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US5246984A Expired / Lapsed US ⏱️ 0.0 years remaining

Water dispersible polyamine-epoxy adduct and epoxy coating composition

Assignee: Air Products and Chemicals Inc
•
Filing: 1992-06-03
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Granted: 1993-09-21
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Expires: 2012-06-03
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Abstract

Abstract This invention relates to a water compatible polyamine-epoxy adduct formed by the reaction of a polyamine with a mixture of a monoepoxide and polyepoxides, the monoepoxide being added in an amount to react with about 10 to 50% of the primary amino groups in said polyamine and the polyepoxides being added in an amount to react with from about 35 to 65% of the remaining primary amino groups. This invention also contemplates a water dispersible blend resin as an amine salt and comprises a water compatible polyamine-epoxy adduct and a resin compatible polyamine-epoxy adduct wherein the water compatible polyamine-epoxy adduct is as described above and the resin compatible polyamine-epoxy adduct is formed by reacting a polyamine with an aromatic monoepoxide, said aromatic monoepoxide reacted in an amount to provide from about 0.4 to 1 equivalents epoxide per primary amino group. The invention also pertains to a two component water epoxy coating composition comprising an aqueous dispersion of a blend of a water compatible polyamine-epoxy adduct, a resin compatible-polyamine-epoxy adduct and a polyepoxide resin emulsified therewith wherein the amount of polyepoxide resin in the coating composition is such that there is from about 0.5 to 1.5 equivalents epoxide per active hydrogen equivalent.

Inventors

  • 👤 Stuart P. Darwen
  • 👤 Daniel A. Cornforth

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 20:09
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/182; C08G59/184; C08G59/20; C08G59/22; C08G59/223; C08G59/40; C08G59/50; C09; C09D; C09D163/00

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 63 words
A water dispersible polyamine-epoxy adduct formed by reacting a polyamine with a mixture of a monoepoxide and one or more polyepoxides wherein the monoepoxide is added in a proportion to react with from about 10 to 50% of the primary amine groups and the polyepoxides are added in amount to react with from about 5% to 65% of the remaining primary amine groups.
Claim 2
Dependent Claim 63 words
A water dispersible polyamine-epoxy adduct formed by reacting a polyamine with a mixture of a monoepoxide and one or more polyepoxides wherein the monoepoxide is added in a proportion to react with from about 10 to 50% of the primary amine groups and the polyepoxides are added in amount to react with from about 5% to 65% of the remaining primary amine groups.
Claim 3
Dependent Claim 25 words
The adduct of claim 1 wherein the ratio of monoepoxide to polyepoxide is from 0.5 to 2 epoxide equivalents of monoepoxide per equivalent of polyepoxide.
Claim 4
Dependent Claim 25 words
The adduct of claim 2 wherein the polyepoxide is comprised of a mixture of an aliphatic diepoxide or polyepoxide and an aromatic diepoxide or polyepoxide.
Claim 5
Dependent Claim 35 words
The adduct of claim 3 wherein the polyamine is a polyalkylene polyamine represented by the formula: H.sub.2 NR--[NHR].sub.n --NH.sub.2 where n is an integer from 0 to about 6 and R is an alkylene group.
Claim 6
Dependent Claim 36 words
The adduct of claim 2 wherein the monoepoxide is represented by a structural formula selected from the group consisting of: ##STR2## wherein R is an aliphatic group having from 4 to 18 carbon atoms or aromatic.

References Cited (Backward Citations)

US3449281A Cited
US4246148A Cited
US4501832A Cited
US5087647A Cited
US4992516A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-09-20 1997-03-22 1997-09-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-09-20 2001-03-22 2001-09-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-09-20 2005-03-22 2005-09-21 $7700.00 Window Closed / Lapsed

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