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US5298783A Expired / Lapsed US ⏱️ 0.0 years remaining

Combined semiconductor gas sensor

Assignee: Yunnan University YNU
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Filing: 1992-06-24
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Granted: 1994-03-29
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Expires: 2012-06-24
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Abstract

Abstract The present invention relates to a combined semiconductor gas sensor, this sensor is constituted by combining two portions, each of the portions is made of a different gas sensitive material, their resistance exhibit different variation with the variation of the density of a specific gas, a detecting signal is led out from the junction of the two portion. Because of the mutual compensation and propagation effect of the two portions of the above mentioned gas sensor, the stability and/or sensitivity as well as the stability to temperature and humidity and the initial relaxation time can be improved. Gas sensors of different characteristics can be obtained by different combinations of two different gas sensitive materials selected according to need.

Inventors

  • 👤 Xinghui Wu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 12:35
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/02; G01N27/04; G01N27/12; G01N33/00; G01N33/0004; G01N33/0009; G01N33/0027; G01N33/0031

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 124 words
A combined semiconductor gas sensor for measuring the density of a specific gas, comprising the combination of two portions, which portions are formed on a single substrate and are made of two different gas sensitive materials respectively, wherein the resistances of these two portions vary differently with the density of the specific gas; when said gas sensor is coupled into a detecting circuit, an output signal is led out from the junction of said two portions, wherein one of the portions serves as the load simultaneously, an absolute value of the temperature coefficient of the gas sensitive material constituting the portion serving as the load simultaneously is not greater than an absolute value of the temperature coefficient of the material constituting the other portion.
Claim 2
Dependent Claim 124 words
A combined semiconductor gas sensor for measuring the density of a specific gas, comprising the combination of two portions, which portions are formed on a single substrate and are made of two different gas sensitive materials respectively, wherein the resistances of these two portions vary differently with the density of the specific gas; when said gas sensor is coupled into a detecting circuit, an output signal is led out from the junction of said two portions, wherein one of the portions serves as the load simultaneously, an absolute value of the temperature coefficient of the gas sensitive material constituting the portion serving as the load simultaneously is not greater than an absolute value of the temperature coefficient of the material constituting the other portion.
Claim 3
Dependent Claim 24 words
The gas sensor according to claim 1, wherein the temperature coefficients of said two portions are equal to or approximately equal to each other.
Claim 4
Dependent Claim 58 words
The gas sensor according to claim 1, wherein both gas sensitive materials are N-type, the combined gas sensor being of N-N-type, wherein one gas sensitive material is sensitive to the gas to be detected but insensitive to interference gas(es), while the other gas sensitive material is sensitive to interference gas(es) but insensitive to the gas to be detected.
Claim 5
Dependent Claim 30 words
The gas sensor according to claim 1, wherein one material is N-type, and the other is P-type respectively, and both of them are sensitive to the gas to be detected.
Claim 6
Dependent Claim 17 words
The gas sensor according to claim 4, wherein both gas sensitive materials are insensitive to interference gases.
Claim 7
Dependent Claim 15 words
The gas sensor according to claim 1, wherein the gas sensor is of sintered type.
Claim 8
Dependent Claim 124 words
The gas sensor according to claim 3, wherein the portion serving as load is made from the following materials: ZnSnO 3 , 54.4%-56.7% by weight, SnO 2 , 27.5%-29.8% by weight, ThO 2 , 1% by weight, TiO 2 , 0.5% by weight, MgO, 4.7% by weight, Co 2 O 3 , 1% by weight, Sb, 3.6% by weight, Al 2 O 3 , 2% by weight, mordanting asbestos, 1.5% by weight, and porcelain powder, 1.5% by weight; and the other portion is made from: SnO 2 , 51.2% by weight, WO 3 , 24% by weight, SiO 2 , 10.3% by weight, ThO 2 , 10.3% by weight, Pt, 0.8% by weight, porcelain powder, 1.7% by weight, and mordanting asbestos, 1.7% by weight.
Claim 9
Dependent Claim 86 words
The gas sensor according to claim 3, wherein the portion serving as load is made from the following materials: WO 3 , 90.4%-91% by weight, Al 2 O 3 , 3%-3.1% by weight, and porcelain powder, 6%-6.5% by weight; and the other portion is made from: ZnSnO 3 , 51.4% by weight, SnO 2 , 41.1% by weight, Al 2 O 3 , 1.5% by weight, CaO, 2% by weight, Ag 2 O, 1.5% by weight, Sb, 1% by weight, and porcelain powder, 1.5% by weight.
Claim 10
Dependent Claim 58 words
The gas sensor according to claim 1, wherein both gas sensitive materials are P-type, the combined gas sensor being of P-P-type, wherein one gas sensitive material is sensitive to the gas to be detected but insensitive to interference gas(es), while the other gas sensitive material is sensitive to interference gas(es) but insensitive to the gas to be detected.
Claim 11
Dependent Claim 17 words
The gas sensor according to claim 4, wherein both gas sensitive materials are insensitive to interference gases.
Claim 12
Dependent Claim 16 words
The gas sensor according to claim 1, wherein the gas sensor is of thin film type.
Claim 13
Dependent Claim 16 words
