Patent US5240480A successfully refreshed from Google Patents.
← Back to Patent Explorer
US5240480A Expired / Lapsed US ⏱️ 0.0 years remaining

Composite mixed conductor membranes for producing oxygen

Assignee: Air Products and Chemicals Inc
•
Filing: 1992-09-15
•
Granted: 1993-08-31
•
Expires: 2012-09-15
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract The present invention relates to novel multi-layer composite solid state membranes which are capable of separating oxygen from oxygen-containing gaseous mixtures at elevated temperatures. The membranes comprise a multicomponent metallic oxide porous layer having an average pore radius of less than about 10 micrometers and a multicomponent metallic oxide dense layer having no connected through porosity wherein the porous and dense layers are contiguous and such layers conduct electrons and oxygen ions at operating temperatures.

Inventors

  • 👤 Robert M. Thorogood
  • 👤 Rajagopalan Srinivasan
  • 👤 Terrence F. Yee
  • 👤 Miles P. Drake

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 17:43
CPC Classifications
C; C01; C01B; C01B13/00; C01B13/02; C01B13/0229; C01B13/0248; C01B13/0251; C01B13/0255; B; B01; B01D; B01D71/00; B01D71/02; B01D71/024; B01D71/0271; B01D2325/00; B01D2325/26; C01B2210/00; C01B2210/0043; C01B2210/0046; Y; Y10; Y10S; Y10S505/00; Y10S505/70; Y10S505/701; Y10S505/775; Y10S505/776; Y10S505/777; Y10S505/778; Y10S505/785

