent Claim 25 words
The composition of claim 1 in which the acrylic polymer consists essentially of polymerized monomers of styrene, methyl methacrylate, n-butyl methacrylate and hydroxy ethyl methacrylate.
Claim 5
Dependent Claim 55 words
The composition of claim 2 in which the acrylic polymer consists essentially of polymerized monomers of 5-20% by weight, based on the weight of the polymer, of styrene, 10-30% by weight of methyl methacrylate, 30-60% by weight of isobutyl methacrylate and 10-30% by weight hydroxy ethyl methacrylate where the total of the monomer equals 100%.
Claim 6
Dependent Claim 16 words
The composition of claim 2 in which the organic polyisocyanate is an aliphatic or cycloaliphatic polyisocyanate.
Claim 7
Dependent Claim 16 words
The composition of claim 5 in which the organic polyisocyanate is the trimer of hexamethylene diisocyanate.
Claim 8
Dependent Claim 28 words
The composition of claim 1 in which the composition contains about 0.01-2% by weight of the binder, of a catalyst of triethylene diamine and an alkyl tin laurate.
Claim 9
Dependent Claim 21 words
The composition of claim 1 in which the clear composition contains about 0.1-10% by weight of ultraviolet light absorbers and antioxidants.
Claim 10
Dependent Claim 15 words
A substrate coated with a dried and cured layer of the composition of claim 1.

References Cited (Backward Citations)

US3639147A Cited
US4246368A Cited
US4710543A Cited
US4728543A Cited
US4808656A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-05-23 1997-11-22 1998-05-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-05-23 2001-11-22 2002-05-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-05-23 2005-11-22 2006-05-24 $7700.00 Window Closed / Lapsed

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