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US5294426A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrorheological fluid compositions

Assignee: Colloid Research Institute
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Filing: 1991-07-22
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Granted: 1994-03-15
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Expires: 2011-07-22
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Abstract

Abstract Electrorheological fluid compositions of this invention are dispersions in an electrically insulating medium of 10 to 50% by volume of spherical silica particles prepared by hydrolyzing a silicon alkoxide of the general formula Si(OR) 4 in which R is an alkyl group in the presence of an alkali catalyst and drying at or below 500° C., show excellent fluidity in the absence of an applied voltage, vary reversibly to the state of high viscosity or even to the state of gel on application of a voltage, and have good storage stability.

Inventors

  • 👤 Masahiro Sekine
  • 👤 Yasufumi Otsubo
  • 👤 Shingo Katayama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 03:43
CPC Classifications
C; C10; C10M; C10M171/00; C10M171/001

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 178 words
An electrorheological fluid composition consisting essentially of an electrically nonconducting liquid and 10 to 50 vol. % silica particles dispersed therein, wherein the nonconducting liquid being at least one member selected from the group consisting of petroleum-derived lubricants, transformer oils, silicone oils, dibutyl sebacate, chlorinated paraffins, alkyl bromides, aromatic polycarboxylic acid alkyl esters, aromatic polycarboxylic acid halophenylalkyl esters, halophenyl alkyl ethers, and fluorine-containing oils and the silica particles being spherical particles formed by hydrolyzing a silicon alkoxide in a reaction mother liquor, the silicon alkoxide being of the following general formula (1) Si(OR).sub.4 ( 1) in which R is an alkyl group in the presence of an alkali catalyst, and drying at or below 500° C. and the silica particles: have an average diameter of 0.1-2.0 μm, have a BET nitrogen specific absorption area of ≦100 m 2 /g, have a carbon content of ≦3% and have a weight lose of 2-12% when heated up to 200° C. in thermogravimetric analysis and a weight lose of 2-10% when heated to 200° C. to 1000° C. in thermogravimetric analysis.
Claim 2
Dependent Claim 178 words
An electrorheological fluid composition consisting essentially of an electrically nonconducting liquid and 10 to 50 vol. % silica particles dispersed therein, wherein the nonconducting liquid being at least one member selected from the group consisting of petroleum-derived lubricants, transformer oils, silicone oils, dibutyl sebacate, chlorinated paraffins, alkyl bromides, aromatic polycarboxylic acid alkyl esters, aromatic polycarboxylic acid halophenylalkyl esters, halophenyl alkyl ethers, and fluorine-containing oils and the silica particles being spherical particles formed by hydrolyzing a silicon alkoxide in a reaction mother liquor, the silicon alkoxide being of the following general formula (1) Si(OR).sub.4 ( 1) in which R is an alkyl group in the presence of an alkali catalyst, and drying at or below 500° C. and the silica particles: have an average diameter of 0.1-2.0 μm, have a BET nitrogen specific absorption area of ≦100 m 2 /g, have a carbon content of ≦3% and have a weight lose of 2-12% when heated up to 200° C. in thermogravimetric analysis and a weight lose of 2-10% when heated to 200° C. to 1000° C. in thermogravimetric analysis.
Claim 3
Dependent Claim 28 words
An electrorheolotical fluid composition according to claim 1 wherein said silica particles are separated from the reaction mother liquor of the hydrolysing step prior to the drying step.
Claim 4
Dependent Claim 28 words
An electrorheological fluid composition according to claim 1 wherein the reaction mother liquor of the hydrolyzing step is replaced by the nonconducting liquid prior to the drying step.
Claim 5
Dependent Claim 89 words
An electrorheological fluid composition consisting essentially of an electrically nonconductive liquid selected from the group consisting of petroleum-derived lubricants, transformer oils, silicone oils, dibutyl sebacate, chlorinated paraffins, alkyl bromides, aromatic polycarboxylic acid alkyl esters, aromatic polycarboxylic acid halophenylalkyl esters, halophenyl alkyl ethers, and fluorine-containing oils and silica particles dispersed therein in an amount of 10 to 50 vol. %, wherein the silica particles: have an average diameter of 0.1-2.0 μm, have a BET nitrogen specific absorption area of ≦100 m 2 /g, and have a carbon content of ≦3%.
Claim 6
Dependent Claim 89 words
An electrorheological fluid composition consisting essentially of an electrically nonconductive liquid selected from the group consisting of petroleum-derived lubricants, transformer oils, silicone oils, dibutyl sebacate, chlorinated paraffins, alkyl bromides, aromatic polycarboxylic acid alkyl esters, aromatic polycarboxylic acid halophenylalkyl esters, halophenyl alkyl ethers, and fluorine-containing oils and silica particles dispersed therein in an amount of 10 to 50 vol. %, wherein the silica particles: have an average diameter of 0.1-2.0 μm, have a BET nitrogen specific absorption area of ≦100 m 2 /g, and have a carbon content of ≦3%.
Claim 7
Dependent Claim 19 words
An electrorheological fluid composition as defined in claim 4, wherein the amount of silica particles is 15-45 vol. %.

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3.5 Years (Year 4) 1997-03-14 1997-09-13 1998-03-15 $2000.00 Window Closed / Lapsed
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