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US5298548A Expired / Lapsed US ⏱️ 0.0 years remaining

Epoxy resin composition and semiconductor devices encapsulated therewith

Assignee: Shin-Etsu Chemical Co Ltd
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Filing: 1992-05-20
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Granted: 1994-03-29
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Expires: 2012-05-20
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Abstract

Abstract An epoxy resin composition comprising (A) a naphthalene ring-containing epoxy resin, (B) a biphenyl-containing epoxy resin, (C) a specific phenolic resin, and (D) an inorganic filler shows good flow and cures to products having low modulus of elasticity, especially at temperatures above Tg, a low coefficient of expansion, high Tg irrespective of low stresses, and minimized water absorption. Then semiconductor devices encapsulated with the present composition remain highly reliable even after being subject to thermal shocks upon surface mounting.

Inventors

  • 👤 Toshio Shiobara
  • 👤 Takayuki Aoki
  • 👤 Kazutoshi Tomiyoshi
  • 👤 Hisashi Shimizu
  • 👤 Takashi Tsuchiya

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 21:29
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/40; C; C08; C08L; C08L63/00; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/32; C08G59/3218; C08G59/38

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 295 words
An epoxy resin composition comprising (A) a naphthalene ring-containing epoxy resin of the following general formula (1): ##STR29## wherein R 1 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, OG is ##STR30## letter k is an integer of from 0 t 5, l is an integer of from 0 to 3, m is an integer of from 0 to 2, and n is equal to 1 or 2, and the OG groups may be attached to either one ring or both rings of the naphthalene ring, (B) a biphenyl-containing epoxy resin of the following formula (2): ##STR31## wherein R 2 is a hydrogen atom, a halogen atom or a monovalent hydrocarbon group having 1 to 5 carbon atoms, and letter q is an integer of from 0 to 5, (C) a phenolic resin of the following formula (3): ##STR32## wherein R 3 is selected from the group consisting of ##STR33## and substituted derivatives thereof in which some or all of the hydrogen atoms in the phenyl ring or rings in R 3 are replaced by alkyl groups having 1 to 5 carbon atoms, R 4 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and letter r is an integer of from 0 to 5, and (D) an inorganic filler present in an amount of 100 to 1,000 parts by weight of filler per 100 parts by weight of components (A), (B) and (C) combined, wherein components (A) and (B) are present in a weight ratio of 1/1 to 9/1 and wherein components (A), (B) and (C) contain epoxy and phenolic hydroxyl groups in such quantities that the molar ratio of epoxy groups to hydroxyl groups in said composition ranges from 1/2 to 3/2.
Claim 2
Dependent Claim 295 words
An epoxy resin composition comprising (A) a naphthalene ring-containing epoxy resin of the following general formula (1): ##STR29## wherein R 1 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, OG is ##STR30## letter k is an integer of from 0 t 5, l is an integer of from 0 to 3, m is an integer of from 0 to 2, and n is equal to 1 or 2, and the OG groups may be attached to either one ring or both rings of the naphthalene ring, (B) a biphenyl-containing epoxy resin of the following formula (2): ##STR31## wherein R 2 is a hydrogen atom, a halogen atom or a monovalent hydrocarbon group having 1 to 5 carbon atoms, and letter q is an integer of from 0 to 5, (C) a phenolic resin of the following formula (3): ##STR32## wherein R 3 is selected from the group consisting of ##STR33## and substituted derivatives thereof in which some or all of the hydrogen atoms in the phenyl ring or rings in R 3 are replaced by alkyl groups having 1 to 5 carbon atoms, R 4 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and letter r is an integer of from 0 to 5, and (D) an inorganic filler present in an amount of 100 to 1,000 parts by weight of filler per 100 parts by weight of components (A), (B) and (C) combined, wherein components (A) and (B) are present in a weight ratio of 1/1 to 9/1 and wherein components (A), (B) and (C) contain epoxy and phenolic hydroxyl groups in such quantities that the molar ratio of epoxy groups to hydroxyl groups in said composition ranges from 1/2 to 3/2.
Claim 3
Dependent Claim 22 words
The epoxy resin composition of claim 1 wherein components (A) and (B) contain about 5 to 80% by weight of naphthalene ring.
Claim 4
Dependent Claim 31 words
The epoxy resin composition of claim 1 wherein 200 to 700 parts by weight of filler (D) is present per 100 parts by weight of components (A), (B) and (C) combined.
Claim 5
Dependent Claim 41 words
The epoxy resin composition of claim 1 which further comprises (E) a silicone-modified copolymer comprising an addition product of an organohydrogen polysiloxane and a resin selected from the group consisting of an alkenyl-containing, epoxidized novolak resin and an alkenyl-containing, naphthalene resin.
Claim 6
Dependent Claim 20 words
A semiconductor device encapsulated with the epoxy resin composition of any one of claims 3 or 4 in cured state.
Claim 7
