US4714468A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Prosthesis formed from dispersion strengthened cobalt-chromium-molybdenum alloy produced by gas atomization
Assignee: Howmedica Osteonics Corp
•
Filing: 1987-01-27
•
Granted: 1987-12-22
•
Expires: 2007-01-27
Abstract
Abstract A dispersion strengthened cobalt-chromium-molybdenum alloy produced by gas atomization containing a fine oxide dispersion, and characterized, after fabrication by gas atomization, thermomechanical processing and further high temperature exposure, by excellent corrosion resistance, high fatigue strength, high ductility and high temperature stability; a process for producing said alloy and prostheses formed from said alloy.
Inventors
- 👤 Kathy K. Wang
- 👤 Larry J. Gustavson
- 👤 John H. Dumbleton
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 06:58
CPC Classifications
C; C22; C22C; C22C19/00; C22C19/07; A; A61; A61L; A61L27/00; A61L27/02; A61L27/04; A61L27/045; A61F; A61F2310/00; A61F2310/00005; A61F2310/00011; A61F2310/00029
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
200 words
A prosthesis made by forging a high-strength, corrosion-resistant, high temperature stable, ductile alloy having homogeneously distributed dispersed oxides and fine, equiaxed grain structure after high temperature exposure, said alloy being produced by gas atomisation and consisting essentially of the following percentage composition by weight: ______________________________________
chromium 26 to 30
molybdenum 5 to 7
manganese 0 to 1
silicon 0 to 1
iron 0 to 0.75
nickel 0 to 1.0
carbon 0 to 0.35
nitrogen 0 to 0.25
oxygen 0.003 to 0.20
oxide-forming metal 0.003 to 2.0
______________________________________ and the balance cobalt, apart from trace amounts of incidental impurities; in which the oxide-forming metal is a metal selected from the group consisting of magnesium, calcium, aluminum, yttrium, lanthanum, titanium and zirconium, which forms high temprature-stable, non-accretive, fine oxide particles which oxide has a free energy of formation greater than the oxide of the matrix metal and is homogeneously distributed in the dispersed phase; and said alloy after fabrication by gas atomization, thermomechanical processing and further high temperature exposure has an ultimate tensile strength of 160-200 k.s.i., a 0.2% offset yield strength of 75-100 k.s.i., an elongation of 37 to 60%, and a fatigue strength at 10 7 cycles of 70-95 k.s.i.
Claim 2
Dependent Claim
200 words
A prosthesis made by forging a high-strength, corrosion-resistant, high temperature stable, ductile alloy having homogeneously distributed dispersed oxides and fine, equiaxed grain structure after high temperature exposure, said alloy being produced by gas atomisation and consisting essentially of the following percentage composition by weight: ______________________________________
chromium 26 to 30
molybdenum 5 to 7
manganese 0 to 1
silicon 0 to 1
iron 0 to 0.75
nickel 0 to 1.0
carbon 0 to 0.35
nitrogen 0 to 0.25
oxygen 0.003 to 0.20
oxide-forming metal 0.003 to 2.0
______________________________________ and the balance cobalt, apart from trace amounts of incidental impurities; in which the oxide-forming metal is a metal selected from the group consisting of magnesium, calcium, aluminum, yttrium, lanthanum, titanium and zirconium, which forms high temprature-stable, non-accretive, fine oxide particles which oxide has a free energy of formation greater than the oxide of the matrix metal and is homogeneously distributed in the dispersed phase; and said alloy after fabrication by gas atomization, thermomechanical processing and further high temperature exposure has an ultimate tensile strength of 160-200 k.s.i., a 0.2% offset yield strength of 75-100 k.s.i., an elongation of 37 to 60%, and a fatigue strength at 10 7 cycles of 70-95 k.s.i.
Claim 3
Dependent Claim
23 words
A prosthesis accordindg to claim 1, in which the oxide forming metal of the forged alloy is aluminum, lanthanum or a mixture thereof.
Claim 4
Dependent Claim
53 words
A prosthesis according to claim 2, in which the percentage composition by weight of the forged alloy is: ______________________________________
chromium 26.47-27.27
molybdenum 5.50-6.01
manganese 0.73-0.78
silicon 0.70-0.71
iron 0.066-0.359
nickel 0.002-0.187
carbon 0.09-0.11
nitrogen 0.10-[0.26]0.25
oxygen 0.0035-0.016
aluminum 0.40-0.81
lanthanum 0-0.15
______________________________________ and the balance cobalt, apart from trace amount of incidental impurities.
Claim 5
Dependent Claim
73 words
A prosthesis according to claim 2, in which the percentage composition by weight of the forged alloy is: ______________________________________
chromium 27.24
molybdenum 5.97
manganese 0.74
silicon 0.71
iron 0.215
nickel 0.053
carbon 0.09
nitrogen 0.21
oxygen 0.0038
aluminum 0.45
lanthanum 0.022
______________________________________ and the balance cobalt, apart from trace amount of incidental impurities, and said alloy after fabrication by gas atomisation, thermomechanical processing and further high temperature exposure has an elongation of 58.7%.
Claim 6
Dependent Claim
73 words
A prosthesis according to claim 2, in which the percentage composition by weight of the forged alloy is: ______________________________________
chromium 26.81
molybdenum 5.97
manganese 0.74
silicon 0.70
iron 0.52
nickel 0.094
carbon 0.09
nitrogen 0.22
oxygen 0.0142
aluminum 0.47
lanthanum 0.15
______________________________________
and the balance cobalt, apart from trace amounts of incidental
impurities, and said alloy after fabrication by gas atomisation,
thermomechanical processing and further high temperature exposure has an
elongation of 51.0%.
Claim 7
Dependent Claim
10 words
A prosthesis according to claim 1 having a porous coating.
References Cited (Backward Citations)
GB423562A
Cited
GB974185A
Cited
US3356542A
Cited
US3591362A
Cited
US3649256A
Cited
SU368341A1
Cited
US3865585A
Cited
DE2350546A1
Cited
US4012229A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-12-21 | 1991-06-22 | 1991-12-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-12-21 | 1995-06-22 | 1995-12-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-12-21 | 1999-06-22 | 1999-12-22 | $7700.00 | Window Closed / Lapsed |