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US5268052A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermal transfer material and thermal transfer recording method

Assignee: Canon Inc
•
Filing: 1990-04-24
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Granted: 1993-12-07
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Expires: 2010-04-24
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Abstract

Abstract A thermal transfer material including a support and a heat-transferable ink layer disposed thereon, wherein the heat-transferable ink layer has a storage elasticity modulus E' satisfying a relationship of: 1×10 7 ≦E'≦1×10 9 N/m 2 at 30° C.; and the temperature providing a thermal differential value of dynamic energy loss angle (tanδ) satisfying a relationship of d(tanδ)/dT=1×10 -2 is in the range of 40° to 60° C.

Inventors

  • 👤 Yoshihisa Takizawa
  • 👤 Naoki Kushida
  • 👤 Takayuki Suzuki
  • 👤 Tetsuo Hasegawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 21:15
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/382; B41M5/392; B41M5/395; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/31935

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 213 words
A thermal transfer recording method, comprising: providing a thermal transfer material further comprising a support and a heat-transferable ink layer disposed thereon, wherein the heat-transferable ink layer, as a whole has a storage elasticity modulus E' satisfying a relationship of: 1×10.sup.7 ≦E'≦1×10.sup.9 N/m.sup.2 at 30° C., and has a temperature providing a thermal differential value of dynamic energy loss angle (tan δ) satisfying a relationship of d(tan δ)/dT=1×10 -2 in the range of 40° to 60° C., and said heat-transferable ink layer comprises a heat-fusible binder which in turn contains 20-75% of a wax and 25-80% of a heat-fusible resin; causing the thermal transfer material to contact a recording medium with its ink layer side; supplying a pattern of energy from a recording head to the thermal transfer material; and separating the thermal transfer material from the recording medium to leave a transferred image on the recording medium; wherein the thermal transfer material moves in a unit period of time by a first distance relative to the recording head which is smaller than a second distance relative to the recording head through which the recording medium moves in the same period of time so that a particular region of the thermal transfer material can withstand a desired number of thermal transfer recording operations.
Claim 2
Dependent Claim 213 words
A thermal transfer recording method, comprising: providing a thermal transfer material further comprising a support and a heat-transferable ink layer disposed thereon, wherein the heat-transferable ink layer, as a whole has a storage elasticity modulus E' satisfying a relationship of: 1×10.sup.7 ≦E'≦1×10.sup.9 N/m.sup.2 at 30° C., and has a temperature providing a thermal differential value of dynamic energy loss angle (tan δ) satisfying a relationship of d(tan δ)/dT=1×10 -2 in the range of 40° to 60° C., and said heat-transferable ink layer comprises a heat-fusible binder which in turn contains 20-75% of a wax and 25-80% of a heat-fusible resin; causing the thermal transfer material to contact a recording medium with its ink layer side; supplying a pattern of energy from a recording head to the thermal transfer material; and separating the thermal transfer material from the recording medium to leave a transferred image on the recording medium; wherein the thermal transfer material moves in a unit period of time by a first distance relative to the recording head which is smaller than a second distance relative to the recording head through which the recording medium moves in the same period of time so that a particular region of the thermal transfer material can withstand a desired number of thermal transfer recording operations.
Claim 3
Dependent Claim 22 words
A thermal transfer recording method according to claim 1, wherein the wax has a melting behavior ΔT not larger than 20° C.
Claim 4
Dependent Claim 35 words
A thermal transfer recording method according to claim 1, wherein the heat-fusible binder further comprises at least one species selected from the group consisting of: ethylene-vinyl acetate copolymer, ethylene-acrylic acid copolymer, and ethylene-ethyl acrylate copolymer.
Claim 5
Dependent Claim 22 words
A thermal transfer recording method according to claim 3, wherein the heat-fusible resin has a melt flow rate of 150-800 g/10 min.
Claim 6
Dependent Claim 23 words
A material according to claim 3, wherein said copolymers comprise vinyl acetate, acrylic acid and ethyl acrylate, respectively, at a content of 15-33%.
Claim 7
Dependent Claim 34 words
A material according to claim 1, wherein the wax further comprises a compound obtained by reacting an isocyanate group-containing compound with an ester compound prepared from a higher fatty acid and a polyhydric alcohol.
Claim 8
Dependent Claim 29 words
A thermal transfer recording method according to claim 1, wherein the wax further comprises a polymerized product prepared from an isocyanate compound and a higher fatty acid pentaerythritol ester.
Claim 9
Dependent Claim 43 words
A thermal transfer recording method according to claim 1, wherein the heat-transferable ink layer further comprises a heat-fusible binder comprising a higher fatty acid polyhydric alcohol ester and a polymerized product prepared from an isocyanate compound and a higher fatty acid pentaerythritol ester.
Claim 10
Dependent Claim 52 words
A thermal transfer recording method according to claim 1, wherein the heat-transferable ink layer has a melt viscosity satisfying the following relationship: (lnη.sub.100° C. -lnη.sub.150° C.)/50≦0.05 wherein η 100 ° C. denotes a melt viscosity (cps) at 100° C. and η 150 ° C. denotes a melt viscosity (cps) at 150° C.
Claim 11
Dependent Claim 37 words
A thermal transfer recording method according to claim 1, wherein the melting point (mp 1 ) of the wax and the melting point (mp 2 ) of the resin satisfy a relationship of: |mp.sub.2 -mp.sub.1 |≦10° C.
Claim 12
Dependent Claim 18 words
A thermal transfer recording method according to claim 1, wherein the heat-transferable ink layer has a multi-layer structure.
Claim 13
Dependent Claim 24 words
A thermal transfer recording method according to claim 11, wherein the multi-layer structure contains a transparent top layer disposed most distant from the support.
Claim 14
Dependent Claim 40 words
A thermal transfer recording method according to claim 12, wherein the melting point mp(top) of the top layer and the melting point mp(ink) of the ink layer disposed between the top layer and the support satisfy a relationship of mp(ink)≧mp(top).
Claim 15
Dependent Claim 63 words
A thermal transfer recording method according to claim 1, wherein the heat-transferable ink layer has a multi-layer structure such that the ink layer closer to the support further comprises a wax having a higher melting point than that of the wax contained in a layer which is adjacent to the ink layer and is more distant from the support than the ink layer.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-12-06 1997-06-07 1997-12-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-12-06 2001-06-07 2001-12-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-12-06 2005-06-07 2005-12-07 $7700.00 Window Closed / Lapsed

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