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US5295985A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyesters and their use in compostable products such as disposable diapers

Assignee: EIDP Inc
•
Filing: 1992-11-06
•
Granted: 1994-03-22
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Expires: 2012-11-06
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Abstract

Abstract The invention provides novel polyesters, fibers and films, nonwovens from the fibers and disposable products of the polyesters such as diapers. The products are degradable under the conditions typically existing in waste compositing processes, have low ingredient costs and yet provide strength and toughness properties adequate for end uses such as in disposable diapers. The polyesters are based upon polyester ingredients, such as polyethylene terephthalate, copolymerized with an alkali metal or alkaline earth metal 4-sulfophthalic acid derivative, and other ingredients, such as polyethylene ether glycols and/or non-aromatic diacids, such as adipic and glutaric acids.

Inventors

  • 👤 James A. Romesser
  • 👤 Hyunkook Shin
  • 👤 Raymond F. Tietz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 21:07
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/18; A; A61; A61F; A61F13/00; A61F13/15; A61F13/15203; A61F13/15252; A61L; A61L15/00; A61L15/16; A61L15/22; A61L15/225; A61L15/26; A61L15/42; A61L15/62; C08G; C08G63/00; C08G63/02; C08G63/60; C08G63/66; C08G63/668; C08G63/672; C08G63/68; C08G63/688; C08G63/6884; C08G63/6886; C08L; C08L3/00; C08L3/02; C08L67/00; D; D01; D01F; D01F6/00; D01F6/78; D01F6/84; D01F6/86; D01F6/88; D01F6/92; A61F13/51; A61F2013/51002; A61F2013/51023; A61F2013/51035; A61F13/514; A61F13/51401; A61F2013/51409; A61F2013/51433; A61F13/53; A61F2013/530131; A61F2013/530343; A61F2013/53035; A61F13/534; A61F2013/53481; C08J2367/00; C08J2367/02; C08L2201/00; C08L2201/06; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/31504; Y10T428/31786; Y10T428/3179; Y10T442/00; Y10T442/60; Y10T442/674; Y10T442/675

