← Back to Patent Explorer
US4687592A Expired / Lapsed US ⏱️ 0.0 years remaining

Detergency builder system

Assignee: Procter and Gamble Co
•
Filing: 1985-07-11
•
Granted: 1987-08-18
•
Expires: 2005-07-11
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A highly effective detergency builder system comprises the combination of a major proportion of an ether polycarboxylate and minor proportions of an iron and manganese chelating agent and a polymeric polycarboxylate dispersing agent.

Inventors

  • 👤 Jerome H. Collins
  • 👤 Larry N. Mackey
  • 👤 Gianfranco L. Spadini

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 13:58
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/26; C11D3/30; C11D3/20; C11D3/2075; C11D3/2082; C11D3/2086; C11D3/2089; C11D3/32; C11D3/33; C11D3/34; C11D3/3418; C11D3/36; C11D3/364; C11D3/37; C11D3/3746; C11D3/3757

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 331 words
A detergent composition comprising: (a) from about 2% to about 30% by weight of a surfactant selected from the group consisting of anionic, nonionic, zwitterionic, ampholytic and cationic surfactants and mixtures thereof; (b) from about 15% to about 40% of an ether polycarboxylate compound or mixtures thereof of the structure: ##STR20## wherein R 1 and R 2 are each independently H, COOM or CH 2 COOM and wherein R 1 and R 2 are not both H and wherein M is hydrogen, an alkali metal, ammonium or substituted ammonium and said compound has a log K Ca (35° C., 0.1M ionic strength, pH 9.5) of at least about 3.6; (c) from about 0.75% to about 3% by weight of an iron and manganese chelating agent selected from the group consisting of: 1) amino carboxylates having one or more units of the substructure: ##STR21## wherein M is hydrogen, an alkali metal, ammonium or substituted ammonium, and x is from 1 to about 3, (2) amino phosphonates having one or more units of the substructure: ##STR22## wherein M is hydrogen, an alkali metal, ammonium or substituted ammonium and x is from 1 to about 3, 3) polyfunctionally-substituted aromatic chelating agents consisting of compounds having the formula: ##STR23## wherein at least one R is --SO 3 H, or --COOH or soluble salts thereof and mixtures thereof and 4) mixtures thereof; (d) from about 0.75% to about 3% by weight of one or more polymeric polycarboxylic acid dispersing agents, copolymers thereof and salts thereof containing at least about 60% by weight of segments with the general formula: ##STR24## wherein X, Y and Z are each selected from the group consisting of hydrogen, methyl, and carboxy; M is hydrogen, alkali metal, ammonium or substituted ammonium and n is from about 30 to about 400; and (e) from 0% to about 75% by weight of an inorganic detergency builder selected from the group consisting of alkali metal phosphates, sodium carbonate, sodium silicate, sodium aluminosilicate and mixtures thereof.
Claim 2
Dependent Claim 331 words
A detergent composition comprising: (a) from about 2% to about 30% by weight of a surfactant selected from the group consisting of anionic, nonionic, zwitterionic, ampholytic and cationic surfactants and mixtures thereof; (b) from about 15% to about 40% of an ether polycarboxylate compound or mixtures thereof of the structure: ##STR20## wherein R 1 and R 2 are each independently H, COOM or CH 2 COOM and wherein R 1 and R 2 are not both H and wherein M is hydrogen, an alkali metal, ammonium or substituted ammonium and said compound has a log K Ca (35° C., 0.1M ionic strength, pH 9.5) of at least about 3.6; (c) from about 0.75% to about 3% by weight of an iron and manganese chelating agent selected from the group consisting of: 1) amino carboxylates having one or more units of the substructure: ##STR21## wherein M is hydrogen, an alkali metal, ammonium or substituted ammonium, and x is from 1 to about 3, (2) amino phosphonates having one or more units of the substructure: ##STR22## wherein M is hydrogen, an alkali metal, ammonium or substituted ammonium and x is from 1 to about 3, 3) polyfunctionally-substituted aromatic chelating agents consisting of compounds having the formula: ##STR23## wherein at least one R is --SO 3 H, or --COOH or soluble salts thereof and mixtures thereof and 4) mixtures thereof; (d) from about 0.75% to about 3% by weight of one or more polymeric polycarboxylic acid dispersing agents, copolymers thereof and salts thereof containing at least about 60% by weight of segments with the general formula: ##STR24## wherein X, Y and Z are each selected from the group consisting of hydrogen, methyl, and carboxy; M is hydrogen, alkali metal, ammonium or substituted ammonium and n is from about 30 to about 400; and (e) from 0% to about 75% by weight of an inorganic detergency builder selected from the group consisting of alkali metal phosphates, sodium carbonate, sodium silicate, sodium aluminosilicate and mixtures thereof.