Dependent Claim 56 words
The claim 1 epoxy resin composition wherein said component (A) is selected from the group consisting of: ##STR34## wherein R is hydrogen or a monovalent hydrocarbon group having 1 to 5 carbon atoms, OG is ##STR35## letter a is equal to 1 or 2, and b and c each are an integer of at least 2.
Claim 8
Dependent Claim 18 words
The claim 1 epoxy resin composition wherein said component (B) is selected from the group consisting of: ##STR36##
Claim 9
Dependent Claim 18 words
The claim 1 epoxy resin composition wherein said component (C) is selected from the group consisting of: ##STR37##
Claim 10
Dependent Claim 13 words
The claim 1 epoxy resin composition which further comprises an additional epoxy resin.
Claim 11
Dependent Claim 55 words
The claim 9 epoxy resin composition wherein said additional epoxy resin is selected from the group consisting of bisphenol-A epoxy resins, phenol novolak epoxy resins, allyl phenol novolak epoxy resins, triphenol alkane epoxy resins, dicyclopentadiene epoxy resins, phenol aralkyl epoxy resins, glycidyl ester epoxy resins, cycloaliphatic epoxy resins, heterocyclic epoxy resins, and halogenated epoxy resins.
Claim 12
Dependent Claim 13 words
The claim 1 epoxy resin composition which further comprises an additional phenolic resin.
Claim 13
Dependent Claim 32 words
The claim 11 epoxy resin composition wherein said additional phenolic resin is selected from the group consisting of novolak phenolic resins, resol phenolic resins, triphenol alkane resins, and naphthalene ring-containing phenolic resins.
Claim 14
Dependent Claim 38 words
The claim 12 epoxy resin composition wherein said naphthalene ring-containing phenolic resins are selected from the group consisting of: ##STR38## wherein R, a and b are as defined above and f is an integer of at least 1.
Claim 15
Dependent Claim 32 words
The claim 1 epoxy resin composition wherein said component (D) is selected from the group consisting of silica, alumina, silicon nitride, aluminum nitride, boron nitride, titanium oxide, glass fibers and mixtures thereof.
Claim 16
Dependent Claim 279 words
A semiconductor device encapsulated with an epoxy resin composition in a cured state, said epoxy resin composition comprising: (A) a naphthalene ring-containing epoxy resin of the following general formula (1): ##STR39## wherein R 1 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, OG is ##STR40## letter k is an integer of from 0 to 5, l is an integer of from 0 to 3, m is an integer of from 0 to 2, and n is equal to 1 or 2, and the OG groups may be attached to either one ring or both rings of the naphthalene ring, (B) a biphenyl-containing epoxy resin of the following formula (2): ##STR41## wherein R 2 is a hydrogen atom, a halogen atom or a monovalent hydrocarbon group having 1 to 5 carbon atoms, and letter q is an integer of from 0 to 5, (C) a phenolic resin of the following formula (3): ##STR42## wherein R 3 is selected from the group consisting of ##STR43## and substituted derivatives thereof in which some or all of the hydrogen atoms in the phenyl ring or rings in R 3 are replaced by alkyl groups having 1 to 5 carbon atoms, R 4 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and letter r is an integer of from 0 to 5, and (D) an inorganic filler, wherein components (A) and (B) are in a weight ratio of 1/1 to 9/1 and wherein components (A), (B) and (C) contain epoxy and phenolic hydroxyl groups in which quantities that the molar ratio of epoxy groups to hydroxyl groups ranges from 1/2 to 3/2.
Claim 17
Dependent Claim 279 words
A semiconductor device encapsulated with an epoxy resin composition in a cured state, said epoxy resin composition comprising: (A) a naphthalene ring-containing epoxy resin of the following general formula (1): ##STR39## wherein R 1 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, OG is ##STR40## letter k is an integer of from 0 to 5, l is an integer of from 0 to 3, m is an integer of from 0 to 2, and n is equal to 1 or 2, and the OG groups may be attached to either one ring or both rings of the naphthalene ring, (B) a biphenyl-containing epoxy resin of the following formula (2): ##STR41## wherein R 2 is a hydrogen atom, a halogen atom or a monovalent hydrocarbon group having 1 to 5 carbon atoms, and letter q is an integer of from 0 to 5, (C) a phenolic resin of the following formula (3): ##STR42## wherein R 3 is selected from the group consisting of ##STR43## and substituted derivatives thereof in which some or all of the hydrogen atoms in the phenyl ring or rings in R 3 are replaced by alkyl groups having 1 to 5 carbon atoms, R 4 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and letter r is an integer of from 0 to 5, and (D) an inorganic filler, wherein components (A) and (B) are in a weight ratio of 1/1 to 9/1 and wherein components (A), (B) and (C) contain epoxy and phenolic hydroxyl groups in which quantities that the molar ratio of epoxy groups to hydroxyl groups ranges from 1/2 to 3/2.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-03-28 1997-09-27 1998-03-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-03-28 2001-09-27 2002-03-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-03-28 2005-09-27 2006-03-29 $7700.00 Window Closed / Lapsed

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