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US5267019A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and apparatus for reducing fringe interference in laser spectroscopy

Assignee: CONSORTIUM FOR SURFACE PROCESSING Inc A NEW JERSEY CORP
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Filing: 1991-09-30
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Granted: 1993-11-30
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Expires: 2011-09-30
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Abstract

Abstract A method and apparatus using a frequency tunable laser to generate a beam which passes through a sample cell and onto an optical detector wherein the tunable laser is modulated at a predetermined frequency which has the undesired effect of producing a periodic interference fringe near an absorption induced signal. An additional level of modulation is applied to the laser beam by a triangular waveform having a predetermined peak-to-peak amplitude and frequency. The triangular waveform peak-to-peak amplitude produces a frequency swing of the laser beam so as to generate from the periodic interference fringe, a signal having reduced components near the absorption induced signal. The signal at the optical detector is demodulated by a lock-in amplifier tuned to a predetermined harmonic of the frequency of the triangular waveform.

Inventors

  • 👤 Edward A. Whittaker
  • 👤 Hoi C. Sun

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 13:48
CPC Classifications
G; G01; G01J; G01J3/00; G01J3/02; G01J3/0262; G01J3/28; G01J3/42; G01J3/433; G01J3/4338; G01N; G01N21/00; G01N21/17; G01N21/25; G01N21/31; G01N21/39; G01N2021/396; G01N2021/399

