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Multilayer composites coextruded with the use of impact-reinforced impervious resin compositions and their use for the manufacture of fuel storage vessels

Assignee: Solvay SA
•
Filing: 1992-11-27
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Granted: 1993-07-27
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Expires: 2012-11-27
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Abstract

Abstract Multilayer composites coextruded with the use of polyolefins and of impact-reinforced impervious resin compositions based on hydrolysed copolymers of vinyl acetate and ethylene comprising, as an additive improving the impact strength, elastomeric copolymers of ethylene and propylene which are modified by grafting an α,β-ethylenically unsaturated carboxylic acid and, preferably, by maleic anhydride. The coextruded multilayer composites are very particularly suitable for the manufacture of fuel storage vessels combining impact strength and high imperviousness to petrol and to petrol/alcohol mixtures.

Inventors

  • 👤 Didier Delimoy
  • 👤 Pierre De Longree

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 10:35
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/18; C; C08; C08L; C08L29/00; C08L29/02; C08L29/04; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1379; Y10T428/1383; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31913; Y10T428/31928

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 82 words
A coextruded multilayer composite, comprising: a layer of a polyolefin; a layer of an impact-reinforced impervious resin composition consisting essentially of a hydrolyzed copolymer of vinyl acetate and ethylene, and an elastomeric copolymer of ethylene and propylene which is modified by grafting an α,β-ethylenically unsaturated carboxylic acid as an additive in an amount effective for improving impact strength; and an intermediate layer of a polymeric adhesive bonding together the layer of a polyolefin and the layer of an impact-reinforced impervious resin composition.
Claim 2
Dependent Claim 82 words
A coextruded multilayer composite, comprising: a layer of a polyolefin; a layer of an impact-reinforced impervious resin composition consisting essentially of a hydrolyzed copolymer of vinyl acetate and ethylene, and an elastomeric copolymer of ethylene and propylene which is modified by grafting an α,β-ethylenically unsaturated carboxylic acid as an additive in an amount effective for improving impact strength; and an intermediate layer of a polymeric adhesive bonding together the layer of a polyolefin and the layer of an impact-reinforced impervious resin composition.
Claim 3
Dependent Claim 55 words
The coextruded multilayer composite according to claim 1 wherein the modified elastomeric copolymers of ethylene and propylene comprise form 40 to 95 mol % of ethylene-derived monomer units, form 60 to 5 mol % of propylene-derived monomer units and from 0.1 to 1.5% by weight of monomer units derived from an α,β-ethylenically unsaturated carboxylic acid.
Claim 4
Dependent Claim 55 words
The coextruded multilayer composite according to claim 1, wherein the modified elastomeric copolymers of ethylene and propylene comprise from 45 to 85 mol % of ethylene-derived monomer units, from 55 to 15 mol % of propylene-derived monomer units and from 0.6 to 1.2% by weight of monomer units derived from and α,β-ethylenically unsaturated carboxylic acid.
Claim 5
Dependent Claim 23 words
The coextruded multilayer composite according to claim 1, wherein the elastomeric copolymers of ethylene and propylene are modified by grafting with maleic anhydride.
Claim 6
Dependent Claim 28 words
The coextruded multilayer composite according to claim 1, wherein the impervious resin compositions comprise form 5 to 35% by weight of modified elastomeric copolymers of ethylene and propylene.
Claim 7
Dependent Claim 28 words
The coextruded multilayer composite according to claim 5, wherein the impervious resin compositions comprise from 15 to 25% by weight of modified elastomeric copolymers of ethylene and propylene.
Claim 8
Dependent Claim 39 words
The coextruded multilayer composite according to claim 1 wherein they comprise three layers consisting of an outer layer of high density polyethylene, an intermediate layer of polymeric adhesive and an outer layer consisting of an impact-reinforced impervious resin composition.
Claim 9
Dependent Claim 37 words
The coextruded multilayer composite according to claim 1, wherein they comprise three layers consisting of an outer layer of polypropylene, an intermediate layer of polymeric adhesive and an outer layer consisting of an impact-reinforced impervious resin composition.
Claim 10
Dependent Claim 36 words
The coextruded multilayer composite according to claim 1, wherein they comprise essentially two outer layers of high density polyethylene, an internal layer consisting of an impact-reinforced impervious resin composition and two intermediate layers of polymeric adhesive.
Claim 11
Dependent Claim 24 words
In a process of manufacturing a fuel storage vessel the improvement comprising manufacturing said vessel from a coextruded multilayer composite according to claim 9.

References Cited (Backward Citations)

JPS55155042A Cited
US4477532A Cited
US4409364A Cited
US4600746A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-07-26 1997-01-25 1997-07-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-07-26 2001-01-25 2001-07-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-07-26 2005-01-25 2005-07-27 $7700.00 Window Closed / Lapsed

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