US5310507A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of making a conductive polymer selective species sensor
Assignee: Physical Sciences Inc
•
Filing: 1992-08-13
•
Granted: 1994-05-10
•
Expires: 2012-08-13
Abstract
Abstract A selective chemical species detector including a conductive polymer based sensing element having a detectable characteristic, for example, the polymer resistivity, permanently altered on exposure to a first chemical species and not permanently altered on exposure to a second chemical species. The detector then determines a permanent change in the detected characteristic and indicates the presence of a chemical species on detection of a such a permanent characteristic change. Also disclosed is a method of fabricating such a sensing element to achieve the desired selectivity.
Inventors
- 👤 Mitchell R. Zakin
- 👤 Lawrence S. Bernstein
- 👤 Richard A. Moody
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 05:52
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/02; G01N27/04; G01N27/12; G01N27/125; G01N27/126
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
180 words
A method of fabricating a selective species sensing element for irreversibly detecting the exposure of said sensing element to a first compensating agent in the presence of a second compensating agent, comprising the steps of: providing a polymer material made conductive with a polymer dopant; determining the doped material permanent saturation resistivity toward the first and second compensating agents in which the permanent saturation resistivity toward the second compensating agent is lower than that towards the first; and permanently adjusting, prior to detecting the exposure of said sensing element to said first compensating agent in the presence of said second compensating agent, the doped material resistivity to be at least that of the second compensating agent doped material permanent saturation resistivity and less than the first compensating agent doped material permanent saturation resistivity so that the adjusted material resistivity permanently changes on exposure to the first compensating agent and not on exposure to the second compensating agent for selective detection of the first compensating agent in the presence of the second compensating agent by monitoring of permanent material resistivity change.
Claim 2
Independent Claim
180 words
A method of fabricating a selective species sensing element for irreversibly detecting the exposure of said sensing element to a first compensating agent in the presence of a second compensating agent, comprising the steps of: providing a polymer material made conductive with a polymer dopant; determining the doped material permanent saturation resistivity toward the first and second compensating agents in which the permanent saturation resistivity toward the second compensating agent is lower than that towards the first; and permanently adjusting, prior to detecting the exposure of said sensing element to said first compensating agent in the presence of said second compensating agent, the doped material resistivity to be at least that of the second compensating agent doped material permanent saturation resistivity and less than the first compensating agent doped material permanent saturation resistivity so that the adjusted material resistivity permanently changes on exposure to the first compensating agent and not on exposure to the second compensating agent for selective detection of the first compensating agent in the presence of the second compensating agent by monitoring of permanent material resistivity change.
Claim 3
Independent Claim
167 words
A method of fabricating a selective species sensing element for irreversibly detecting the exposure of said sensing element to a first dopant in the presence of a second dopant, comprising the steps of: providing a conductive polymer material made conductive with a polymer dopant; determining the material permanent saturation conductivity toward the first and second dopants, in which the permanent saturation conductivity toward the second dopant is lower than that toward the first; and permanently adjusting, prior to detecting the exposure of said sensing element to said first dopant in the presence of said second dopant, the polymer material conductivity to be at least that of the second dopant polymer material permanent saturation conductivity and less than the first dopant polymer material permanent saturation conductivity so that the adjusted material conductivity permanently changes on exposure to the first dopant and not on exposure to the second dopant for selective detection of the first in the presence of the second dopant by monitoring of permanent material conductivity change.
Claim 4
Independent Claim
167 words
A method of fabricating a selective species sensing element for irreversibly detecting the exposure of said sensing element to a first dopant in the presence of a second dopant, comprising the steps of: providing a conductive polymer material made conductive with a polymer dopant; determining the material permanent saturation conductivity toward the first and second dopants, in which the permanent saturation conductivity toward the second dopant is lower than that toward the first; and permanently adjusting, prior to detecting the exposure of said sensing element to said first dopant in the presence of said second dopant, the polymer material conductivity to be at least that of the second dopant polymer material permanent saturation conductivity and less than the first dopant polymer material permanent saturation conductivity so that the adjusted material conductivity permanently changes on exposure to the first dopant and not on exposure to the second dopant for selective detection of the first in the presence of the second dopant by monitoring of permanent material conductivity change.
Claim 5
Dependent Claim
26 words
The method of claim 1 in which the conductive polymer material is selected from the group consisting of polythiophene, polyaniline, polypyrrole, polyacetylene, polydiacetylene, and their derivatives.
Claim 6
Dependent Claim
26 words
The method of claim 2 in which the conductive polymer material is selected from the group consisting of polythiophene, polyaniline, polypyrrole, polyacetylene, polydiacetylene, and their derivatives.
Claim 7
Dependent Claim
18 words
The method of claim 1 in which the doped polymer resistivity is adjusted with a polymer compensating agent.
Claim 8
Dependent Claim
17 words
The method of claim 2 in which the doped polymer conductivity is adjusted with a polymer dopant.
References Cited (Backward Citations)
US4204216A
Cited
US4222903A
Cited
US4334880A
Cited
US4721601A
Cited
US4638286A
Cited
US4911801A
Cited
US4735692A
Cited
US5028394A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-05-09 | 1997-11-08 | 1998-05-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-05-09 | 2001-11-08 | 2002-05-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-05-09 | 2005-11-08 | 2006-05-10 | $7700.00 | Window Closed / Lapsed |