US5308412A
Expired / Lapsed
US
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Method of surface hardening cobalt-chromium based alloys for orthopedic implant devices
Assignee: Zimmer Technology Inc
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Filing: 1993-03-15
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Granted: 1994-05-03
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Expires: 2013-03-15
Abstract
Abstract A method of surface hardening cobalt-chromium based orthopedic implant devices, and a cobalt-chromium orthopedic implant device prepared by the disclosed method. An orthopedic implant device made of a cobalt-chromium or cobalt-chromium-molybdenum alloy, such as ASTM F-75 or ASTM F-799 is exposed to molecular nitrogen gas or ionized nitrogen at a process temperature and for a process time duration sufficient to enhance surface hardness and wear resistance properties, without the formation of a measurable nitrogen layer that tends to increase surface roughness and brittleness and diminish wear resistance properties. The process temperature is in the range of 500° F. to 2400° F., preferably about 1400° F., and the process time duration at the preferred process temperature is approximately 48 hours. The hardened surface of the cobalt-chromium-molybdenum implant occurs primarily due to nitride formation and solid solution hardening of the cobalt-chromium-molybdenum with nitrogen and oxygen, by dissolution.
Inventors
- 👤 H. Ravindranath Shetty
- 👤 Walter H. Ottersberg
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 12:44
CPC Classifications
A; A61; A61L; A61L27/00; A61L27/02; A61L27/04; A61L27/045; A61F; A61F2/00; A61F2/02; A61F2/30; A61F2/30767; C; C23; C23C; C23C8/00; C23C8/06; C23C8/28; C23C8/34; A61F2/3094; A61F2/32; A61F2/36; A61F2/3609; A61F2/3662; A61F2/367; A61F2/3676; A61F2002/30001; A61F2002/30316; A61F2002/30317; A61F2002/30322; A61F2002/30667; A61F2002/30682; A61F2002/30685; A61F2/30771; A61F2002/3082; A61F2002/30922; A61F2002/30934; A61F2250/00; A61F2250/0014; A61F2250/0026; A61F2310/00; A61F2310/00005; A61F2310/00011; A61F2310/00029; A61F2310/00389; A61F2310/00592; A61F2310/00598; A61F2310/00622; A61F2310/0073; A61F2310/00754; A61F2310/00856; A61F2310/00886; Y; Y10; Y10S; Y10S623/00; Y10S623/92; Y10S623/923
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
105 words
A method of manufacturing a cobalt-chromium orthopedic implant device having enhanced wear resistance properties, comprising the steps of: providing a cobalt-chromium substrate in the form of an orthopedic implant device; and hardening the surface of the cobalt-chromium substrate by exposing the cobalt-chromium substrate to an atmosphere of non-diluted molecular nitrogen gas at a process temperature within the range of 500° F. to 2400° F. for a process time duration sufficient to achieve a hardened outer surface layer and a hardened diffusion layer characterized primarily by solid solution hardening of the surface of the cobalt-chromium substrate by dissolution of nitrogen and oxygen in the cobalt-chromium substrate.
Claim 2
Independent Claim
105 words
A method of manufacturing a cobalt-chromium orthopedic implant device having enhanced wear resistance properties, comprising the steps of: providing a cobalt-chromium substrate in the form of an orthopedic implant device; and hardening the surface of the cobalt-chromium substrate by exposing the cobalt-chromium substrate to an atmosphere of non-diluted molecular nitrogen gas at a process temperature within the range of 500° F. to 2400° F. for a process time duration sufficient to achieve a hardened outer surface layer and a hardened diffusion layer characterized primarily by solid solution hardening of the surface of the cobalt-chromium substrate by dissolution of nitrogen and oxygen in the cobalt-chromium substrate.
Claim 3
Dependent Claim
16 words
The method of claim 1 in which the orthopedic implant device is a load bearing member.
Claim 4
Dependent Claim
24 words
The method of claim 1 in which the orthopedic implant device makes articulating contact with one of a polymer, a ceramic or a metal.
Claim 5
Dependent Claim
43 words
The method of claim 1 in which said hardened surface region exhibits a peak nitrogen concentration within the range of about 5 atomic percent to about 50 atomic percent at a depth between 100 and 5000Å below the surface of the outer substrate.
