← Back to Patent Explorer
US5246995A Expired / Lapsed US ⏱️ 0.0 years remaining

Film-forming organopolysiloxane composition

Assignee: DuPont Toray Specialty Materials KK
•
Filing: 1991-07-11
•
Granted: 1993-09-21
•
Expires: 2011-07-11
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A film-forming organopolysiloxane composition is disclosed which imparts an excellent releaseability and lubricity to the surface of various types of rubber materials. The composition comprises a solvent dispersion of (a) 50 to 90 weight percent of a block organopolysiloxane copolymer; (b) 2 to 50 weight percent of a compound selected from the group consisting of an organosilane or a partial hydrolyzate thereof; (c) 4 to 40 weight percent of a mixture an epoxy group-containing organoalkoxysilane and an alkenyl group-containing organoacetoxysilane in a weight ratio of 1:9 to 9:1 or a condensation-reaction product thereof; (d) 0.1 to 10 weight percent of an hydroxy or alkoxy terminated diorganopolysiloxane; and (f) 0.1 to 10 weight percent of a condensation-reaction catalyst.

Inventors

  • 👤 Ichiro Murakami
  • 👤 Hideyuki Motomura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 12:04
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08J; C08J7/00; C08J7/04; C08J7/0427; C08J7/043; C08G; C08G77/00; C08G77/04; C08G77/14; C08G77/16; C08G77/18; C08G77/42; C08G77/44; C08J2321/00; C08J2483/00; Y; Y10; Y10S; Y10S528/00; Y10S528/901