The gas sensor according to claim 1, wherein the gas sensor is of thick film type.
Claim 14
Dependent Claim 205 words
A combined gas sensor for measuring the density of a specific gas, the gas sensor comprising: a first portion of a gas sensitive material, the first portion having a first end and a second end, such that when the first portion is exposed to the specific gas, the resistance between the first and second ends across the first portion varies with the density of the specific gas; a second portion of a gas sensitive material, the second portion having a first end and a second end, such that when the second portion is exposed to the specific gas, the resistance between the first and second ends of the second portion across the second portion varies with the density of the specific gas differently from said resistance across the first portion; a first electrode connected to the first end of the first portion; a second electrode connected to the second end of the second portion, the first and second electrodes being for passing a current therebetween through the first and second portions; and a third electrode connected to the second end of the first portion and the first end of the second portion, for providing an output signal indicative of the density of the specific gas.
Claim 15
Dependent Claim 205 words
A combined gas sensor for measuring the density of a specific gas, the gas sensor comprising: a first portion of a gas sensitive material, the first portion having a first end and a second end, such that when the first portion is exposed to the specific gas, the resistance between the first and second ends across the first portion varies with the density of the specific gas; a second portion of a gas sensitive material, the second portion having a first end and a second end, such that when the second portion is exposed to the specific gas, the resistance between the first and second ends of the second portion across the second portion varies with the density of the specific gas differently from said resistance across the first portion; a first electrode connected to the first end of the first portion; a second electrode connected to the second end of the second portion, the first and second electrodes being for passing a current therebetween through the first and second portions; and a third electrode connected to the second end of the first portion and the first end of the second portion, for providing an output signal indicative of the density of the specific gas.
Claim 16
Dependent Claim 19 words
The combined gas sensor of claim 13 wherein the first and second portions are formed on a single substrate.
Claim 17
Dependent Claim 14 words
The combined gas sensor of claim 14 wherein the substrate is a ceramic tube.
Claim 18
Dependent Claim 32 words
The combined gas sensor of claim 13 wherein the output signal is a voltage determined by the ratio of said resistance across the first portion to said resistance across the second portion.
Claim 19
Dependent Claim 39 words
The combined gas sensor of claim 13 wherein the first portion has a greater sensitivity to the specific gas than the second portion, and the first portion has a smaller sensitivity to an interference gas than the second portion.
Claim 20
Dependent Claim 39 words
The combined gas sensor of claim 13 whose sensitivity to the specific gas is greater than a sensitivity to the specific gas of the first portion and greater than a sensitivity to the specific gas of the second portion.
Claim 21
Dependent Claim 51 words
The combined gas sensor of claim 13 whose resolution to the specific gas and an interference gas is greater than a resolution to the specific gas and the interference gas of the first portion and greater than a resolution to the specific gas and the interference gas of the second portion.
Claim 22
Dependent Claim 35 words
The combined gas sensor of claim 13 wherein variations of said resistance across the first and second portions with humidity at least partially offset each other to reduce variation of the output signal with humidity.
Claim 23
Dependent Claim 63 words
The gas sensor of claim 13, further comprising means for connecting the first electrode to a first voltage and the second electrode to a second voltage lower in magnitude than the first voltage, wherein, for the specific gas, a time constant of the resistance response of the first portion is smaller than a time constant of the resistance response of the second portion.
Claim 24
Dependent Claim 63 words
The gas sensor of claim 13, further comprising means for connecting the first electrode to a first voltage and the second electrode to a second voltage lower in magnitude than the first voltage, wherein, for an interference gas, a time constant of the resistance response of the first portion is greater than a time constant of the resistance response of the second portion.
Claim 25
Dependent Claim 67 words
The combined gas sensor of claim 13 wherein: for the specific gas, a time constant of the resistance response of the first portion is smaller than a time constant of the resistance response of the second portion, and for an interference gas, a time constant of the resistance response of the first portion is greater than a time constant of the resistance response of the second portion.
Claim 26
Dependent Claim 30 words
The combined gas sensor of claim 13 wherein an initial relaxation time of the first portion is equal or approximately equal to an initial relaxation time of the second portion.

References Cited (Backward Citations)

US4305724A Cited
US4413502A Cited
US4929313A Cited
US4568445A Cited
US5078855A Cited
JPH02226061A Cited
US5145645A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-03-28 1997-09-27 1998-03-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-03-28 2001-09-27 2002-03-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-03-28 2005-09-27 2006-03-29 $7700.00 Window Closed / Lapsed

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