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 164 words
A method for reducing fringe interference in laser absorption spectroscopy using a frequency tunable laser aligned to pass a laser beam through a sample volume and to an optical detector to thereby detect an absorption induced signal from the sample, said method comprising the steps of: modulating the tunable laser at a first predetermined frequency having the undesired effect of generating a periodic interference fringe near the absorption induced signal; modulating the tunable laser with a triangular waveform having a predetermined peak-to-peak amplitude and a second predetermined frequency different from said first predetermined frequency, the predetermined peak-to-peak amplitude of the triangular waveform being selected to generate a frequency swing of the laser beam sufficient to produce from the periodic interference fringe a signal having reduced components near an absorption induced signal; and demodulating the signal received by the optical detector at a predetermined harmonic of the second predetermined frequency of the triangular waveform; whereby the signal-to-background ratio of the absorption induced signal is enhanced.
Claim 2
Independent Claim 164 words
A method for reducing fringe interference in laser absorption spectroscopy using a frequency tunable laser aligned to pass a laser beam through a sample volume and to an optical detector to thereby detect an absorption induced signal from the sample, said method comprising the steps of: modulating the tunable laser at a first predetermined frequency having the undesired effect of generating a periodic interference fringe near the absorption induced signal; modulating the tunable laser with a triangular waveform having a predetermined peak-to-peak amplitude and a second predetermined frequency different from said first predetermined frequency, the predetermined peak-to-peak amplitude of the triangular waveform being selected to generate a frequency swing of the laser beam sufficient to produce from the periodic interference fringe a signal having reduced components near an absorption induced signal; and demodulating the signal received by the optical detector at a predetermined harmonic of the second predetermined frequency of the triangular waveform; whereby the signal-to-background ratio of the absorption induced signal is enhanced.
Claim 3
Dependent Claim 99 words
The method according to claim 1 further comprising the step of determining the difference between the free spectral range of the interference fringe and the spectral linewidth of the absorption induced signal; wherein the predetermined peak-to-peak amplitude of the triangular waveform is selected to generate a frequency swing of the laser beam substantially equal to (n+1/2) times the free spectral range frequency of the interference fringe when the difference between the free spectral range of the interference fringe and the absorption induced signal linewidth is about one order of magnitude or less; and wherein n is a positive integer.
Claim 4
Dependent Claim 38 words
The method according to claim 2 wherein the step of demodulating the signal received at the optical detector comprises the step of demodulating the signal at an odd harmonic of the second predetermined frequency of the triangular waveform.
Claim 5
Dependent Claim 96 words
The method according to claim 1 further comprising the step of determining the difference between the free spectral range of the interference fringe and the spectral linewidth of the absorption induced signal; and wherein the predetermined peak-to-peak amplitude of the triangular waveform is selected to generate a predetermined frequency swing of the laser beam substantially equal to a positive integer times the free spectral range frequency of the interference fringe when the difference between the free spectral range of the interference fringe and the absorption induced signal linewidth is about one order of magnitude or less.
Claim 6
Dependent Claim 38 words
The method according to claim 4 wherein the step of demodulating the signal received at the optical detector comprises the step of demodulating the signal at an even harmonic of the second predetermined frequency of the triangular waveform.
Claim 7
Dependent Claim 32 words
The method according to claim 1 wherein the predetermined peak-to-peak amplitude of the triangular waveform is selected to produce a frequency swing of the laser beam to maximize the absorption induced signal.
Claim 8
Dependent Claim 105 words
The method according to claim 6 further comprising the step of determining the difference between the free spectral range of the interference fringe and the spectral linewidth of the absorption induced signal; and wherein the step of demodulating the signal received by the optical detector comprises the step of demodulating the signal at the second harmonic or a higher harmonic of the second predetermined frequency of the triangular waveform when the difference between the free spectral range of the interference fringe and the spectral linewidth of the absorption induced signal is in the range of about one order of magnitude to two orders of magnitude.
Claim 9
Independent Claim 188 words
A method for reducing fringe interference in laser absorption spectroscopy using a frequency tunable laser aligned to pass a laser beam through a sample volume and to an optical detector to thereby detect an absorption induced signal from the sample, said method comprising the steps of: modulating the tunable laser at a first predetermined frequency having the undesired effect of generating a periodic interference fringe near the absorption induced signal; sweeping the first predetermined frequency of the tunable laser relatively slowly over a predetermined range to obtain a spectrum including the absorption induced signal; modulating the tunable laser with a triangular waveform having a predetermined peak-to-peak amplitude and a second predetermined frequency different from said first predetermined frequency, the predetermined peak-to-peak amplitude of the triangular waveform being selected to generate a frequency swing of the laser beam sufficient to produce from the periodic interference fringe a signal having reduced components near an absorption induced signal; and demodulating the signal received by the optical detector at a predetermined harmonic of the second predetermined frequency of the triangular waveform; whereby the signal-to-background ratio of the absorption induced signal is enhanced.
Claim 10
Independent Claim 188 words
A method for reducing fringe interference in laser absorption spectroscopy using a frequency tunable laser aligned to pass a laser beam through a sample volume and to an optical detector to thereby detect an absorption induced signal from the sample, said method comprising the steps of: modulating the tunable laser at a first predetermined frequency having the undesired effect of generating a periodic interference fringe near the absorption induced signal; sweeping the first predetermined frequency of the tunable laser relatively slowly over a predetermined range to obtain a spectrum including the absorption induced signal; modulating the tunable laser with a triangular waveform having a predetermined peak-to-peak amplitude and a second predetermined frequency different from said first predetermined frequency, the predetermined peak-to-peak amplitude of the triangular waveform being selected to generate a frequency swing of the laser beam sufficient to produce from the periodic interference fringe a signal having reduced components near an absorption induced signal; and demodulating the signal received by the optical detector at a predetermined harmonic of the second predetermined frequency of the triangular waveform; whereby the signal-to-background ratio of the absorption induced signal is enhanced.
Claim 11
Dependent Claim 99 words
The method according to claim 8 further comprising the step of determining the difference between the free spectral range of the interference fringe and the spectral linewidth of the absorption induced signal; wherein the predetermined peak-to-peak amplitude of the triangular waveform is selected to generate a frequency swing of the laser beam substantially equal to (n+1/2) times the free spectral range frequency of the interference fringe when the difference between the free spectral range of the interference fringe and the absorption induced signal linewidth is about one order of magnitude or less; and wherein n is a positive integer.
Claim 12
Dependent Claim 38 words
The method according to claim 9 wherein the step of demodulating the signal received at the optical detector comprises the step of demodulating the signal at an odd harmonic of the second predetermined frequency of the triangular waveform.
Claim 13
Dependent Claim 96 words
The method according to claim 8 further comprising the step of determining the difference between the free spectral range of the interference fringe and the spectral linewidth of the absorption induced signal; and wherein the predetermined peak-to-peak amplitude of the triangular waveform is selected to generate a predetermined frequency swing of the laser beam substantially equal to a positive integer times the free spectral range frequency of the interference fringe when the difference between the free spectral range of the interference fringe and the absorption induced signal linewidth is about one order of magnitude or less.
Claim 14
Dependent Claim 38 words
The method according to claim 11 wherein the step of demodulating the signal received at the optical detector comprises the step of demodulating the signal at an even harmonic of the second predetermined frequency of the triangular waveform.
Claim 15
Dependent Claim 32 words
The method according to claim 8 wherein the predetermined peak-to-peak amplitude of the triangular waveform is selected to produce a frequency swing of the laser beam to maximize the absorption induced signal.
Claim 16
Dependent Claim 105 words
The method according to claim 13 further comprising the step of determining the difference between the free spectral range of the interference fringe and the spectral linewidth of the absorption induced signal; and wherein the step of demodulating the signal received by the optical detector comprises the step of demodulating the signal at the second harmonic or a higher harmonic of the second predetermined frequency of the triangular waveform when the difference between the free spectral range of the interference fringe and the spectral linewidth of the absorption induced signal is in the range of about one order of magnitude to two orders of magnitude.
Claim 17
Dependent Claim 200 words
A laser spectrometer for detecting and absorption induced signal from a sample, said spectrometer comprising: a frequency tunable laser for generating a laser beam; an optical detector positioned in the optical path of the laser beam; a cell for containing a sample, said cell positioned in the optical path of the laser beam between said frequency tunable laser and said optical detector; a modulator coupled to said frequency tunable laser for modulating same at a first predetermined frequency and having the undesired effect of generating a periodic fringe near an absorption induced signal; a triangular waveform generator cooperating with said modulator for further modulating said frequency tunable laser with a triangular waveform having a predetermined peak-to-peak amplitude and a second predetermined frequency different from said first predetermined frequency, said predetermined peak-to-peak amplitude of said triangular waveform producing a frequency swing of said laser beam so as to generate from the periodic interference fringe a signal having reduced components near the absorption induced signal of the sample; and a demodulator coupled to said optical detector for obtaining the absorption induced signal, said demodulator including a lock-in amplifier tuned to a predetermined harmonic of said second predetermined frequency of said triangular waveform.
Claim 18
Dependent Claim 200 words
A laser spectrometer for detecting and absorption induced signal from a sample, said spectrometer comprising: a frequency tunable laser for generating a laser beam; an optical detector positioned in the optical path of the laser beam; a cell for containing a sample, said cell positioned in the optical path of the laser beam between said frequency tunable laser and said optical detector; a modulator coupled to said frequency tunable laser for modulating same at a first predetermined frequency and having the undesired effect of generating a periodic fringe near an absorption induced signal; a triangular waveform generator cooperating with said modulator for further modulating said frequency tunable laser with a triangular waveform having a predetermined peak-to-peak amplitude and a second predetermined frequency different from said first predetermined frequency, said predetermined peak-to-peak amplitude of said triangular waveform producing a frequency swing of said laser beam so as to generate from the periodic interference fringe a signal having reduced components near the absorption induced signal of the sample; and a demodulator coupled to said optical detector for obtaining the absorption induced signal, said demodulator including a lock-in amplifier tuned to a predetermined harmonic of said second predetermined frequency of said triangular waveform.
Claim 19
Dependent Claim 76 words
The laser spectrometer according to claim 15 wherein said triangular waveform generator includes means for generating a predetermined peak-to-peak amplitude of said triangular waveform so as to produce a frequency swing of the laser beam substantially equal to (n+1/2) times the free spectral range frequency of the periodic interference fringe; wherein n is a positive integer; and wherein said lock-in amplifier is tuned to an odd harmonic of the second predetermined frequency of said triangular waveform.
Claim 20
Dependent Claim 74 words
The laser spectrometer according to claim 15 wherein said triangular waveform generator includes means for generating a predetermined peak-to-peak amplitude of said triangular waveform so as to produce a frequency swing of said laser beam substantially equal to a positive integer times the free spectral range frequency of the periodic interference fringe; and wherein said demodulator includes a lock-in amplifier tuned to an even harmonic of the second predetermined frequency of said triangular waveform.
Claim 21
Dependent Claim 32 words
The laser spectrometer according to claim 15 wherein said triangular waveform generator includes means for generating a predetermined peak-to-peak amplitude of said triangular waveform so as to maximize the absorption induced signal.
Claim 22
Dependent Claim 66 words
The laser spectrometer according to claim 18 wherein said lock-in amplifier is tuned to the second harmonic or a higher harmonic of the second predetermined frequency of the triangular waveform when a difference between the free spectral range of the interference fringe and the spectral linewidth of the absorption induced signal is in the range of about one order of magnitude to two orders of magnitude.
Claim 23
Dependent Claim 38 words
The laser spectrometer according to claim 15 further comprising a controller cooperating with said modulator for slowly sweeping the first predetermined frequency of said laser beam over a range to obtain a spectrum including the absorption induced signal.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-11-29 1997-05-31 1997-11-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-11-29 2001-05-31 2001-11-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-11-29 2005-05-31 2005-11-30 $7700.00 Window Closed / Lapsed

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