Claim 6
Dependent Claim
65 words
The method of claim 1 in which said hardened surface region includes a hardened surface layer limited in thickness to a depth of approximately 100 micrometers and a hardened diffusion region underneath said hardened surface layer, said surface layer comprising chromium nitride, chromium oxide, and chromium carbide, and said hardened diffusion region comprising a solid solution of nitrogen, oxygen, and carbon in said cobalt-chromium substrate.
Claim 7
Dependent Claim
15 words
The method of claim 3 in which the polymer is ultrahigh molecular weight polyethylene (UHMWPE).
Claim 8
Independent Claim
113 words
A method of manufacturing a cobalt-chromium orthopedic implant device having enhanced surface hardness and wear resistance properties, comprising the steps of: providing a cobalt-chromium substrate in the form of an orthopedic implant device; and exposing the cobalt-chromium substrate to an atmosphere of molecular nitrogen gas at a process temperature and for a process time duration sufficient to cause nitrogen dissolution in the cobalt-chromium substrate without a substantial quantity of formation of a substantial quantity of chromium nitride on the surface of said the cobalt-chromium substrate, thereby enhancing the surface hardness and wear resistance properties of the cobalt-chromium substrate by substantially avoiding increased surface roughness and brittleness that would diminish the wear resistance properties.
Claim 9
Independent Claim
113 words
A method of manufacturing a cobalt-chromium orthopedic implant device having enhanced surface hardness and wear resistance properties, comprising the steps of: providing a cobalt-chromium substrate in the form of an orthopedic implant device; and exposing the cobalt-chromium substrate to an atmosphere of molecular nitrogen gas at a process temperature and for a process time duration sufficient to cause nitrogen dissolution in the cobalt-chromium substrate without a substantial quantity of formation of a substantial quantity of chromium nitride on the surface of said the cobalt-chromium substrate, thereby enhancing the surface hardness and wear resistance properties of the cobalt-chromium substrate by substantially avoiding increased surface roughness and brittleness that would diminish the wear resistance properties.
Claim 10
Dependent Claim
14 words
The method of claim 7 in which said cobalt-chromium substrate comprises a cobalt-chromium-molybdenum alloy.
Claim 11
Dependent Claim
19 words
The method of claim 7 in which said cobalt-chromium alloy is one of ASTM F-75 and Modified ASTM F-75.
Claim 12
Dependent Claim
20 words
The method of claim 7 in which the process temperature is in the range of 500° F. to 2400° F.
Claim 13
Dependent Claim
14 words
The method of claim 7 in which the process time is approximately forty-eight hours.
Claim 14
Dependent Claim
22 words
The method of claim 7 in which the process temperature is approximately 1400° F. and the process time is approximately forty-eight hours.
Claim 15
Dependent Claim
28 words
The method of claim 7 in which said atmosphere of molecular nitrogen gas is provided at a process pressure within the range of 1 psig to 2 psig.
Claim 16
Dependent Claim
13 words
The method of claim 9 in which the cobalt-chromium alloy is ASTM F-799.
Claim 17
Dependent Claim
14 words
The method of claim 10 in which the process temperature is approximately 1400° F.
Claim 18
Independent Claim
112 words
A method of increasing the surface hardness and wear resistance properties of an orthopedic implant device that is fabricated from a cobalt-chromium material, comprising the steps of: providing a substrate of cobalt-chromium material in the form of an orthopedic implant device; and exposing the substrate to an atmosphere of non-diluted molecular nitrogen gas at a process temperature and for a process time duration sufficient to enhance both surface hardness and wear resistance properties of said substrate by nitrogen dissolution in the substrate by substantially avoiding increased surface roughness and brittleness and thereby diminishing wear resistance properties by the formation of a substantial quantity of chromium nitride on the surface of the substrate.
Claim 19
Independent Claim
112 words
A method of increasing the surface hardness and wear resistance properties of an orthopedic implant device that is fabricated from a cobalt-chromium material, comprising the steps of: providing a substrate of cobalt-chromium material in the form of an orthopedic implant device; and exposing the substrate to an atmosphere of non-diluted molecular nitrogen gas at a process temperature and for a process time duration sufficient to enhance both surface hardness and wear resistance properties of said substrate by nitrogen dissolution in the substrate by substantially avoiding increased surface roughness and brittleness and thereby diminishing wear resistance properties by the formation of a substantial quantity of chromium nitride on the surface of the substrate.
