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Curable organopolysiloxane compositions

Assignee: Shin-Etsu Chemical Co Ltd
•
Filing: 1992-04-09
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Granted: 1993-09-28
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Expires: 2012-04-09
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Abstract

Abstract A curable organopolysiloxane composition comprising (A) an organopolysiloxane having at least two alkenyl groups and a viscosity of 100 to 200,000 cs, (B) a specific organopolysiloxane having an alkoxysilyl group, (C) an organohydrogen polysiloxane having at least two hydrogen atoms attached to silicon atoms, and (D) an addition reaction catalyst is improved in adhesion. It cures to substrates of metals, glass, rubber and plastics to form a firm bond even in low temperature or brief high temperature curing conditions.

Inventors

  • 👤 Toshiaki Takahashi
  • 👤 Hironao Fujiki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 12:38
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C09; C09J; C09J183/00; C09J183/04; C08G; C08G77/00; C08G77/04; C08G77/12; C08G77/20; C08G77/70

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 214 words
A curable organopolysiloxane composition comprising, in admixture, (A) an organopolysiloxane having at least two alkenyl groups in a molecule and a viscosity of 100 to 200,000 centistokes at 25° C., (B) an organopolysiloxane having the general compositional formula (I): (A).sub.a (D).sub.b (E).sub.c (G).sub.d (J).sub.e (L).sub.f (M).sub.g (I) wherein A=[(R 1 O) h R 2 3-h Si(CH 2 ) n ] i R 2 3-i SiO 1/2 , D=[CH 2 ═CH(CH 2 ) n-2 ] i R 2 3-i SiO 1/2 , E=(R 1 O) 3 SiO 1/2 , G 32 R 1 3 SiO 1/2 , J=HO 178 , L=R 1 O 178 , M=SiO 4/2 , R 1 is a monovalent saturated hydrocarbon group having 1 to 10 carbon atoms, R 2 is a monovalent saturated hydrocarbon group having 1 to 10 carbon atoms or aryl group, letters a, b, c, d, e, f, and g are numbers meeting a>0, b>0, c≧0, d≧0, e≧0, f≧0, g>0, a+b+c+d+e+f+g=1, and 0.4≦(a+b+c+d+e+f)/g≦4, h and i each are an integer of from 1 to 3, and n is an integer of at least 2, (C) an organohydrogenpolysiloxane having at least two hydrogen atoms attached to silicon atoms in a molecule, and (D) an addition reaction catalyst selected from the group consisting of platinum and a platinum compound.
Claim 2
Dependent Claim 214 words
A curable organopolysiloxane composition comprising, in admixture, (A) an organopolysiloxane having at least two alkenyl groups in a molecule and a viscosity of 100 to 200,000 centistokes at 25° C., (B) an organopolysiloxane having the general compositional formula (I): (A).sub.a (D).sub.b (E).sub.c (G).sub.d (J).sub.e (L).sub.f (M).sub.g (I) wherein A=[(R 1 O) h R 2 3-h Si(CH 2 ) n ] i R 2 3-i SiO 1/2 , D=[CH 2 ═CH(CH 2 ) n-2 ] i R 2 3-i SiO 1/2 , E=(R 1 O) 3 SiO 1/2 , G 32 R 1 3 SiO 1/2 , J=HO 178 , L=R 1 O 178 , M=SiO 4/2 , R 1 is a monovalent saturated hydrocarbon group having 1 to 10 carbon atoms, R 2 is a monovalent saturated hydrocarbon group having 1 to 10 carbon atoms or aryl group, letters a, b, c, d, e, f, and g are numbers meeting a>0, b>0, c≧0, d≧0, e≧0, f≧0, g>0, a+b+c+d+e+f+g=1, and 0.4≦(a+b+c+d+e+f)/g≦4, h and i each are an integer of from 1 to 3, and n is an integer of at least 2, (C) an organohydrogenpolysiloxane having at least two hydrogen atoms attached to silicon atoms in a molecule, and (D) an addition reaction catalyst selected from the group consisting of platinum and a platinum compound.
