US5300413A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Photoelectric elements for producing spectral image records retrievable by scanning
Assignee: Eastman Kodak Co
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Filing: 1992-11-27
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Granted: 1994-04-05
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Expires: 2012-11-27
Abstract
Abstract A method is disclosed of extracting two or more spectral image records from an imagewise exposed multicolor photographic element containing a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum. In each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area. No more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.07 micrometers, and each of the remaining tabular grain emulsions exhibit a coefficient of variation of tabular grain thickness of less than 15 percent. The mean tabular grain thickness of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer. The imagewise exposed element is photographically processed to develop silver halide grains as a function of exposure and to remove developed silver. The processed photographic element is scanned in a first spectral wavelength region at which the tabular grains in a first of the emulsions reflect to a greater degree than the tabular grains of any emulsion which has recorded imagewise exposure in a different region of the spectrum, and the processed photographic element is also scanned in a second spectral wavelength region within which the tabular grains in a second of the emulsions reflect.
Inventors
- 👤 James E. Sutton
- 👤 John Gasper
- 👤 Allen K.-C. Tsaur
- 👤 Ann Tarn
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-10 02:13
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/3022; G03C1/00; G03C1/005; G03C1/0051; G03C1/46; Y; Y10; Y10S; Y10S430/00; Y10S430/146
Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
162 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of emulsions for individually recording imagewise exposure in one of at least two different regions of the visible spectrum, each of the emulsions for recording imagewise exposure being tabular grain emulsions having an average aspect ratio of at least 2, wherein in each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, no more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.07 micrometer, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the mean tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 2
Dependent Claim
162 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of emulsions for individually recording imagewise exposure in one of at least two different regions of the visible spectrum, each of the emulsions for recording imagewise exposure being tabular grain emulsions having an average aspect ratio of at least 2, wherein in each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, no more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.07 micrometer, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the mean tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 3
Dependent Claim
166 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of emulsions for individually recording imagewise exposure in one of at least two different regions of the visible spectrum, each of the emulsions for recording imagewise exposure being tabular grain emulsions, wherein the tabularity of each of the tabular grain emulsions is greater than 25, in each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, no more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.7 micrometers, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the mean tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 4
Dependent Claim
166 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of emulsions for individually recording imagewise exposure in one of at least two different regions of the visible spectrum, each of the emulsions for recording imagewise exposure being tabular grain emulsions, wherein the tabularity of each of the tabular grain emulsions is greater than 25, in each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, no more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.7 micrometers, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the mean tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 5
Dependent Claim
170 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum, wherein the coefficient of variation of the equivalent circular diameters of the tabular grains intended to record exposure to the same region of the spectrum is greater than 15 percent, in each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, no more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.07 micrometers, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the mean tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 6
Dependent Claim
170 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum, wherein the coefficient of variation of the equivalent circular diameters of the tabular grains intended to record exposure to the same region of the spectrum is greater than 15 percent, in each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, no more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.07 micrometers, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the mean tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 7
Dependent Claim
51 words
A multicolor photographic element according to claim 1 wherein in each of the tabular grain emulsions having a mean tabular grain thickness greater than 0.07 μm tabular grains accounting for 90 percent of total grain projected area exhibit a coefficient of variation of tabular grain thickness of less than 10 percent.
Claim 8
Dependent Claim
30 words
A multicolor photographic element according to claim 1 wherein in each of the tabular grain emulsions the tabular grains account for greater than 97 percent of total grain projected area.
Claim 9
Dependent Claim
53 words
A multicolor photographic element according to claim 5 wherein in each of the tabular grain emulsions having a mean tabular grain thickness of greater than 0.07 μm the tabular grains accounting for 97 percent of total grain projected area exhibit a coefficient of variation of tabular grain thickness of less than 10 percent.
Claim 10
Dependent Claim
28 words
A multicolor photographic element according to claim 1 wherein the tabular grains in at least one emulsion exhibit a means equivalent circular diameter of at least 1.0 micrometer.
Claim 11
Dependent Claim
141 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum, wherein in each of the tabular grain emulsions tabular grins exhibiting a means equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, no more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.07 micrometers, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the means tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.04 micrometer.
Claim 12
Dependent Claim
141 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum, wherein in each of the tabular grain emulsions tabular grins exhibiting a means equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, no more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.07 micrometers, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the means tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.04 micrometer.
Claim 13
Dependent Claim
161 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum, wherein in each of the tabular grain emulsions tabular grains exhibiting a means equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, the mean tabular grain thickness of one of the tabular rain emulsions is 0.06 micrometer or less, the mean abular grain thickness of each of the remaining tabular grain emulsions is in the range of from 0.08 to 0.18 micrometer, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the mean tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 14
Dependent Claim
161 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum, wherein in each of the tabular grain emulsions tabular grains exhibiting a means equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, the mean tabular grain thickness of one of the tabular rain emulsions is 0.06 micrometer or less, the mean abular grain thickness of each of the remaining tabular grain emulsions is in the range of from 0.08 to 0.18 micrometer, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the mean tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 15
Dependent Claim
144 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum, wherein in each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, the mean tabular grain emulsions thickness of each one of the tabular grain emulsions is in the range of from 0.08 to 0.18 micrometer, each of the tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the mean tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 16
Dependent Claim
144 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum, wherein in each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, the mean tabular grain emulsions thickness of each one of the tabular grain emulsions is in the range of from 0.08 to 0.18 micrometer, each of the tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the mean tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 17
Dependent Claim
40 words
A multicolor photographic element according to claim 1 wherein the support includes means for absorbing light following photographic processing within a wavelength region to which the tabular grains of at least one of the emulsions exhibit maximum reflectance when scanned.
Claim 18
Dependent Claim
169 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum, wherein the support includes means for absorbing light following photographic processing within wavelength regions to which the tabular grains in each of the wavelength regions exhibit maximum reflectance when scanned, in each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and means thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, no more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.07 micrometer, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the mean tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 19
Dependent Claim
169 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum, wherein the support includes means for absorbing light following photographic processing within wavelength regions to which the tabular grains in each of the wavelength regions exhibit maximum reflectance when scanned, in each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and means thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, no more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.07 micrometer, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the mean tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 20
Dependent Claim
169 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum, wherein at least two of the tabular grain emulsions for individually recording imagewise exposure in different regions of the spectrum are located in a single layer on the support, in each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, no more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.07 micrometer, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the means tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 21
Dependent Claim
169 words
A multicolor photographic element comprised of a support and, coated on the support, a plurality of tabular grain emulsions for individually recording imagewise exposure in at least two different regions of the visible spectrum, wherein at least two of the tabular grain emulsions for individually recording imagewise exposure in different regions of the spectrum are located in a single layer on the support, in each of the tabular grain emulsions tabular grains exhibiting a mean equivalent circular diameter of greater than 0.4 micrometer and a mean thickness of less than 0.2 micrometer account for greater than 90 percent of total grain projected area, no more than one of the tabular grain emulsions exhibits a mean tabular grain thickness of less than 0.07 micrometer, each of the remaining tabular grain emulsions exhibits a coefficient of variation of tabular grain thickness of less than 15 percent, and the means tabular grain thicknesses of emulsions for recording imagewise exposure to different regions of the visible spectrum differs by at least 0.02 micrometer.
Claim 22
Dependent Claim
24 words
A multicolor photographic element according to claim 13 wherein all of the tabular grain emulsions are located in the same layer on the support.
Claim 23
Dependent Claim
37 words
A multicolor photographic element according to claim 1 wherein each of the tabular grain emulsions intended to record imagewise exposure within a different region o the spectrum is located in a different layer unit on the support.
Claim 24
Dependent Claim
189 words
A multicolor photographic element comprised of a support and, coated on the support, a red recording tabular grain emulsion layer unit, a green recording tabular grain emulsion layer unit, and a blue recording tabular grain emulsion layer unit, wherein in each of the tabular grain emulsion layer units the tabular grains are comprised of silver bromide or bromoiodide, exhibit a mean equivalent circular diameter of at least 1.0 micrometer, exhibit a tabularity of greater than 25, account for greater than 97 percent of total grain projected area, exhibit a coefficient of variation of tabular grain equivalent circular diameter of greater than 15 percent, the tabular grains in the emulsion layer units coated nearest the support exhibit a mean thickness of less than 0.06 micrometer, the tabular grains in each of the two remaining emulsion layer units exhibit a mean thickness in the range of from 0.08 to 0.18 micrometer and exhibit a coefficient of variation of tabular grain thickness of less than 10 percent, and the mean tabular grain thickness in each emulsion layer unit differ from those in the remaining emulsion layer units by at least 0.04 micrometer.
Claim 25
Dependent Claim
189 words
A multicolor photographic element comprised of a support and, coated on the support, a red recording tabular grain emulsion layer unit, a green recording tabular grain emulsion layer unit, and a blue recording tabular grain emulsion layer unit, wherein in each of the tabular grain emulsion layer units the tabular grains are comprised of silver bromide or bromoiodide, exhibit a mean equivalent circular diameter of at least 1.0 micrometer, exhibit a tabularity of greater than 25, account for greater than 97 percent of total grain projected area, exhibit a coefficient of variation of tabular grain equivalent circular diameter of greater than 15 percent, the tabular grains in the emulsion layer units coated nearest the support exhibit a mean thickness of less than 0.06 micrometer, the tabular grains in each of the two remaining emulsion layer units exhibit a mean thickness in the range of from 0.08 to 0.18 micrometer and exhibit a coefficient of variation of tabular grain thickness of less than 10 percent, and the mean tabular grain thickness in each emulsion layer unit differ from those in the remaining emulsion layer units by at least 0.04 micrometer.
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