Epoxidation process using titanium-rich silicalite catalysts

Claim 2

A process for producing an epoxide comprising contacting an olefin with a hydrogen peroxide source in the presence of a catalytically effective amount of a titanium silicalite zeolite having a Si:Ti molar ratio in the lattice framework of said zeolite of from 8:1 to 18:1 for a time and at a temperature effective to convert the olefin to epoxide.

Claim 3

The process of claim 1 wherein the crystalline titanium silicalite zeolite has an MFI or MEL topology.

Claim 4

The process of claim 1 wherein an organic solvent is additionally present during said contacting.

Claim 5

The process of claim 1 wherein said titanium silicalite zeolite is prepared using a solution of titanium tetrabutoxide dissolved in an anhydrous alcoholic medium.

Claim 6

The process of claim 1 wherein said titanium silicalite zeolite is prepared using a quaternary ammonium salt selected from tetrapropyl ammonium hydroxide, tetrabutyl ammonium hydroxide, methyltributyl ammonium hydroxide, trimethyl ethanol ammonium hydroxide, tetramethyl ammonium hydroxide, and mixtures thereof.

Claim 7

The process of claim 1 wherein the hydrogen peroxide source is produced by oxidation of an aryl-substituted secondary alcohol with molecular oxygen.

Claim 8

The process of claim 1 wherein the temperature is from 0° C. to 150° C.

Claim 9

The process of claim 1 wherein the olefin has the general formula ##STR3## wherein R 1 , R 2 , R 3 , and R 4 are the same or different and are selected from hydrogen, C 1 -C 20 alkyl, C 7 -C 20 aryl alkyl, C 5 -C 12 cycloalkyl, C 6 -C 20 alkyl cycloalkyl, and C 6 -C 20 aryl.

Claim 10

The process of claim 1 wherein the amount of titanium silicalite zeolite is from 0.01 to 10 grams per mole of olefin.

Claim 11

The process of claim 1 wherein said process is conducted at a pressure of between 1 and 100 atmospheres.

Claim 12

The process of claim 1 wherein the Si:Ti molar ratio is from 9.5:1 to 18:1.

Claim 13

The process of claim 1 wherein the molar ratio of olefin:hydrogen peroxide source is from 1:10 to 10:1.

Claim 14

A process for producing an epoxide comprising contacting an olefin with a hydrogen peroxide source in the presence of an organic solvent and titanium silicalite zeolite having a Si:Ti molar ratio in the lattice framework of said zeolite of from 9.5:1 to 18:1 at a temperature of from 0° C. to 150° C. and for a time effective to convert the olefin to epoxide, wherein the amount of titanium silicalite zeolite is from 0.01 to 10 grams per mole of olefin and the molar ratio of olefin:hydrogen peroxide source is from 1:10 to 10:1.

Claim 15

A process for producing an epoxide comprising contacting an olefin with a hydrogen peroxide source in the presence of an organic solvent and titanium silicalite zeolite having a Si:Ti molar ratio in the lattice framework of said zeolite of from 9.5:1 to 18:1 at a temperature of from 0° C. to 150° C. and for a time effective to convert the olefin to epoxide, wherein the amount of titanium silicalite zeolite is from 0.01 to 10 grams per mole of olefin and the molar ratio of olefin:hydrogen peroxide source is from 1:10 to 10:1.

Claim 16

The process of claim 13 wherein said organic solvent is selected from the group consisting of ketones, alcohols, and mixtures thereof.

Claim 17

The process of claim 13 wherein said organic solvent is an aryl-substituted secondary alcohol and the hydrogen peroxide source is produced by oxidation of the secondary alcohol with molecular oxygen.

Claim 18

The process of claim 13 wherein said organic solvent is selected from the group consisting of methanol, β-methylbenzyl, alcohol, isopropyl alcohol, cyclohexanol, acetophenone, acetone, and mixtures thereof.

Claim 19

The process of claim 13 wherein said zeolite has been treated with an acid-neutralizing agent selected from alkaline substances and silylating agents.

Claim 20

The process of claim 13 wherein said zeolite has an MFI or MEL topology.

Claim 21

The process of claim 13 wherein the olefin is selected from the group consisting of ethylene, propylene, 1-butene, 2-butene, 1-pentene, 2-pentene, allyl alcohol, allyl chloride, styrene, cyclohexene, alkyl phenyl ether, norbornene, isoprene, butadiene, isobutylene, 1-octene, vinyl cyclohexane and methallyl alcohol.

Claim 22

The process of claim 13 wherein the zeolite is prepared using a solution of titanium tetrabutoxide dissolved in an anhydrous alcoholic medium.

Claim 23

The process of claim 13 wherein the zeolite is prepared using a quaternary ammonium salt selected from tetrapropyl ammonium hydroxide, methyltributyl ammonium hydroxide, trimethyl ethanol ammonium hydroxide, tetramethyl ammonium hydroxide, tetrabutyl ammonium hydroxide, and mixtures thereof.

Claim 24

The process of claim 13 wherein said process is conducted at a pressure of between 1 and 100 atmospheres.

Claim 25

A process for producing propylene oxide comprising contacting propylene with hydrogen peroxide in the presence of a solvent selected from the group consisting of alcohols, ketones, and mixtures thereof and a titanium silicalite zeolite having a Si:Ti molar ratio in the lattice framework of said zeolite of from 9.5:1 to 18:1 and an MEL or MFI topology at a temperature of from 25° to 120° and for a time effective to convert the propylene to propylene oxide, wherein the amount of titanium silicalite zeolite is from 0.01 to 10 grams per mole of olefin and the molar ratio of olefin:hydrogen perioxide is from 1.05:1 to 1.57:1.

Claim 26

A process for producing propylene oxide comprising contacting propylene with hydrogen peroxide in the presence of a solvent selected from the group consisting of alcohols, ketones, and mixtures thereof and a titanium silicalite zeolite having a Si:Ti molar ratio in the lattice framework of said zeolite of from 9.5:1 to 18:1 and an MEL or MFI topology at a temperature of from 25° to 120° and for a time effective to convert the propylene to propylene oxide, wherein the amount of titanium silicalite zeolite is from 0.01 to 10 grams per mole of olefin and the molar ratio of olefin:hydrogen perioxide is from 1.05:1 to 1.57:1.

Claim 27

The process of claim 13 wherein said organic solvent is selected from the group consisting of acetone, isopropyl alcohol, and mixtures thereof.