Claim 3
Dependent Claim 20 words
The composition of claim 1 whrein component (B) contains 0.005 to 0.02 mol of --CH═CH 2 group per 100 grams.
Claim 4
Dependent Claim 27 words
The composition of claim 1 wherein about 2 to about 50 parts by weight of component (B) is blended per 100 parts by weight of component (A).
Claim 5
Dependent Claim 35 words
The composition of claim 1 wherein component (C) is added in an amount to provide 0.8 to 20 hydrogen atoms attached to silicon atoms per one of the alkenyl groups in components (A) and (B).
Claim 6
Dependent Claim 11 words
The composition of claim 1 which further comprises (E) a filler.
Claim 7
Dependent Claim 21 words
A cured product obtained by curing a curable organopolysiloxane composition as set forth in any one of claims 1 to 5.
Claim 8
Dependent Claim 34 words
The composition of claim 1 wherein component (A) is selected from the group consisting of ##STR7## and wherein j=1, 2 or 3; k.m.p and r=positive integers and 1, n,q and s=0 or positive integers.
Claim 9
Dependent Claim 239 words
the composition of claim 1 wherein component (B) is selected from the group consisting of 1 ([(CH 3 O) 3 SiCH 2 CH 2 ](CH 3 ) 2 SiO 1/2 ) 2 [(CH 2 ═CH) (CH 3 ) 2 SiO 1/2 ] 2 (SiO 4/2 ) 4 , 2 ([(CH 3 O) 3 SiCH 2 CH 2 ](CH 3 ) 2 SiO 1/2 ) 3 [(CH 2 ═CH) (CH 3 ) 2 SiO 1/2 ] 2 [(CH 3 ) 3 SiO 1/2 ] 3 (SiO 4/2 ) 8 , 3 ([(CH 3 O) 3 SiCH 2 CH 2 ](CH 3 ) 2 SiO 1/2 ) 16 [(CH 2 ═CH) (CH 3 ) 2 SiO 1/2 ] 4 [(CH 3 ) 3 SiO 4/2 ] 12 [(SiO 4/2 ) 2 , 4 ([(CH 3 O) 3 SiCH 2 CH 2 ](CH 3 ) 2 SiO 1/2 ) 12 [(CH 2 ═CH) (CH 3 ) 2 SiO 178 ] 4 [(CH 3 O) 3 SiO 178 ] 4 [(CH 3 ) 3 SiO 178 ] 12 (SiO 4/2 ) 2 , and e,crc/5/ ([CH 3 O) 3 SiCH 2 CH 2 ](CH 3 ) 2 SiO 178 ) 10 [(CH 2 ═CH) (CH 3 ) 2 SiO 178 ] 4 [(CH 3 O) 3 SiO 178 ] 4 ](CH 3 ) 3 SiO 178 ] 4 (HO 178 ) 4 (CH 3 O 178 ) 4 (SiO 4/2 ) 27 .
Claim 10
Dependent Claim 35 words
The composition of claim 1 wherein component (c) is selected from the group consisting of ##STR8## wherein t, u, v and w=0 or positive integers; X=an integer 2 or higher; R=H, methyl, propyl or trimethylsiloxy.
Claim 11
Dependent Claim 44 words
The composition of claim 1 wherein said (D) platinum compound is selected from the group consisting of platinum black, solid platinum on alumina, solic platinum on silica, chloroplatinic acid, alcohol-modified chloroplatinic acid, complexes of chloraplatinic acid and olefins and complexes of platinum and vinylsiloxanes.

References Cited (Backward Citations)

JPS5826376A Cited
JPS595219A Cited
US5100976A Cited
JPH05313508A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-09-27 1997-03-29 1997-09-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-09-27 2001-03-29 2001-09-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-09-27 2005-03-29 2005-09-28 $7700.00 Window Closed / Lapsed

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