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US5248368A Expired / Lapsed US ⏱️ 0.0 years remaining

Bonding aluminum cladding to random glass mat reinforced polypropylene sheet

Assignee: General Electric Co
•
Filing: 1991-12-30
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Granted: 1993-09-28
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Expires: 2011-12-30
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Abstract

Abstract The present invention relates to a method for making a composite article by applying an adhesive composition to one side of each of two foils of metal. The adhesive composition contains an ethylene/acrylic acid copolymer and a thermoplastic styrene/diene block copolymer. A sheet of fiber-reinforced polypropylene has both of its sides coated with a second thermoplastic styrene block/diene block copolymer which includes an acid or acid anhydride component. Finally, the adhesive coated metal foils are mated with the treated polypropylene sheet under elevated temperature and pressure for forming the composite article.

Inventors

  • 👤 Michael G. Minnick
  • 👤 Atul Govil

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 12:46
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/12; C08J5/124; B; B32; B32B; B32B15/00; B32B15/04; B32B15/08; C09; C09J; C09J123/00; C09J123/02; C09J123/04; C09J123/08; C09J5/00; C09J5/06; C08J2323/00; C08J2323/02; C08J2323/04; C08J2323/08; C08L; C08L2666/00; C08L2666/02; C08L2666/04; C08L2666/24

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 100 words
A method for making a composite article which comprises the steps of: (a) applying an adhesive composition to one side of each of two foils of metal, said adhesive composition comprising an ethylene/acrylic acid copolymer and either a first thermoplastic styrene/diene block copolymer; (b) treating both sides of a sheet of fiber-reinforced polypropylene with a coating of a second thermoplastic styrene/diene block copolymer which includes an acid or acid anhydride component; and (c) mating the adhesive coated side of said metal foils with said treated polypropylene sheet from step (b) under elevated temperature and pressure for forming a composite article.
Claim 2
Independent Claim 100 words
A method for making a composite article which comprises the steps of: (a) applying an adhesive composition to one side of each of two foils of metal, said adhesive composition comprising an ethylene/acrylic acid copolymer and either a first thermoplastic styrene/diene block copolymer; (b) treating both sides of a sheet of fiber-reinforced polypropylene with a coating of a second thermoplastic styrene/diene block copolymer which includes an acid or acid anhydride component; and (c) mating the adhesive coated side of said metal foils with said treated polypropylene sheet from step (b) under elevated temperature and pressure for forming a composite article.
Claim 3
Dependent Claim 32 words
The method of claim 1 wherein said ethylene/acrylic acid copolymer contains between about 91 and 93.5 wt-% ethylene content and has a melt flow index ranging from about 1.5 to 5.0 dg/min.
Claim 4
Dependent Claim 21 words
The method of claim 1 wherein said adhesive composition contains between about 10 and 50 wt-% of said ethylene/acrylic acid copolymer.
Claim 5
Dependent Claim 20 words
The method of claim 1 wherein said first thermoplastic styrene/diene block copolymer comprises a styrene-ethylene-butadiene-styrene copolymer which contains ethylenic unsaturation.
Claim 6
Dependent Claim 15 words
The method of claim 1 wherein said adhesive composition is applied as a sheet thereof.
Claim 7
Dependent Claim 14 words
The method of claim 1 wherein said fiber of said fiber-reinforced polypropylene comprises glass.
Claim 8
Dependent Claim 22 words
The method of claim 6 wherein said glass content of said fiber-reinforced polypropylene ranges from between about 30% and 40% by weight.
Claim 9
Dependent Claim 20 words
The method of claim 1 wherein said fiber-reinforced polypropylene sheet ranges in thickness from between about 0.135 and 0.160 inches.
Claim 10
Dependent Claim 19 words
The method of claim 1 wherein said metal foil ranges in thickness from between about 0.12 and 1 mm.
Claim 11
Dependent Claim 13 words
The method of claim 1 wherein said foil is aluminum or a steel.
Claim 12
Dependent Claim 15 words
The method of claim 10 wherein said foil is an aluminum or aluminum alloy foil.
Claim 13
Dependent Claim 21 words
The method of claim 1 wherein said second thermoplastic styrene/diene block copolymer comprises a styrene-ethylene-butadiene-styrene block copolymer modified with maleic anhydride.
Claim 14
Dependent Claim 28 words
The method of claim 1 wherein said elevated temperature ranges from between about 130° and 155° C. and said pressure ranges from between about 200 and 400 psi.

References Cited (Backward Citations)

US3410928A Cited
US3431157A Cited
US4678836A Cited
US4994130A Cited
US5092952A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-09-27 1997-03-29 1997-09-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-09-27 2001-03-29 2001-09-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-09-27 2005-03-29 2005-09-28 $7700.00 Window Closed / Lapsed

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