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US5300376A Expired / Lapsed US ⏱️ 0.0 years remaining

Highly conductive electrolyte for use in an ambient temperature rechargeable lithium battery and ambient temperature rechargeable lithium battery including said electrolyte

Assignee: United States Department of the Army
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Filing: 1992-09-15
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Granted: 1994-04-05
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Expires: 2012-09-15
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Abstract

Abstract A highly conductive electrolyte is provided for use in an ambient temperae rechargeable lithium battery including a lithium intercalating anode and a more positive lithium intercalating cathode. The electrolyte includes a solution of a lithium salt in acetonitrile.

Inventors

  • 👤 Edward J. Plichta
  • 👤 Wishvender K. Behl

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 00:29
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/05; H01M10/056; H01M10/0564; H01M10/0566; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 109 words
A highly conductive electrolyte for use in an ambient temperature rechargeable lithium battery including a lithium intercalcating anode selected from the group consisting of TiS 2 , WO 2 , MoO 2 , VSe 2 , Li 2 TiS 2 , Li 2 VSe 2 , lithiated graphite, lithiated carbon, and lithiated petroleum coke, and a lithium intercalating cathode selected from the group consisting of LiCoO 2 and LiNiO 2 , said electrolyte having a solution of a lithium salt in acetonitrile, wherein the lithium salt is selected from the group consisting of LiAsF 2 , LiAlCl 4 , LiClO 4 , LiBF 4 , and LiPF 6 .
Claim 2
Dependent Claim 109 words
A highly conductive electrolyte for use in an ambient temperature rechargeable lithium battery including a lithium intercalcating anode selected from the group consisting of TiS 2 , WO 2 , MoO 2 , VSe 2 , Li 2 TiS 2 , Li 2 VSe 2 , lithiated graphite, lithiated carbon, and lithiated petroleum coke, and a lithium intercalating cathode selected from the group consisting of LiCoO 2 and LiNiO 2 , said electrolyte having a solution of a lithium salt in acetonitrile, wherein the lithium salt is selected from the group consisting of LiAsF 2 , LiAlCl 4 , LiClO 4 , LiBF 4 , and LiPF 6 .
Claim 3
Dependent Claim 16 words
A highly conductive electrolyte according to claim 1 wherein the lithium salt is LiAsF 6 .
Claim 4
Dependent Claim 16 words
A highly conductive electrolyte according to claim 1 wherein the lithium salt is LiAlCl 4 .
Claim 5
Dependent Claim 16 words
A highly conductive electrolyte according to claim 1 wherein the electrolyte salt is LiBF 4 .
Claim 6
Dependent Claim 16 words
A highly conductive electrolyte according to claim 1 wherein the electrolyte salt is LiBF 4 .
Claim 7
Dependent Claim 16 words
A highly conductive electrolyte according to claim 1 wherein the electrolyte salt is LiPF 6 .
Claim 8
Dependent Claim 22 words
A highly conductive electrolyte according to claim 2 wherein the electrolyte is a solution of about 1.5 molar LiAsF 6 in acetonitrile.
Claim 9
Dependent Claim 106 words
An ambient temperature chargeable lithium battery system comprising a lithium intercalating anode selected from the group consisting of TiS 2 , WO 2 , MoO 2 , VSe 2 , Li 2 TiS 2 , Li 2 VSe 2 , lithiated graphite, lithiated carbon, and lithiated petroleum coke, a lithium intercalating cathode selected from the group consisting of LiCoO 2 and LiNiO 2 and a solution of a lithium salt in acetonitrile as the electrolyte wherein the lithium salt in the electrolyte solution is selected from the group consisting of LiAlCl 4 , LiClO 4 , LiBF 4 , LiAsF 6 , and LiPF 6 .
Claim 10
Dependent Claim 106 words
An ambient temperature chargeable lithium battery system comprising a lithium intercalating anode selected from the group consisting of TiS 2 , WO 2 , MoO 2 , VSe 2 , Li 2 TiS 2 , Li 2 VSe 2 , lithiated graphite, lithiated carbon, and lithiated petroleum coke, a lithium intercalating cathode selected from the group consisting of LiCoO 2 and LiNiO 2 and a solution of a lithium salt in acetonitrile as the electrolyte wherein the lithium salt in the electrolyte solution is selected from the group consisting of LiAlCl 4 , LiClO 4 , LiBF 4 , LiAsF 6 , and LiPF 6 .
Claim 11
Dependent Claim 22 words
An ambient temperature rechargeable lithium battery system according to claim 8 wherein the lithium intercalating and is Li 2 TiS 2 .
Claim 12
Dependent Claim 20 words
An ambient temperature rechargeable lithium battery system according to claim 11 wherein the lithium intercalating cathode is LiCoO 2 .
Claim 13
Dependent Claim 20 words
An ambient temperature rechargeable lithium battery system according to claim 8 wherein the lithium intercalating cathode is LiNiO 2 .
Claim 14
Dependent Claim 23 words
An ambient temperature rechargeable lithium battery system according to claim 8 wherein the lithium salt in the electrolyte solution is LiAsF 6 .
Claim 15
Dependent Claim 32 words
An ambient temperature rechargeable lithium battery system including TiS 2 as the anode, LiCoO 2 as the cathode, and a solution of about 1.5 molar LiAsF 6 in acetonitrile as the electrolyte.
Claim 16
Dependent Claim 32 words
An ambient temperature rechargeable lithium battery system including TiS 2 as the anode, LiCoO 2 as the cathode, and a solution of about 1.5 molar LiAsF 6 in acetonitrile as the electrolyte.

References Cited (Backward Citations)

DE213557C Cited
JPS54125443A Cited
US4882244A Cited
US5084366A Cited
US5017444A Cited
US5102751A Cited
JPH03296556A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-04-04 1997-10-04 1998-04-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-04-04 2001-10-04 2002-04-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-04-04 2005-10-04 2006-04-05 $7700.00 Window Closed / Lapsed

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