Catalytic process for the preparation of polyketones from carbon monoxide and ethylenically unsaturated hydrocarbon

Claim 1

In a process for the preparation of a polyketone by contacting CO and an alkenically unsaturated hydrocarbon in the presence of a Group VIII metal catalyst, the improvement which comprises contacting the CO and the alkenically unsaturated hydrocarbon in the presence of a catalyst comprising a Group VIII metal complex containing bidentate ligands, the Group VIII metal selected from the group consisting of palladium, cobalt, and nickel, the ligands comprising hydrocarbon groups bonded to a Group Va element selected from the group consisting of phosphorus, arsenic, and antimony, wherein the catalyst is a complex compound that is obtained by reacting (1) a palladium, cobalt or nickel compound, (2) a bidentate ligand of the general formula ##STR9## in which M is a group Va element selected from the group consisting of phosphorus, arsenic, and antimony, R 1 , R 2 , R 3 , and R 4 are identical or different hydrocarbon groups, R represents a divalent organic bridging group having at least two carbon atoms in the bridge, wherein the carbon atoms of the bridging group R do not contain substituents that would sterically hinder formation of the complex compound, and (3) an anion of a carboxylic acid having a pKa of less than 2.