Claims Analysis

Total Claims: 41
Claim 1
Independent Claim 70 words
A membrane capable of separating oxygen from an oxygen-containing gaseous mixture, which membrane comprises a porous layer having an average pore radius of less than about 10 micrometers and a dense layer having no connected through porosity wherein the porous layer and the dense layer are contiguous and each layer comprises a multicomponent metallic oxide capable of conducting electrons and oxygen ions at a temperature greater than about 500° C.
Claim 2
Dependent Claim 70 words
A membrane capable of separating oxygen from an oxygen-containing gaseous mixture, which membrane comprises a porous layer having an average pore radius of less than about 10 micrometers and a dense layer having no connected through porosity wherein the porous layer and the dense layer are contiguous and each layer comprises a multicomponent metallic oxide capable of conducting electrons and oxygen ions at a temperature greater than about 500° C.
Claim 3
Dependent Claim 36 words
The membrane according to claim 1 wherein the dense layer has a thickness ranging from 0.01 micrometer to about 500 micrometers and the porous layer has a thickness ranging from 1 micrometer to about 2 millimeters.
Claim 4
Dependent Claim 48 words
The membrane according to claim 2 wherein the multicomponent metallic oxide demonstrates an oxygen ionic conductivity ranging from 0.01 ohm -1 cm -1 to 100 ohm -1 cm -1 and an electronic conductivity ranging from about 1 ohm -1 cm -1 to 100 ohm -1 cm -1 .
Claim 5
Dependent Claim 105 words
The membrane according to claim 3 wherein the dense layer and the porous layer are independently formed from one or a mixture of multicomponent metallic oxides represented by the formula A x A' x' A" x" B y B' y' B" y" O 3-z , where A,A',A" are chosen from the group comprising Groups 1, 2 and 3 and the F block lanthanides; and B,B'B" are chosen from the D block transition metals according to the Periodic Table of the Elements adopted by the IUPAC wherein 0<x≦1, 0<x'≦1, 0<x"≦1, 0<y≦1, 0≦y'≦1, 0≦y"≦1, x+x'+x"=1, y+y'+y"=1 and z is a number which renders the compound charge neutral.
Claim 6
Dependent Claim 31 words
The membrane according to claim 4 wherein A, A' or A" of the enumerated formula is a Group 2 metal selected from the group consisting of calcium, strontium, barium and magnesium.
Claim 7
Dependent Claim 53 words
The membrane according to claim 5 wherein the dense layer is formed from a multicomponent metallic oxide represented by the formula La x A 1-x Co y Fe 1-y O 3-z wherein x is between 0 and 1, y is between 0 and 1 and A is selected from barium, strontium or calcium.
Claim 8
Dependent Claim 72 words
The membrane according to claim 4 wherein the dense layer is formed from a multicomponent metallic oxide is selected from the group consisting of La 0 .2 Ba 0 .8 Co 0 .8 Fe 0 .2 O 3-x , Pr 0 .2 Ba 0 .8 Co 0 .8 Fe 0 .2 O 3-x and La 0 .2 Ba 0 .8 Co 0 .6 Cu 0 .2 Fe 0 .2 O 3-x .
Claim 9
Dependent Claim 79 words
A membrane capable of separating oxygen from an oxygen-containing gaseous mixture, which membrane comprises a dense layer having no connected through porosity, which dense layer is contiguous to a porous layer having an average pore radius which increases as a function of distance away from the dense layer, the porous layer and the dense layer which are independently formed from a multicomponent metallic oxide capable of conducting electrons and oxygen ions at a temperature greater than about 500° C.
Claim 10
Dependent Claim 79 words
A membrane capable of separating oxygen from an oxygen-containing gaseous mixture, which membrane comprises a dense layer having no connected through porosity, which dense layer is contiguous to a porous layer having an average pore radius which increases as a function of distance away from the dense layer, the porous layer and the dense layer which are independently formed from a multicomponent metallic oxide capable of conducting electrons and oxygen ions at a temperature greater than about 500° C.
Claim 11
Dependent Claim 36 words
The membrane according to claim 8 wherein the dense layer has a thickness ranging from 0.01 micrometer to about 500 micrometers and the porous layer has a thickness ranging from 1 micrometer to about 2 millimeters.
Claim 12
Dependent Claim 48 words
The membrane according to claim 8 wherein the multicomponent metallic oxide demonstrates an oxygen ionic conductivity ranging from 0.01 ohm -1 cm -1 to 100 ohm -1 cm -1 and an electronic conductivity ranging from about 1 ohm -1 cm -1 to 100 ohm -1 cm -1 .
Claim 13
Dependent Claim 105 words
The membrane according to claim 10 wherein the dense layer and the porous layer are independently formed from one or a mixture of multicomponent metallic oxides represented by the formula A x A' x' A" x" B y B' y' B" y" O 3-z , where A,A',A" are chosen from the group comprising Groups 1, 2 and 3 and the F block lanthanides; and B,B',B" are chosen from the D block transition metals according to the Periodic Table of the Elements adopted by the IUPAC wherein 0<x≦1, 0≦x'≦1, 0≦x"≦1, 0<y≦1, 0≦y'≦1, 0≦y"≦1, x+x'+x"=1, y+y'+y"=1 and z is a number which renders the compound charge neutral.
Claim 14
Dependent Claim 30 words
The membrane according to claim 11 wherein A, A' or A" of the formula is a Group 2 metal selected from the group consisting of calcium, strontium, barium and magnesium.
