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US5292610A Expired / Lapsed US ⏱️ 0.0 years remaining

Microcapsules and their use

Assignee: Agfa Gevaert AG
•
Filing: 1992-03-06
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Granted: 1994-03-08
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Expires: 2012-03-06
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Abstract

Abstract Microcapsules containing at least one leuco dye, at least one photopolymerisation initiator and at least one photopolymerisable monomer corresponding to the following formula A[--NHCO--X--L.sub.1 --(OCO--CR.sub.1 =CH.sub.2).sub.1 ].sub.m wherein A stands for a 3- to 6-valent organic group having the following meanings: a) a saturated hydrocarbon group having 5 to 25 carbon atoms or b) ##STR1## or c) ##STR2## wherein A 1 , A 2 , R 3 , R 4 , o and p have the meanings indicated in the description, X denotes O or NR 2 , L 1 denotes a divalent or trivalent aliphatic hydrocarbon group whose carbon chain may be interrupted by 1 to 3 oxygen atoms, R 1 denotes hydrogen or methyl, R 2 denotes hydrogen or C 1 -C 4 -alkyl, l denotes 1 or 2 and m denotes a number from 3 to 6, are distinguished by improved sensitivity.

Inventors

  • 👤 Gunter Helling
  • 👤 Michael Muller
  • 👤 Wolfgang Podszun

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 17:20
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/002; G03F7/004; G03F7/027; Y; Y10; Y10S; Y10S430/00; Y10S430/163

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 243 words
Microcapsules comprising a wall containing an internal phase comprising at least one leuco dye, at least one photopolymerisation initiator and at least one photopolymerisable monomer, characterized in that the photopolymerisable monomer corresponds to the following formula A[-NHCO-X-L.sub.1 -(OCO-CR.sub.1 ═CH.sub.2).sub.n ].sub.m wherein A denotes a tri- to hexa-valent organic group having the following meanings: a) a saturated hydrocarbon group having 5 to 25 carbon atoms or b) ##STR7## wherein A 1 stands for a straight chained or branched aliphatic group having 2 to 20 carbon atoms and optionally containing 1 to 3 oxygen atoms, an aromatic group having 6 to 24 carbon atoms, an araliphatic group having 7 to 26 carbon atoms or a cycloaliphatic group having 6 to 26 carbon atoms, R 3 and R 4 denote hydrogen or methyl, A 2 denotes a saturated hydrocarbon group having 5 to 25 carbon atoms, o denotes a number from 0 to 5 and p denotes a number from 3 to 6, or c) ##STR8## wherein A 1 , A 2 , R 3 , R 4 , o and p have the meanings indicated above, X denotes O or NR 2 , L 1 denotes a divalent or trivalent aliphatic hydrocarbon group whose carbon chain may be interrupted by 1 to 3 oxygen atoms, R 1 denotes hydrogen or methyl, R 2 denotes hydrogen or C 1 -C 4 -alkyl, n stands for 2 and m stands for a number from 3 to 6.
Claim 2
Dependent Claim 243 words
Microcapsules comprising a wall containing an internal phase comprising at least one leuco dye, at least one photopolymerisation initiator and at least one photopolymerisable monomer, characterized in that the photopolymerisable monomer corresponds to the following formula A[-NHCO-X-L.sub.1 -(OCO-CR.sub.1 ═CH.sub.2).sub.n ].sub.m wherein A denotes a tri- to hexa-valent organic group having the following meanings: a) a saturated hydrocarbon group having 5 to 25 carbon atoms or b) ##STR7## wherein A 1 stands for a straight chained or branched aliphatic group having 2 to 20 carbon atoms and optionally containing 1 to 3 oxygen atoms, an aromatic group having 6 to 24 carbon atoms, an araliphatic group having 7 to 26 carbon atoms or a cycloaliphatic group having 6 to 26 carbon atoms, R 3 and R 4 denote hydrogen or methyl, A 2 denotes a saturated hydrocarbon group having 5 to 25 carbon atoms, o denotes a number from 0 to 5 and p denotes a number from 3 to 6, or c) ##STR8## wherein A 1 , A 2 , R 3 , R 4 , o and p have the meanings indicated above, X denotes O or NR 2 , L 1 denotes a divalent or trivalent aliphatic hydrocarbon group whose carbon chain may be interrupted by 1 to 3 oxygen atoms, R 1 denotes hydrogen or methyl, R 2 denotes hydrogen or C 1 -C 4 -alkyl, n stands for 2 and m stands for a number from 3 to 6.
Claim 3
Dependent Claim 23 words
Microcapsules according to claim 1, characterized in that L 1 has 2 to 15 carbon atoms and is straight chained, branched or cyclic.
Claim 4
Dependent Claim 41 words
Microcapsules according to claim 1, wherein A is selected from the group consisting of ##STR9## wherein R 5 and R 6 denote hydrogen or C 1 -C 4 -alkyl and x and y denote each a number from 2 to 6.
Claim 5
Dependent Claim 34 words
Microcapsules according to claim 1, wherein the quantity of photopolymerisable monomers corresponding to the formula A[--NHCO--X--L.sub.1 --(OCO--CR.sub.1 ═CH.sub.2).sub.n ].sub.m is from 25 to 98% by weight, based on the internal phase of the microcapsules.
Claim 6
Dependent Claim 34 words
Microcapsules according to claim 1, wherein the quantity of photopolymerisable monomers corresponding to the formula A['NHCO--X--L.sub.1 --(OCO--CR.sub.1 ═CH.sub.2).sub.n ].sub.m is from 35 to 95% by weight, based on the internal phase of the microcapsules.
Claim 7
Dependent Claim 49 words
Microcapsules according to claim 1, wherein, in addition to said at least one leuco dye, at least one photopolyermisation initiator and at least one photopolymerisable monomer, said internal phase further comprises reactive diluents in a quantity of from 5-50% by weight, based on the internal phase of the microcapsules.
Claim 8
Dependent Claim 17 words
Microcapsules according to claim 6, wherein said reactive diluents comprises at least one of monoacrylates and monomethyacryates.
Claim 9
Dependent Claim 36 words
Microcapsules according to claim 6, wherein said reactive diluents comprise at least one comonomer selected from the group consisting of glycerol di(meth)acrylate, triethylene glycol di(meth)acrylate, tetraethyleneglycol di(meth)acrylate, 1,12-dodecanediol di(meth)acrylate, 1,6-hexanediol di(methy)acrylate, diethyleneglycol di(methy)acrylate and trimethylolpropane tri(meth)acrylate.
Claim 10
Dependent Claim 31 words
Microcapsules according to claim 1, wherein said wall comprises at least one material selected from the group consisting of polyurethanes, polyureas, polyamides, polyesters, ammonium aldehyde resins, gelatines, epoxy resins and polycarbonates.
Claim 11
Dependent Claim 16 words
Microcapsules according to claim 1, wherein said microcapsules have an average particle size of from 1-40μ.
Claim 12
Dependent Claim 25 words
Microcapsules according to claim 1, wherein said at least one photopolymerisation initiator disintegrates on exposure to at least one of UV light and visible light.

References Cited (Backward Citations)

US4399209A Cited
GB2159973A Cited
US4940645A Cited
US5085974A Cited
US5064744A Cited

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