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 336 words
A fiber and film forming polyester consisting essentially of recurring structural units of the formulae: --[--C(O)--R--C(O)--OGO--].sub.a --[--C(O)--Q--O--].sub.b -- wherein about 0.1 to about 2.5 mole % of R is an alkali metal or alkaline earth metal salt of a 4-sulfophthalic radical, up to about 40 mole % of R is a radical D, in amount d, selected from the group consisting of a chemical bond and one or more divalent, non-aromatic, C 1 -C 10 hydrocarbylene radicals, and the remainder of R is a divalent aromatic radical, with at least about 85 mole % of said remainder being p-phenylene, wherein up to about 30 mole % of G is a polyethylene ether radical E, in amount 4e, selected from the group consisting of --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 -- and --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --, and the remainder of G is selected from the group consisting of hydrocarbylene radicals --(CH 2 ) 2 --, --(CH 2 ) 3 --, and --(CH 2 ) 4 --, and wherein the structural units of the formula: [--C(O)--R--C(O)--OGO--].sub.a contain a total amount of radicals D and/or E that is at least S, wherein S is the total of d+e, where d is the mole % of radical D and e is one quarter of the mole % of radical E, and wherein S is at least 5 mole %, wherein Q is derived from an hydroxy acid of formula HO[--C(O)--Q--O--].sub.x H, where Q is selected from the group consisting of a chemical bond and hydrocarbylene radicals --(CH 2 ) n --(where n is an integer from 1 to 5), --C(R')H--, and --C(R')HCH 2 --, wherein R' is selected from the group of --CH 3 and --CH 2 CH 3 , and where x and Q are selected such that the hydroxy acid has a melting point at least 5 degrees C below its decomposition temperature, and wherein "a⃡ and "b" are mole fractions of the polymer, and the mole fraction "a" is 0.6 to 1 and, correspondingly, mole fraction "b" is 0 to 0.4.
Claim 2
Dependent Claim 336 words
A fiber and film forming polyester consisting essentially of recurring structural units of the formulae: --[--C(O)--R--C(O)--OGO--].sub.a --[--C(O)--Q--O--].sub.b -- wherein about 0.1 to about 2.5 mole % of R is an alkali metal or alkaline earth metal salt of a 4-sulfophthalic radical, up to about 40 mole % of R is a radical D, in amount d, selected from the group consisting of a chemical bond and one or more divalent, non-aromatic, C 1 -C 10 hydrocarbylene radicals, and the remainder of R is a divalent aromatic radical, with at least about 85 mole % of said remainder being p-phenylene, wherein up to about 30 mole % of G is a polyethylene ether radical E, in amount 4e, selected from the group consisting of --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 -- and --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --, and the remainder of G is selected from the group consisting of hydrocarbylene radicals --(CH 2 ) 2 --, --(CH 2 ) 3 --, and --(CH 2 ) 4 --, and wherein the structural units of the formula: [--C(O)--R--C(O)--OGO--].sub.a contain a total amount of radicals D and/or E that is at least S, wherein S is the total of d+e, where d is the mole % of radical D and e is one quarter of the mole % of radical E, and wherein S is at least 5 mole %, wherein Q is derived from an hydroxy acid of formula HO[--C(O)--Q--O--].sub.x H, where Q is selected from the group consisting of a chemical bond and hydrocarbylene radicals --(CH 2 ) n --(where n is an integer from 1 to 5), --C(R')H--, and --C(R')HCH 2 --, wherein R' is selected from the group of --CH 3 and --CH 2 CH 3 , and where x and Q are selected such that the hydroxy acid has a melting point at least 5 degrees C below its decomposition temperature, and wherein "a⃡ and "b" are mole fractions of the polymer, and the mole fraction "a" is 0.6 to 1 and, correspondingly, mole fraction "b" is 0 to 0.4.
Claim 3
Dependent Claim 302 words
A fiber and film forming polyester consisting essentially of recurring structural units of the formulae: --[--C(O)--R--C(O)--OGO--].sub.a --[--C(O)--Q--O--].sub.b -- wherein about 0.1 to about 2.5 mole % of R is an alkali metal or alkaline earth metal salt of a 4-sulfophthalic radical, up to about 40 mole % of R is a radical D selected from the group consisting of a chemical bond and one or more divalent, non-aromatic, C 1 -C 10 hydrocarbylene radicals, and the remainder of R is a divalent aromatic radical, with at least about 85 mole % of said remainder being p-phenylene, wherein up to about 30 mole % of G is a polyethylene ether radical E selected from the group consisting of --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --and--(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --, and the remainder of G is selected from the group consisting of a polyalkylene ether radical F of number average molecular weight at least about 250, and hydrocarbylene radicals --(CH 2 ) 2 --, --(CH 2 ) 3 --, and --(CH 2 ) 4 --, and wherein the structural units of the formula: [--C(O)--R--C(O)--OGO--].sub.a contain at least 5 mole % of radical F, wherein Q is derived from an hydroxy acid of formula HO[--C(O)--Q--O--].sub.x H, where Q is selected from the group consisting of a chemical bond and hydrocarbylene radicals --(CH 2 ) n -- (where n is an integer from 1 to 5), --C(R')H--, and --C(R')HCH 2 --, wherein R' is selected from the group of --CH 3 and --CH 2 CH 3 , and where x and Q are selected such that the hydroxy acid has a melting point at least 5 degrees C below its decomposition temperature, and wherein "a" and "b" are mole fractions of the polymer, and the mole fraction "a" is 0.6 to 1 and, correspondingly, mole fraction "b" is 0 to 0.4.
Claim 4
Dependent Claim 302 words
A fiber and film forming polyester consisting essentially of recurring structural units of the formulae: --[--C(O)--R--C(O)--OGO--].sub.a --[--C(O)--Q--O--].sub.b -- wherein about 0.1 to about 2.5 mole % of R is an alkali metal or alkaline earth metal salt of a 4-sulfophthalic radical, up to about 40 mole % of R is a radical D selected from the group consisting of a chemical bond and one or more divalent, non-aromatic, C 1 -C 10 hydrocarbylene radicals, and the remainder of R is a divalent aromatic radical, with at least about 85 mole % of said remainder being p-phenylene, wherein up to about 30 mole % of G is a polyethylene ether radical E selected from the group consisting of --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --and--(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --, and the remainder of G is selected from the group consisting of a polyalkylene ether radical F of number average molecular weight at least about 250, and hydrocarbylene radicals --(CH 2 ) 2 --, --(CH 2 ) 3 --, and --(CH 2 ) 4 --, and wherein the structural units of the formula: [--C(O)--R--C(O)--OGO--].sub.a contain at least 5 mole % of radical F, wherein Q is derived from an hydroxy acid of formula HO[--C(O)--Q--O--].sub.x H, where Q is selected from the group consisting of a chemical bond and hydrocarbylene radicals --(CH 2 ) n -- (where n is an integer from 1 to 5), --C(R')H--, and --C(R')HCH 2 --, wherein R' is selected from the group of --CH 3 and --CH 2 CH 3 , and where x and Q are selected such that the hydroxy acid has a melting point at least 5 degrees C below its decomposition temperature, and wherein "a" and "b" are mole fractions of the polymer, and the mole fraction "a" is 0.6 to 1 and, correspondingly, mole fraction "b" is 0 to 0.4.
Claim 5
Dependent Claim 17 words
A polyester according to claim 1, wherein at least about 97.5 mole % of R is p-phenylene.
Claim 6
Dependent Claim 10 words
A fiber of the polyester of claim 1 or 3.
Claim 7
Dependent Claim 11 words
A non-woven sheet of the polyester of claim 1 or 3.
Claim 8
Dependent Claim 10 words
A film of the polyester of claim 1 or 3.
Claim 9
Dependent Claim 10 words
A foam of the polyester of claim 1 or 3.
Claim 10
Dependent Claim 18 words
A composite of the film of claim 6 and of a layer of nonwoven sheet or of paper.
Claim 11
Dependent Claim 26 words
A disposable diaper which includes an absorbent body portion having on one surface thereof a water permeable sheet of the polyester of claim 1 or 3.
Claim 12
Dependent Claim 26 words
A disposable diaper which includes an absorbent body portion having on one surface thereof a water impermeable sheet of the polyester of claim 1 or 3.
Claim 13
Dependent Claim 17 words
A polyester according to claim 2, wherein at least about 97.5 mole % of R is p-phenylene.
Claim 14
Dependent Claim 10 words
A fiber of the polyester of claim 2 or 11.
Claim 15
Dependent Claim 11 words
A non-woven sheet of the polyester of claim 2 or 11.
Claim 16
Dependent Claim 10 words
A film of the polyester of claim 2 or 11.
Claim 17
Dependent Claim 10 words
A foam of the polyester of claim 2 or 11.
Claim 18
Dependent Claim 18 words
A composite of the film of claim 14 and of a layer of nonwoven sheet or of paper.

References Cited (Backward Citations)

US3018272A Cited
US3853820A Cited
US4418116A Cited
US4526738A Cited
US4483976A Cited
US4704329A Cited
US4883706A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-03-21 1997-09-20 1998-03-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-03-21 2001-09-20 2002-03-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-03-21 2005-09-20 2006-03-22 $7700.00 Window Closed / Lapsed

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