Claim 15
Dependent Claim 53 words
The membrane according to claim 11 wherein the dense layer is formed from a multicomponent metallic oxide represented by the formula La x A 1-x Co y Fe 1-y O 3-z wherein x is between 0 and 1, y is between 0 and 1 and A is selected from barium, strontium or calcium.
Claim 16
Dependent Claim 71 words
The membrane according to claim 11 wherein the dense layer is formed from a multicomponent metallic oxide selected from the group consisting of La 0 .2 Ba 0 .8 Co 0 .8 Fe 0 .2 O 3-x , Pr 0 .2 Ba 0 .8 Co 0 .8 Fe 0 .2 O 3-x and La 0 .2 Ba 0 .8 Co 0 .6 Cu 0 .2 Fe 0 .2 O 3-x .
Claim 17
Dependent Claim 99 words
A membrane capable of separating oxygen from an oxygen-containing gaseous mixture, which membrane comprises a dense layer having no connected through porosity and a plurality of porous layers, each respective porous layer having a discrete average pore radius wherein the average pore radius of each respective porous layer is larger than the average pore radius of the preceding porous layer as function of distance away from the dense layer, the porous layer and the dense layer which are independently formed from a multicomponent metallic oxide capable of conducting electrons and oxygen ions at temperatures greater than about 500° C.
Claim 18
Dependent Claim 99 words
A membrane capable of separating oxygen from an oxygen-containing gaseous mixture, which membrane comprises a dense layer having no connected through porosity and a plurality of porous layers, each respective porous layer having a discrete average pore radius wherein the average pore radius of each respective porous layer is larger than the average pore radius of the preceding porous layer as function of distance away from the dense layer, the porous layer and the dense layer which are independently formed from a multicomponent metallic oxide capable of conducting electrons and oxygen ions at temperatures greater than about 500° C.
Claim 19
Dependent Claim 36 words
The membrane according to claim 15 wherein the dense layer has a thickness ranging from 0.01 micrometer to about 500 micrometers and the porous layer has a thickness ranging from 1 micrometer to about 2 millimeters.
Claim 20
Dependent Claim 48 words
The membrane according to claim 16 wherein the multicomponent metallic oxide demonstrates an oxygen ionic conductivity ranging from 0.01 ohm -1 cm -1 to 100 ohm -1 cm -1 and an electronic conductivity ranging from about 1 ohm -1 cm -1 to 100 ohm -1 cm -1 .
Claim 21
Dependent Claim 105 words
The membrane according to claim 17 wherein the dense layer and the porous layer are independently formed from one or a mixture of multicomponent metallic oxides represented by the formula A x A' x' A" x" B y B' y' B" y" O 3-z , where A,A',A" are chosen from the group comprising Groups 1, 2 and 3 and the F block lanthanides; and B,B',B" are chosen from the D block transition metals according to the Periodic Table of the Elements adopted by the IUPAC wherein 0<x≦1, 0≦x'≦1, 0≦x"≦1, 0<y≦1, 0≦y'≦1, 0≦y"≦1, x+x'+x"=1, y+y'+y"=1 and z is a number which renders the compound charge neutral.
Claim 22
Dependent Claim 30 words
The membrane according to claim 18 wherein A, A' or A" of the formula is a Group 2 metal selected from the group consisting of calcium, strontium, barium and magnesium.
Claim 23
Dependent Claim 53 words
The membrane according to claim 18 wherein the dense layer is formed from a multicomponent metallic oxide represented by the formula La x A 1-x Co y Fe 1-y O 3-z wherein x is between 0 and 1, y is between 0 and 1 and A is selected from barium, strontium or calcium.
Claim 24
Dependent Claim 71 words
The membrane according to claim 18 wherein the dense layer is formed from a multicomponent metallic oxide is selected from the group consisting of La 0 .2 Ba 0 .8 Co 0 .8 Fe 0 .2 O 3-x , Pr 0 .2 Ba 0 .8 Co 0 .8 Fe 0 .2 O 3-x and La 0 .2 Ba 0 .8 Co 0 .6 Cu 0 .2 Fe 02 O 3-x .
Claim 25
Dependent Claim 82 words
A membrane capable of separating oxygen from an oxygen-containing gaseous mixture, which membrane comprises a first porous layer formed from a multicomponent metallic oxide having an average pore radius of less than about 10 micrometers which is deposed to a second porous layer which is not a mixed conducting oxide, the first porous layer being contiguous with a dense layer having no connected through porosity comprising a multicomponent metallic oxide capable of conducting oxygen ions at temperatures greater than about 500° C.
Claim 26
Dependent Claim 82 words
A membrane capable of separating oxygen from an oxygen-containing gaseous mixture, which membrane comprises a first porous layer formed from a multicomponent metallic oxide having an average pore radius of less than about 10 micrometers which is deposed to a second porous layer which is not a mixed conducting oxide, the first porous layer being contiguous with a dense layer having no connected through porosity comprising a multicomponent metallic oxide capable of conducting oxygen ions at temperatures greater than about 500° C.
Claim 27
Dependent Claim 48 words
The membrane according to claim 22 wherein the porous layer which is not a mixed conducting oxide is formed from a material selected from the group consisting of alumina, silica, magnesia, titania, a high temperature oxygen compatible metal alloy, a metal stabilized zirconia and compounds and mixtures thereof.
Claim 28
Dependent Claim 21 words
The membrane according to claim 22 wherein the dense layer has a thickness ranging from 0.01 micrometer to about 500 micrometers.
Claim 29
Dependent Claim 54 words
The membrane according to claim 24 wherein the dense layer is formed from a multicomponent metallic oxide demonstrates an oxygen ionic conductivity ranging from 0.01 ohm -1 cm -1 to 100 ohm -1 cm -1 and an electronic conductivity ranging from about 1 ohm -1 cm -1 to 100 ohm -1 cm -1 .
Claim 30
Dependent Claim 106 words
The membrane according to claim 25 wherein the dense layer and the first porous layer are independently formed from one or a mixture of multicomponent metallic oxides represented by the formula A x A' x' A" x" B y B' y' B" y" O 3-z , where A,A',A" are chosen from the group comprising Groups 1, 2 and 3 and the F block lanthanides; and B,B',B" are chosen from the D block transition metals according to the Periodic Table of the Elements adopted by the IUPAC wherein 0<x≦1, 0≦x'≦1, 0≦x"≦1, 0<y≦1, 0≦y'≦1, 0≦y"≦1, x+x'+x"=1, y+y'+y"=1 and z is a number which renders the compound charge neutral.
Claim 31
Dependent Claim 30 words
The membrane according to claim 25 wherein A, A' or A" of the formula is a Group 2 metal selected from the group consisting of calcium, strontium, barium and magnesium.
Claim 32
Dependent Claim 59 words
The membrane according to claim 25 wherein the dense layer and the first porous layer are independently formed from a multicomponent metallic oxide represented by the formula La x A 1-x Co y Fe 1-y O 3-z wherein x is between 0 and 1, y is between 0 and 1 and A is selected from barium, strontium or calcium.
Claim 33
Dependent Claim 74 words
The membrane according to claim 25 wherein the dense layer and the first porous layer are independently formed from a multicomponent metallic oxide selected from the group consisting of La 0 .2 Ba 0 .8 Co 0 .8 Fe 0 .2 O 3-x , Pr 0 .2 Ba 0 .8 Fe 0 .2 O 3-x and La 0 .2 Ba 0 .8 Co 0 .6 Cu 0 .2 Fe 0 .2 O 3-x .
Claim 34
Dependent Claim 73 words
A membrane capable of separating oxygen from an oxygen-containing gaseous mixture, which membrane comprises a first porous layer and a second porous layer which are separated by and contiguous with a dense layer having no connected through porosity wherein the first porous layer, the second porous layer and the dense layer are independently formed from a multicomponent metallic oxide capable of conducting electrons and oxygen ions at temperatures greater than about 500° C.
Claim 35
Dependent Claim 73 words
A membrane capable of separating oxygen from an oxygen-containing gaseous mixture, which membrane comprises a first porous layer and a second porous layer which are separated by and contiguous with a dense layer having no connected through porosity wherein the first porous layer, the second porous layer and the dense layer are independently formed from a multicomponent metallic oxide capable of conducting electrons and oxygen ions at temperatures greater than about 500° C.
Claim 36
Dependent Claim 36 words
The membrane according to claim 30 wherein the dense layer has a thickness ranging from 0.01 micrometer to about 500 micrometers and the porous layer has a thickness ranging from 1 micrometer to about 2 millimeters.
Claim 37
Dependent Claim 48 words
The membrane according to claim 31 wherein the multicomponent metallic oxide demonstrates an oxygen ionic conductivity ranging from 0.01 ohm -1 cm -1 to 100 ohm -1 cm -1 and an electronic conductivity ranging from about 1 ohm -1 cm -1 to 100 ohm -1 cm -1 .
Claim 38
Dependent Claim 108 words
The membrane according to claim 32 wherein the dense layer and the first and second porous layers are independently formed from one or a mixture of multicomponent metallic oxides represented by the formula A x A' x' A" x" B y B' y' B" y" O 3-z , where A,A',A" are chosen from the group comprising Groups 1, 2 and 3 and the F block lanthanides; and B,B',B" are chosen from the D block transition metals according to the Periodic Table of the Elements adopted by the IUPAC wherein 0<x≦1, 0≦x'≦1, 0≦x"≦1, 0<y≦1, 0≦y'≦1, 0≦y"≦1, x+x'+x"=1, y+y'+y"=1 and z is a number which renders the compound charge neutral.
Claim 39
Dependent Claim 30 words
The membrane according to claim 33 wherein A, A' or A" of the formula is a Group 2 metal selected from the group consisting of calcium, strontium, barium and magnesium.
Claim 40
Dependent Claim 53 words
The membrane according to claim 33 wherein the dense layer is formed from a multicomponent metallic oxide represented by the formula La x A 1-x Co y Fe 1-y O 3-z wherein x is between 0 and 1, y is between 0 and 1 and A is selected from barium, strontium or calcium.
Claim 41
Dependent Claim 72 words
The membrane according to claim 33 wherein the dense layer is formed from a multicomponent metallic oxide is selected from the group consisting of La 0 .2 Ba 0 .8 Co 0 .8 Fe 0 .2 O 3-x , Pr 0 .2 Ba 0 .8 Co 0 .8 Fe 0 .2 O 3-x and La 0 .2 Ba 0 .8 Co 0 .6 Cu 0 .2 Fe 0 .2 O 3-x .

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-08-30 1997-03-01 1997-08-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-08-30 2001-03-01 2001-08-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-08-30 2005-03-01 2005-08-31 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag