Patent US5242602A successfully refreshed from Google Patents.
US5242602A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Spectrophotometric monitoring of multiple water treatment performance indicators using chemometrics
Assignee: WR Grace and Co Conn
•
Filing: 1992-03-04
•
Granted: 1993-09-07
•
Expires: 2012-03-04
Abstract
Abstract The present invention is directed to a novel method for analyzing aqueous systems to simultaneously quantify the concentrations of multiple active or inactive treating components which may be contained therein. The method comprises determining the absorbance or emission spectrum of the components in the aqueous system over the wavelength range of from 200 to 2500 nm, and then applying chemometrics algorithms to extract and analyze features in the spectrum that are specific to the qualitative and quantitative concentrations from the specific components to simultaneously determine the concentrations of the components.
Inventors
- 👤 John Richardson
- 👤 Larry M. Kye
- 👤 Mark D. Brickhouse
- 👤 Gary G. Engstrom
- 👤 Kenneth J. Schlager
- 👤 Scott J. Kahle
- 👤 John A. Kelly
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 17:02
CPC Classifications
G; G01; G01N; G01N21/00; G01N21/17; G01N21/25; G01N21/27; G01N33/00; G01N33/18; G01N33/1813; G01N21/31; G01N21/84; G01N21/85; G01N21/8507; G01N33/182; G01N2201/00; G01N2201/12; G01N2201/129
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
59 words
A method for simultaneously measuring the concentration of multiple performance indicators comprising components used in treating an aqueous system comprising directly determining an absorbance or emission spectrum of the aqueous system in a wavelength range of 200 to 2500 nm, and applying chemometrics algorithms to the absorbance or emission spectrum to simultaneously determine the concentrations of the performance indicators.
Claim 2
Independent Claim
59 words
A method for simultaneously measuring the concentration of multiple performance indicators comprising components used in treating an aqueous system comprising directly determining an absorbance or emission spectrum of the aqueous system in a wavelength range of 200 to 2500 nm, and applying chemometrics algorithms to the absorbance or emission spectrum to simultaneously determine the concentrations of the performance indicators.
Claim 3
Dependent Claim
55 words
The method according to claim 1 wherein the concentrations of the performance indicators determined by the chemometrics algorithms are compared to predefined ranges for the respective performance indicators, and if any of the concentrations of the performance indicators are outside the predefined ranges, changing the dosage of those performance indicators which are outside this range.
Claim 4
Dependent Claim
32 words
The method according to claim 1 wherein the aqueous system is a cooling water system, a boiler water system, a desalinization unit, a wastewater treatment facility, or pulp or paper processing equipment.
Claim 5
Dependent Claim
28 words
The method according to claim 1 wherein the spectrum is analyzed with a UV-vis-NIR diode array spectrophotometer in a wavelength range of from 200 nm to 2500 nm.
Claim 6
Dependent Claim
23 words
The method according to claim 1 wherein the chemometrics algorithm is based on a rotated principle component analysis of absorbance or emission spectrum.
Claim 7
Dependent Claim
35 words
The method according to claim 1 wherein the performance indicators are selected from the group consisting of scale inhibitors, corrosion inhibitors, lubricants, metal working fluids, pH regulators, dispersants, defoaming agents, sequestrants, biocides, detackifiers, precipitating agents.
Claim 8
Independent Claim
82 words
A method for simultaneously measuring the concentration of multiple performance indicators comprising components used in treating an aqueous system comprising directly determining an absorbance or emission spectrum of the aqueous system which contains the performance indicators in a wavelength range of 200 to 2500 nm, and applying chemometrics algorithms to the absorbance or emission spectrum to simultaneously determine the concentrations of the respective performance indicators and wherein the chemometrics algorithm is based on principle component analysis of the absorbance or emission spectrum.
Claim 9
Independent Claim
82 words
A method for simultaneously measuring the concentration of multiple performance indicators comprising components used in treating an aqueous system comprising directly determining an absorbance or emission spectrum of the aqueous system which contains the performance indicators in a wavelength range of 200 to 2500 nm, and applying chemometrics algorithms to the absorbance or emission spectrum to simultaneously determine the concentrations of the respective performance indicators and wherein the chemometrics algorithm is based on principle component analysis of the absorbance or emission spectrum.