Claim 20
Dependent Claim
33 words
The method of claim 16 including the step of polishing the surface hardened implant device sufficiently to provide an ultrahigh finish to the device, thereby substantially improving the wear resistance of the implant.
Claim 21
Dependent Claim
20 words
The method of claim 16 in which the process temperature is in the range of 500° F. to 2400° F.
Claim 22
Independent Claim
103 words
A method of manufacturing a cobalt-chromium orthopedic implant device having enhanced wear resistance properties, comprising the steps of: providing a cobalt-chromium substrate in the form of an orthopedic implant device; and hardening the surface of the cobalt-chromium substrate by exposing the cobalt-chromium substrate to an atmosphere of ionized nitrogen at a process temperature within the range of 500° F. to 2400° F. for a process time duration sufficient to achieve a hardened outer surface layer and a hardened diffusion layer characterized primarily by solid solution hardening of the surface of the cobalt-chromium substrate by dissolution of nitrogen and oxygen in the cobalt-chromium substrate.
Claim 23
Independent Claim
103 words
A method of manufacturing a cobalt-chromium orthopedic implant device having enhanced wear resistance properties, comprising the steps of: providing a cobalt-chromium substrate in the form of an orthopedic implant device; and hardening the surface of the cobalt-chromium substrate by exposing the cobalt-chromium substrate to an atmosphere of ionized nitrogen at a process temperature within the range of 500° F. to 2400° F. for a process time duration sufficient to achieve a hardened outer surface layer and a hardened diffusion layer characterized primarily by solid solution hardening of the surface of the cobalt-chromium substrate by dissolution of nitrogen and oxygen in the cobalt-chromium substrate.
Claim 24
Independent Claim
108 words
A method of manufacturing a cobalt-chromium orthopedic implant device having enhanced surface hardness and wear resistance properties, comprising the steps of: providing a cobalt-chromium substrate in the form of an orthopedic implant device; and exposing the cobalt-chromium substrate to an atmosphere of ionized nitrogen at a process temperature and for a process time duration sufficient to cause nitrogen dissolution in the cobalt-chromium substrate without formation of a substantial quantity of chromium nitride on the surface of said the cobalt-chromium substrate, thereby enhancing the surface hardness and wear resistance properties of the cobalt-chromium substrate by substantially avoiding increased surface roughness and brittleness that would diminish the wear resistance properties.
Claim 25
Independent Claim
108 words
A method of manufacturing a cobalt-chromium orthopedic implant device having enhanced surface hardness and wear resistance properties, comprising the steps of: providing a cobalt-chromium substrate in the form of an orthopedic implant device; and exposing the cobalt-chromium substrate to an atmosphere of ionized nitrogen at a process temperature and for a process time duration sufficient to cause nitrogen dissolution in the cobalt-chromium substrate without formation of a substantial quantity of chromium nitride on the surface of said the cobalt-chromium substrate, thereby enhancing the surface hardness and wear resistance properties of the cobalt-chromium substrate by substantially avoiding increased surface roughness and brittleness that would diminish the wear resistance properties.
Claim 26
Independent Claim
110 words
A method of increasing the surface hardness and wear resistance properties of an orthopedic implant device that is fabricated from a cobalt-chromium material, comprising the steps of: providing a substrate of cobalt-chromium material in the form of an orthopedic implant device; and exposing the substrate to an atmosphere of ionized nitrogen at a process temperature and for a process time duration sufficient to enhance both surface hardness and wear resistance properties of said substrate by nitrogen dissolution in the substrate by substantially avoiding increased surface roughness and brittleness and thereby diminishing wear resistance properties by the formation of a substantial quantity of chromium nitride on the surface of the substrate.
Claim 27
Independent Claim
110 words
A method of increasing the surface hardness and wear resistance properties of an orthopedic implant device that is fabricated from a cobalt-chromium material, comprising the steps of: providing a substrate of cobalt-chromium material in the form of an orthopedic implant device; and exposing the substrate to an atmosphere of ionized nitrogen at a process temperature and for a process time duration sufficient to enhance both surface hardness and wear resistance properties of said substrate by nitrogen dissolution in the substrate by substantially avoiding increased surface roughness and brittleness and thereby diminishing wear resistance properties by the formation of a substantial quantity of chromium nitride on the surface of the substrate.
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