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Process for the production of polyurethane coatings

Assignee: Bayer Corp
•
Filing: 1992-05-01
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Granted: 1993-08-17
•
Expires: 2012-05-01
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Abstract

Abstract The present invention relates to a process for the preparation of a polyurethane coating by coating a substrate with a coating composition containing a) a polyisocyanate component and b) an isocyanate-reactive component containing at least one compound corresponding to the formula <IMAGE> (I) wherein X represents an organic group which has a valency of n and is inert towards isocyanate groups at a temperature of 100 DEG C. or less, R1 and R2 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100 DEG C. or less, R3 and R4 may be identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100 DEG C. or less and n represents an integer with a value of at least 2, and curing the coating composition at a temperature of 100 DEG C. or less.

Inventors

  • 👤 Christian Zwiener
  • 👤 Josef Pedain
  • 👤 Lothar Kahl
  • 👤 Klaus Nachtkamp

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 08:17
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/30; C08G18/38; C08G18/3819; C08G18/3821; C08G18/40; C08G18/62; C08G18/6216; C08G18/622; C08G18/6225; C08G18/6229; C08G18/70; C08G18/72; C08G18/77; C08G18/78; C08G18/7806; C08G18/7818; C08G18/7831; C08G18/79; C08G18/791; C08G18/792

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 153 words
A process for preparing a coating which comprises coating a substrate with a coating composition comprising effective film forming amounts of a) a polyisocyanate component and b) an isocyanate-reactive component comprising i) at least one compound corresponding to the formula ##STR5## wherein X represents an organic group which has a valency of n and is inert towards isocyanate groups at a temperature of 100° C., provided that X is not obtained by removing the amino groups from an aromatic polyamine, R 1 and R 2 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100° C. or less, R 3 and R 4 represent hydrogen and n represents 2, and ii) a polyhydroxyl compound in an amount of up to 20 hydroxy groups for each secondary amino group from component i), and hardening said composition at a temperature of 10° to 80° C.
Claim 2
Dependent Claim 153 words
A process for preparing a coating which comprises coating a substrate with a coating composition comprising effective film forming amounts of a) a polyisocyanate component and b) an isocyanate-reactive component comprising i) at least one compound corresponding to the formula ##STR5## wherein X represents an organic group which has a valency of n and is inert towards isocyanate groups at a temperature of 100° C., provided that X is not obtained by removing the amino groups from an aromatic polyamine, R 1 and R 2 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100° C. or less, R 3 and R 4 represent hydrogen and n represents 2, and ii) a polyhydroxyl compound in an amount of up to 20 hydroxy groups for each secondary amino group from component i), and hardening said composition at a temperature of 10° to 80° C.
Claim 3
Dependent Claim 39 words
The process of claim 1 wherein X represents an organic group obtained by removing the amino groups from ethylene diamine, 1,2-diaminopropane, 1,4-diaminobutane, 1,6-diaminohexane, 2,5-diamino-2,5-dimethylhexane, 2,2,4- and/or 2,4,4-trimethyl-1,6-diaminohexane, 1,11-diaminoundecane, 1,12-diaminododecane, 1-amino-3,3,5-trimethyl-5-aminomethylcyclohexane, 2,4- and/or 2,6-hexahydrotoluylene diamine, 2,4'-and/or 4,4'-diaminodicyclohexyl methane or 3,3'-dimethy-4,4'-diaminodicyclohexylmethane.
Claim 4
Dependent Claim 87 words
The process of claim 1 wherein component b) additionally comprises a copolymer which is prepared from a hydroxyalkyl ester of acrylic acid and/or methacrylic acid and another olefinically unsaturated monomer, has a molecular weight (M n ) of about 800 to 50,000 and a hydroxyl group content of about 0.1 to 12% by weight, and is present in an amount sufficient to provide a positive amount of up to 20 hydroxyl groups of said copolymer for each amino group provided by a compound corresponding to formula I.
Claim 5
Dependent Claim 87 words
The process of claim 2 wherein component b) additionally comprises a copolymer which is prepared from a hydroxyalkyl ester of acrylic acid and/or methacrylic acid and another olefinically unsaturated monomer, has a molecular weight (M n ) of about 800 to 50,000 and a hydroxyl group content of about 0.1 to 12% by weight, and is present in an amount sufficient to provide a positive amount of up to 20 hydroxyl groups of said copolymer for each amino group provided by a compound corresponding to formula I.
Claim 6
Dependent Claim 17 words
The process of claim 1 wherein R 1 and R 2 represent a methyl or ethyl group.
Claim 7
Dependent Claim 17 words
The process of claim 2 wherein R 1 and R 2 represent a methyl or ethyl group.
Claim 8
Dependent Claim 17 words
The process of claim 3 wherein R 1 and R 2 represent a methyl or ethyl group.
Claim 9
Dependent Claim 17 words
The process of claim 4 wherein R 1 and R 2 represent a methyl or ethyl group.
Claim 10
Dependent Claim 37 words
The process of claim 1 that the proportions of components a) and b) are calculated to provide an equivalent ratio of isocyanate groups of component a) to isocyanate-reactive groups of component b) of about 0.8:1 to 20:1.
Claim 11
Dependent Claim 34 words
The process of claim 1 wherein said coating composition additionally comprises a solvent in an amount sufficient to provide a weight ratio of components a) and b) to solvent of about 60:40 to 90:10.

References Cited (Backward Citations)

US3639418A Cited
US3814776A Cited
DE2158945A1 Cited
US4169931A Cited
US4412033A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-08-16 1997-02-15 1997-08-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-08-16 2001-02-15 2001-08-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-08-16 2005-02-15 2005-08-17 $7700.00 Window Closed / Lapsed

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