Claim 3
Dependent Claim 19 words
The composition of claim 1 wherein the ether polycarboxylate has a log K Ca of at least about 4.2.
Claim 4
Dependent Claim 37 words
The composition of claim 1 wherein the ether polycarboxylate comprises a material selected from the group consisting of 2-oxa-1,1,3 propanetricarboxylic acid, 2-oxa-1,3,4 butanetricarboxylic acid, 3-oxa-1,2,4,5-pentanetetracarboxylic acid, mixtures thereof and alkali metal, ammonium and substituted ammonium salts thereof.
Claim 5
Dependent Claim 42 words
The composition of claim 1 wherein the iron and manganese chelating agent comprises a material selected from the group consisting of ethylenediaminetetraacetates, diethylenetriaminepentaacetates, N-hydroxyethylethylenediaminetriacetates, nitrilotriacetates, ethanoldiglycines, ethylenediaminetetrakis(methylenephosphonates), nitrilotris(methylenephosphonates), diethylenetriaminepentakis(methylenephosphonates), disulfonated catechols, mixtures thereof and alkali metal, ammonium and substituted ammonium salts thereof.
Claim 6
Dependent Claim 35 words
The composition of claim 3 wherein the polymeric polycarboxylate comprises a material selected from the group consisting of polyacrylates, copolymers of acrylates and maleates, mixtures thereof and alkali metal, ammonium and substituted ammonium salts thereof.
Claim 7
Dependent Claim 56 words
The composition of claim 1 wherein said composition is a granular detergent composition comprising from about 15% to about 60% of an inorganic detergency builder selected from the group consisting of sodium carbonate, sodium silicate and mixtures thereof and from about 15% to about 40% of sodium salts of said ether polycarboxylate compound or mixtures thereof.
Claim 8
Dependent Claim 28 words
The composition of claim 5 wherein said surfactant comprises an anionic surfactant selected from the group consisting of alkyl sulfates, alkyl ether sulfates, alkylbenzene sulfonates and mixtures thereof.
Claim 9
Dependent Claim 31 words
The composition of claim 6 wherein said ether polycarboxylate comprises a material selected from the group consisting of the sodium salts of 2-oxa-1,1,3-propanetricarboxylic acid, 2-oxa-1,3,4-butanetricarboxylic acid, 3-oxa-1,2,4,5-pentanetetracarboxylic acid, and mixtures thereof.
Claim 10
Dependent Claim 9 words
The composition of claim 7 containing essentially no phosphorus.
Claim 11
Dependent Claim 30 words
The composition of claim 8 which comprises an alkali metal salt of a polymeric polycarboxylate selected from the group consisting of polyacrylates, copolymers of acrylates and maleates and mixtures thereof.
Claim 12
Dependent Claim 27 words
The composition of claim 1 wherein said composition is a liquid detergent composition comprising from about 5% to about 15% of said ether polycarboxylate or mixture thereof.
Claim 13
Dependent Claim 23 words
A composition according to claim 1 additionally comprising from about 5% to about 35% by weight of inorganic or organic peroxy bleaching agent.
Claim 14
Dependent Claim 21 words
A composition according to claim 11 additionally comprising from about 0.5% to about 10% by weight of organic peroxyacid bleach precursor.
Claim 15
Dependent Claim 71 words
A composition according to claim 12 wherein the bleach precursor has the general formula: ##STR25## wherein R is an alkyl group containing from 6 to 12 carbon atoms wherein the longest linear alkyl chain extending from and including the carboxyl carbon contains from 5 to 10 carbon atoms and L is a leaving group, the conjugate acid of which has a logarithmic acidity constant in the range from 6 to 13.

References Cited (Backward Citations)

US3308067A Cited
US3293176A Cited
US3368978A Cited
US3758420A Cited
US4021376A Cited
US3776850A Cited
US4083794A Cited
US4125485A Cited
US4146495A Cited
GB2143231A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-08-17 1991-02-16 1991-08-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-08-17 1995-02-16 1995-08-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-08-17 1999-02-16 1999-08-18 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag