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Reduction of α-olefin-carbon monoxide copolymers to polyalcohols with borohydride salt

Assignee: ExxonMobil Chemical Patents Inc
•
Filing: 1991-07-08
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Granted: 1994-04-05
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Expires: 2011-07-08
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Abstract

Abstract This invention relates to a process of reducing polyketones to polyalcohols using borohydride salts where the reducing agent is suspended in water.

Inventors

  • 👤 Gregory G. Hlatky

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 16:11
CPC Classifications
C; C08; C08G; C08G67/00; C08G67/02

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 36 words
A process for the reduction of alpha-olefin/carbon monoxide copolymers to polyalcohols consisting essentially of: 1) suspending an alpha-olefin/carbon monoxide copolymer in water, 2) adding a borohydride salt to the suspension, and 3) recovering the polyalcohol product.
Claim 2
Dependent Claim 36 words
A process for the reduction of alpha-olefin/carbon monoxide copolymers to polyalcohols consisting essentially of: 1) suspending an alpha-olefin/carbon monoxide copolymer in water, 2) adding a borohydride salt to the suspension, and 3) recovering the polyalcohol product.
Claim 3
Dependent Claim 22 words
The process of claim 1, wherein the carbon monoxide copolymer has from about 1 mole % to 50 mole % carbonyl units.
Claim 4
Dependent Claim 18 words
The process of claim 1, wherein the carbon monoxide copolymer is a copolymer of ethylene and carbon monoxide.
Claim 5
Dependent Claim 24 words
The process of claim 1, wherein carbon monoxide in said carbon monoxide copolymer is present at about 30 mole % to 50 mole %.
Claim 6
Dependent Claim 20 words
The process of claim 1 wherein the carbon monoxide copolymer is ground to a mesh of between 2 and 60.
Claim 7
Dependent Claim 15 words
The process of claim 1, wherein the borohydride salt is sodium borohydride or potassium borohydride.
Claim 8
Dependent Claim 19 words
The process of claim 1, wherein the carbon monoxide copolymer is ground to a mesh of 20 or finer.
Claim 9
Dependent Claim 26 words
The process of claim 1, wherein the gram(s) of borohydride salt are present in a ratio of 2.0:1 or greater to gram(s) of carbon monoxide copolymer.
Claim 10
Dependent Claim 26 words
The process of claim 1, wherein the gram(s) of borohydride salt are present in a ratio between 1.5:1 and 2.5:1 to gram(s) of carbon monoxide copolymer.

References Cited (Backward Citations)

US2495286A Cited
US3694412A Cited
US4076911A Cited
US4835250A Cited
US4818810A Cited
US4868254A Cited
US4929701A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-04-04 1997-10-04 1998-04-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-04-04 2001-10-04 2002-04-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-04-04 2005-10-04 2006-04-05 $7700.00 Window Closed / Lapsed

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