Claim 10
Dependent Claim
23 words
The method according to claim 7 wherein the principle component analysis is based on a first derivative of the absorbance or emission spectrum.
Claim 11
Dependent Claim
23 words
The method according to claim 7 wherein the principle component analysis is based on a second derivative of the absorbance or emission spectrum.
Claim 12
Independent Claim
72 words
A method for simultaneously measuring the concentrations of multiple performance indicators comprising one or more treating components and at least one inert tracer in aqueous systems comprising directly determining an absorbance or emission spectrum of the aqueous system in a wavelength range of 200 to 2500 nm, and applying chemometrics algorithms to the absorbance or emission spectrum to determine the concentrations of the performance indicators and the at least one inert tracer.
Claim 13
Independent Claim
72 words
A method for simultaneously measuring the concentrations of multiple performance indicators comprising one or more treating components and at least one inert tracer in aqueous systems comprising directly determining an absorbance or emission spectrum of the aqueous system in a wavelength range of 200 to 2500 nm, and applying chemometrics algorithms to the absorbance or emission spectrum to determine the concentrations of the performance indicators and the at least one inert tracer.
Claim 14
Dependent Claim
55 words
The method according to claim 10 wherein the concentrations of the performance indicators determined by the chemometrics algorithms are compared to predefined ranges for the respective performance indicators, and if any of the concentrations of the performance indicators are outside the predefined ranges, changing the dosage of those performance indicators which are outside this range.
Claim 15
Dependent Claim
32 words
The method according to claim 10 wherein the aqueous system is a cooling water system, a boiler water system, a desalinization unit, a wastewater treatment facility, or pulp or paper processing equipment.
Claim 16
Dependent Claim
28 words
The method according to claim 10 wherein the spectrum is analyzed with a UV-vis-NIR diode array spectrophotometer in a wavelength range of from 200 nm to 800 nm.
Claim 17
Dependent Claim
23 words
The method according to claim 10 wherein the chemometrics algorithm is based on a rotated principle component analysis of absorbance or emission spectrum.
Claim 18
Dependent Claim
35 words
The method according to claim 10 wherein the performance indicators are selected from the group consisting of scale inhibitors, corrosion inhibitors, lubricants, metal working fluids, pH regulators, dispersants, defoaming agents, sequestrants, biocides, detackifiers, precipitating agents.
Claim 19
Independent Claim
91 words
A method for simultaneously measuring the concentrations of multiple performance indicators comprising one or more treating components and at least one inert tracer in an aqueous system comprising directly determining an absorbance or emission spectrum of the aqueous system in a wavelength range of from 200 to 2500 nm, and applying chemometrics algorithms to the absorbance or emission spectrum to determine the concentrations of the performance indicators and the at least one inert tracer and wherein the chemometrics algorithms is based on principle component analysis of the absorbance or emission spectrum.
Claim 20
Independent Claim
91 words
A method for simultaneously measuring the concentrations of multiple performance indicators comprising one or more treating components and at least one inert tracer in an aqueous system comprising directly determining an absorbance or emission spectrum of the aqueous system in a wavelength range of from 200 to 2500 nm, and applying chemometrics algorithms to the absorbance or emission spectrum to determine the concentrations of the performance indicators and the at least one inert tracer and wherein the chemometrics algorithms is based on principle component analysis of the absorbance or emission spectrum.
Claim 21
Dependent Claim
23 words
The method according to claim 16 wherein the principle component analysis is based on a first derivative of the absorbance or emission spectrum.
Claim 22
Dependent Claim
23 words
The method according to claim 16 wherein the principle component analysis is based on a second derivative of the absorbance or emission spectrum.
References Cited (Backward Citations)
JPS5929073A
Cited
US4829533A
Cited
US4783314A
Cited
EP0320086A2
Cited
US4966711A
Cited
US5121443A
Cited
US5006311A
Cited
US5132096A
Cited
US5121337A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-09-06 | 1997-03-08 | 1997-09-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-09-06 | 2001-03-08 | 2001-09-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-09-06 | 2005-03-08 | 2005-09-07 | $7700.00 | Window Closed / Lapsed |