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 290 words
A film-forming organopolysiloxane composition consisting essentially of an organic solvent dispersion of (a) 50 to 90 weight percent of a block organopolysiloxane copolymer composed of (i) 10 to 80 weight percent of an organopolysiloxane resin composed of R.sub.x SiO.sub.(4-x)/2 units, wherein R is a monovalent hydrocarbon group and x has an average value of 1.0 to 1.3, (ii) 2 to 30 weight percent of end-blocking siloxane unit composed of R.sup.1.sub.y R.sup.2 SiO.sub.(3-y)/2 units, wherein R 1 is a silicon-bonded hydrolyzable group, R 2 is a monovalent hydrocarbon group and y has an average value of 1.8 to 2.0, and (iii) 10 to 80 weight percent of a straight-chain organopolysiloxane composed of R.sup.3.sub.2 SiO units, wherein R 3 is a monovalent hydrocarbon group, at least 80 mole percent of said R 3 group being methyl; (b) 2 to 50 weight percent of a compound selected from the group consisting of an organosilane having the general formula ##STR2## wherein R 4 , R 5 , R 6 and R 7 are monovalent hydrocarbon groups, a is zero, 1, 2, 3 or 4, b is zero, 1, 2, 3 or 4, a+b is 3 or 4, c is zero or 1 and a+b+c is 4, and a partial hydrolyzate of said organosilane; (c) 4 to 40 weight percent of a component selected from the group consisting of a mixture of an epoxy group-containing organoalkoxysilane and an alkenyl group-containing organoacetoxysilane in a weight ratio of 1:9 to 9:1 and a condensation-reaction product of said mixture; (d) 0.1 to 10 weight percent of a diorganopolysiloxane which is terminated with a group selected from the group consisting of an hydroxyl group and an alkoxy group; and (f) 0.1 to 10 weight percent of a condensation-reaction catalyst.
Claim 2
Dependent Claim 290 words
A film-forming organopolysiloxane composition consisting essentially of an organic solvent dispersion of (a) 50 to 90 weight percent of a block organopolysiloxane copolymer composed of (i) 10 to 80 weight percent of an organopolysiloxane resin composed of R.sub.x SiO.sub.(4-x)/2 units, wherein R is a monovalent hydrocarbon group and x has an average value of 1.0 to 1.3, (ii) 2 to 30 weight percent of end-blocking siloxane unit composed of R.sup.1.sub.y R.sup.2 SiO.sub.(3-y)/2 units, wherein R 1 is a silicon-bonded hydrolyzable group, R 2 is a monovalent hydrocarbon group and y has an average value of 1.8 to 2.0, and (iii) 10 to 80 weight percent of a straight-chain organopolysiloxane composed of R.sup.3.sub.2 SiO units, wherein R 3 is a monovalent hydrocarbon group, at least 80 mole percent of said R 3 group being methyl; (b) 2 to 50 weight percent of a compound selected from the group consisting of an organosilane having the general formula ##STR2## wherein R 4 , R 5 , R 6 and R 7 are monovalent hydrocarbon groups, a is zero, 1, 2, 3 or 4, b is zero, 1, 2, 3 or 4, a+b is 3 or 4, c is zero or 1 and a+b+c is 4, and a partial hydrolyzate of said organosilane; (c) 4 to 40 weight percent of a component selected from the group consisting of a mixture of an epoxy group-containing organoalkoxysilane and an alkenyl group-containing organoacetoxysilane in a weight ratio of 1:9 to 9:1 and a condensation-reaction product of said mixture; (d) 0.1 to 10 weight percent of a diorganopolysiloxane which is terminated with a group selected from the group consisting of an hydroxyl group and an alkoxy group; and (f) 0.1 to 10 weight percent of a condensation-reaction catalyst.
Claim 3
Dependent Claim 50 words
The composition according to claim 1, further comprising a filler selected from the group consisting of an organic micropowder and an inorganic micropowder, wherein said filler is present at a level of up to 10 weight percent based on the 50 to 90 weight percent of said block copolymer (a).
Claim 4
Dependent Claim 19 words
The composition according to claim 1, wherein R is selected from the group consisting of methyl and phenyl radicals.
Claim 5
Dependent Claim 27 words
The composition according to claim 3, wherein R 2 is a methyl radical and R 1 is selected from the group consisting of methoxy and ethoxy groups.
Claim 6
Dependent Claim 12 words
The composition according to claim 4, wherein said diorganopolysiloxane (d) is polydimethylsiloxane.
Claim 7
Dependent Claim 38 words
The composition according to claim 5, wherein said compound (b) is selected from the group consisting of methyltris(methyl ethyl ketoxime)silane, vinyltris(methyl ethyl ketoxime)silane, methylmethoxydi(methyl ethyl ketoxime)silane, diethoxydi(methyl ethyl ketoxime)silane, methyltrimethoxysilane, methyltriethoxysilane, vinyltrimethoxysilane, mixtures thereof and partial hydrolysis-condensates thereof.
Claim 8
Dependent Claim 41 words
The composition according to claim 6, wherein said epoxy group-containing organoalkoxysilane of said component (c) is selected from the group consisting of gamma-glycidoxypropyltrimethoxysilane, gamma-glycidoxypropyltriethoxysilane and beta-(3,4-epoxycyclohexyl)ethyltrimethoxysilane and said alkenyl group-containing organoacetoxysilane is selected from the group consisting of vinyltriacetoxysilane and allyltriacetoxysilane.
Claim 9
Dependent Claim 83 words
The composition according to claim 7, wherein said film-forming organopolysiloxane composition comprises an organic solvent dispersion of 50 to 90 weight percent of said block organopolysiloxane copolymer (a), 5 to 40 weight percent of said compound (b), 5 to 15 weight percent of said component (c), 0.1 to 5 weight percent of said diorganopolysiloxane (d), 0.3 to 5 weight percent of said condensation-reaction catalyst (f) and the weight ratio of said epoxy group-containing organoalkoxysilane to said alkenyl group-containing organoacetoxysilane is 3:7 to 7:3.
Claim 10
Dependent Claim 50 words
The composition according to claim 6, further comprising a filler selected from the group consisting of an organic micropowder and an inorganic micropowder, wherein said filler is present at a level of up to 10 weight percent based on the 50 to 90 weight percent of said block copolymer (a).
Claim 11
Dependent Claim 50 words
The composition according to claim 7, further comprising a filler selected from the group consisting of an organic micropowder and an inorganic micropowder, wherein said filler is present at a level of up to 10 weight percent based on the 50 to 90 weight percent of said block copolymer (a).

References Cited (Backward Citations)

US4122127A Cited
US4115356A Cited
US4431472A Cited
US4595610A Cited
US4673750A Cited
US5013781A Cited
JPH01198840A Cited
US4996112A Cited
US4973623A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-09-20 1997-03-22 1997-09-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-09-20 2001-03-22 2001-09-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-09-20 2005-03-22 2005-09-21 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag