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US5232622A Expired / Lapsed US ⏱️ 0.0 years remaining

Chlorine-free machine dishwashing

Assignee: Rohm and Haas Co
•
Filing: 1991-08-12
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Granted: 1993-08-03
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Expires: 2011-08-12
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Abstract

Abstract This invention relates to chlorine-free machine dishwashing detergent compositions that provide cleaning as effective as conventional chlorine containing machine dishwashing compositions. More specifically, this invention relates to dishwashing detergent compositions containing copolymers formed from maleic acid, maleic anhydride, or salts thereof, and a copolymerizable hydrophobic monomer, oligomer or polymer, containing from 4 to 20 carbon atoms. Another aspect of the invention is a chlorine-free machine dishwashing detergent containing low levels of, or no phosphate.

Inventors

  • 👤 Charles E. Jones
  • 👤 Andrea C. Keenan
  • 👤 George M. Lein

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-10 00:59
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/37; C11D3/3746; C11D3/3757

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 238 words
A machine dishwashing detergent composition consisting of: (a) from about 0.5 to 10 percent by weight of a copolymer containing as polymerized units from 20 to 75% by weight of the copolymer of maleic acid, maleic anhydride, or salts thereof and from 25 to 80% by weight of the copolymer of a hydrophobe, wherein the hydrophobe is at least one monomer selected from the group consisting of isobutylene, diisobutylene, styrene, decene and eicosene; (b) from 0 to about 90 percent by weight of an alkaline builder selected from the group consisting of alkali metal polyphosphates, alkali metal carbonates, alkali metal borates, alkali metal hydroxides, alkali metal bicarbonates, alkali metal citrates, alkali metal carboxylates and alkali metal polycarboxylates; (c) from 0 to about 50 percent of an alkali metal silicate; (d) from 0 to about 40 percent of a zeolite; (e) from 0 to about 5 percent by weight of a stabilizer; (f) from 0 to about 10 percent by weight of surfactant selected from the group consisting of anionic, nonionic, zwitterionic, and amphoteric surfactants and combinations thereof as the only surfactants present; and (g) from 0 to about 5 percent by weight of other conventional adjuvants selected from the group consisting of perfumes, colorants, bacterial agents, and viscosity modifiers; wherein the sum of the percentages of a, b, c, d, e, f, and g is equal to 100 percent, and wherein said composition is substantially free of chlorine.
Claim 2
Dependent Claim 238 words
A machine dishwashing detergent composition consisting of: (a) from about 0.5 to 10 percent by weight of a copolymer containing as polymerized units from 20 to 75% by weight of the copolymer of maleic acid, maleic anhydride, or salts thereof and from 25 to 80% by weight of the copolymer of a hydrophobe, wherein the hydrophobe is at least one monomer selected from the group consisting of isobutylene, diisobutylene, styrene, decene and eicosene; (b) from 0 to about 90 percent by weight of an alkaline builder selected from the group consisting of alkali metal polyphosphates, alkali metal carbonates, alkali metal borates, alkali metal hydroxides, alkali metal bicarbonates, alkali metal citrates, alkali metal carboxylates and alkali metal polycarboxylates; (c) from 0 to about 50 percent of an alkali metal silicate; (d) from 0 to about 40 percent of a zeolite; (e) from 0 to about 5 percent by weight of a stabilizer; (f) from 0 to about 10 percent by weight of surfactant selected from the group consisting of anionic, nonionic, zwitterionic, and amphoteric surfactants and combinations thereof as the only surfactants present; and (g) from 0 to about 5 percent by weight of other conventional adjuvants selected from the group consisting of perfumes, colorants, bacterial agents, and viscosity modifiers; wherein the sum of the percentages of a, b, c, d, e, f, and g is equal to 100 percent, and wherein said composition is substantially free of chlorine.
Claim 3
Dependent Claim 22 words
The chlorine-free machine dishwashing detergent composition of claim 1 wherein the copolymer concentration is from about 2 to 7 percent by weight.
Claim 4
Dependent Claim 14 words
The chlorine-free machine dishwashing detergent composition of claim 1 wherein the hydrophobe is diisobutylene.
Claim 5
Dependent Claim 47 words
The chlorine-free machine dishwashing detergent composition of claim 1 wherein the copolymer contains as polymerized units from 25 to 70% by weight of the copolymer of maleic acid, maleic anhydride, or the salts thereof, and from 30 to 75% by weight of the copolymer of the hydrophobe.
Claim 6
Dependent Claim 23 words
The chlorine-free machine dishwashing detergent composition of claim 1 wherein the alkaline builder concentration is from about 20 to 90 percent by weight.
Claim 7
Dependent Claim 22 words
The chlorine-free machine dishwashing detergent composition of claim 1 wherein the silicate concentration is from about 1 to 10 percent by weight.
Claim 8
Dependent Claim 22 words
The chlorine-free machine dishwashing detergent composition of claim 1 wherein the zeolite concentration is from about 20 to 40 percent by weight.
Claim 9
Dependent Claim 22 words
The chlorine-free machine dishwashing detergent composition of claim 1 wherein the surfactant concentration is from about 1 to 5 percent by weight.
Claim 10
Dependent Claim 46 words
A process of washing food soiled utensils in a machine dishwasher comprising contacting said utensils with an aqueous solution of about 0.2 to 1.5 percent by weight of the detergent composition of claim 1 at a water temperature of about 80° F. to about 140° F.
Claim 11
Dependent Claim 22 words
The process of claim 9 wherein the copolymer concentration in the detergent composition is from about 2 to 7 percent by weight.
Claim 12
Dependent Claim 10 words
The process of claim 9 wherein the hydrophobe is diisobutylene.
Claim 13
Dependent Claim 43 words
The process of claim 9 wherein the copolymer contains as polymerized units from 25 to 70% by weight of the copolymer of maleic acid, maleic anhydride or the salt thereof and from 30 to 75% by weight of the copolymer of the hydrophobe.
Claim 14
Dependent Claim 23 words
The process of claim 9 wherein the alkaline builder concentration in the detergent composition is from about 20 to 90 percent by weight.
Claim 15
Dependent Claim 22 words
The process of claim 9 wherein the silicate concentration in the detergent composition is from about 1 to 10 percent by weight.
Claim 16
Dependent Claim 22 words
The process of claim 9 wherein the zeolite concentration in the detergent composition is from about 20 to 40 percent by weight.
Claim 17
Dependent Claim 22 words
The process of claim 9 wherein the surfactant concentration in the detergent composition is from about 1 to 5 percent by weight.
Claim 18
Dependent Claim 25 words
The process of claim 9 wherein the detergent concentration in the aqueous solution is from about 0.4 to 1 percent by weight of the detergent.
Claim 19
Dependent Claim 16 words
The process of claim 9 wherein the temperature is from about 100° F. to 125° F.

References Cited (Backward Citations)

US4347168A Cited
US4457856A Cited
US4687592A Cited
US4689167A Cited
US4906397A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-08-02 1997-02-01 1997-08-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-08-02 2001-02-01 2001-08-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-08-02 2005-02-01 2005-08-03 $7700.00 Window Closed / Lapsed

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